• 제목/요약/키워드: Porous Layer

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Polycarbonate/Metal Salt 막의 산소분리특성에 미치는 비용매와 금속염 농도의 영향 (Effect of Nonsolvent and Metal Salt Concentration on Oxygen Separation Performances of Polycarbonate/Metal Salt Membrane)

  • 서상훈;이우태
    • 한국산업융합학회 논문집
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    • 제4권1호
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    • pp.61-69
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    • 2001
  • Polycarbonate(PC) membranes for oxygen enrichment from air were prepared by the wet phase inversion method. In order to improve oxygen separation performances of the PC membrane, the effect of the added ethanol(nonsolvent) and $CuCl_2$(metal salt) concentration in the casting solution on morphology, oxygen permeability ami $O_2/N_2$ separation factor of the membrane was studied. In addition, tensile strength and elongation at break of the membrane were investigated. An asymmetric membrane with a dense top layer and a porous sublayer was obtained. The thickness of the dense top layer decreased with increasing amount of nonsolvent additive. Compared with pure PC membrane without additive(metal salt), the oxygen permeability and $O_2/N_2$ separation factor of the $PC/CuCl_2$ membrane are significantly improved. The oxygen permeability and $O_2/N_2$ separation factor is $5.25{\times}10^{-9}cm^3(STP){\cdot}cm/cm^2{\cdot}sec{\cdot}cmHg$ and 4.5, respectively. This improvement might be due to good interaction between metal salt and oxygen.

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강화상과 기공이 포함된 금속기지 복합재 모델의 ECAP 거동에 대한 유한요소해석 (Finite Element Analysis of Deformation Behavior During ECAP for an Aluminum Alloy Composite Model containing a SiC Particle and Porosities)

  • 이성철;하상렬;김기태;황상무;허륜민;정형식
    • 대한기계학회논문집A
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    • 제28권6호
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    • pp.739-746
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    • 2004
  • The plastic deformation behavior of an aluminum alloy containing a particle and porosities was investigated at room temperature during equal channel angular pressing (ECAP). Finite element analysis by using ABAQUS shows that ECAP is a useful tool for eliminating residual porosity in the specimen, and more effective under friction condition. The simulation, however, shows considerably low density distributions for matrix near a particle at which many defects may occur during severe deformation. Finite element results of effective strains and deformed shapes for matrix with a particle were compared with theoretical calculations under simple shear stress. Also, based on the distribution of the maximum principal stress in the specimen, Weibull fracture probability was obtained for particle sizes and particle-coating layer materials. The probability was useful to predict the trend of more susceptible failure of a brittle coating layer than a particle without an interphase in metal matrix composites.

Fabrication of YSZ/GDC Bilayer Electrolyte Thin Film for Solid Oxide Fuel Cells

  • Yang, Seon-Ho;Choi, Hyung-Wook
    • Transactions on Electrical and Electronic Materials
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    • 제15권4호
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    • pp.189-192
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    • 2014
  • Yttria-stablized zirconia (YSZ) is the most commonly used electrolyte material, but the reduction in working temperature leads to insufficient ionic conductivity. Ceria based electrolytes (GDC) are more attractive in terms of conductivity at low temperature, but these materials are well known to be reducible at very low oxygen partial pressure. The reduction of electrolyte resistivity is necessary to overcome cell performance losses. So, thin YSZ/GDC bilayer technology seems suitable for decreasing the electrolyte resistance at lower operating temperatures. Bilayer electrolytes composed of a galdolinium-doped $CeO_2$ ($Ce_{0.9}Gd_{0.1}O_{1.95}$, GDC) layer and yttria-stabilized $ZrO_2$ (YSZ) layer with various thicknesses were deposited by RF sputtering and E-beam evaporation. The bilayer electrolytes were deposited between porous Ni-GDC anode and LSM cathode for anode-supported single cells. Thin film structure and surface morphology were investigated by X-ray diffraction (XRD), using $CuK{\alpha}$-radiation in the range of 2ce morphol$^{\circ}C$. The XRD patterns exhibit a well-formed cubic fluorite structure, and sharp lines of XRD peaks can be observed, which indicate a single solid solution. The morphology and size of the prepared particles were investigated by field-emission scanning electron microscopy (FE-SEM). The performance of the cells was evaluated over $500{\sim}800^{\circ}C$, using humidified hydrogen as fuel, and air as oxidant.

Properties of Indium Tin Oxide Multilayer Fabricated by Glancing Angle Deposition Method

  • Oh, Gyujin;Lee, Kyoung Su;Kim, Eun Kyu
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.367-367
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    • 2013
  • Commercial applications of indium tin oxide (ITO) can be separated into two useful areas. As it is perceived to bear electrical properties and optical transparency at once, its chance to apply to promising fields, usually for an optical device, gets greater in the passing time. ITO is one of the transparent conducting oxides (TCO), and required to carry the relative resistance less than $10^{-3}{\Omega}$/cm and transmittances over 80 % in the visible wavelength of light. Because ITO has considerable refractive index, there exist applications for anti-reflection coatings. Anti-reflection properties require gradual change in refractive index from films to air. Such changes are obtained from film density or nano-clustered fractional void. Glancing angle deposition (GLAD) method is a well known process for adjusting nanostructure of the films. From its shadowing effects, GLAD helps to deposit well-controlled porous films effectively. In this study, we are comparing the reference sample to samples coated with controlled ITO multilayer accumulated by an e-beam evaporation system. At first, the single ITO layer samples are prepared to decide refractive index with ellipsometry. Afterwards, ITO multilayer samples are fabricated and fitted by multilayer ellipsometric model based on single layer data. The structural properties were measured by using atomic force microscopy (AFM), and by scanning X-ray diffraction (XRD) measurements. The ellipsometry was used to determine refractive indices and extinction coefficient. The optical transmittance of the film was investigated by using an ultraviolet-visible (UV-Vis) spectrophotometer.

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ENHANCEMENT THE SOUND TRANSMISSION LOSS OF POROELASTIC LININGS

  • Song, B.Heuk-Jin;Bolton, J.Stuart
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2000년도 춘계학술대회논문집
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    • pp.606-611
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    • 2000
  • It has been noted that the low frequency absorption coefficient of a porous sample placed in a standing wave tube is affected by the nature of the sample's edge constraint. The edge constraint has the effect of stiffening the solid phase of the sample, which itself can be strongly coupled to the material's fluid phase, and hence the incident sound field, by viscous means at low frequencies. In recent work it has also been shown that such a circumferential constraint causes the low frequency transmission loss of a layer of fibrous material to approach a finite low frequency limit that is proportional to the flow resistance of the layer and which is substantially higher than that of an unconstrained sample of the same material. However, it was also found that the benefit of the circumferential edge constraint was reduced in a transitional frequency range by a shearing resonance of the sample. Here it will be shown that the effect of that resonance can be mitigated or eliminated by adding additional axial and radial constraints running through the sample. It will also be shown that the constraint effect can be modeled closely by using a finite element procedure based on the Biot poroelastic theory. Implications for low frequency barrier design are also discussed.

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ECAP 공정시 강화상이 첨가된 금속기지 거동에 대한 유한요소해석 (Finite Element Analysis for Behavior of Aluminum Alloy Embedding a Particle under Equal Channel Angular Pressing)

  • 이성철;하상렬;김기태;정형식
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.1157-1162
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    • 2003
  • Behavior of aluminum alloy embedding a particle was investigated at room temperature under ECAP. Finite element analysis by using ABAQUS shows that ECAP is a useful tool for eliminating residual porosity in the specimen, and much more effective under friction condition. The simulation, however, shows considerably low density distributions for matrix near a particle at which rich defects may occur during severe deformation. Finite element results of effective strains and deformed shapes for matrix with a particle were compared with theoretical calculations under simple shear stress. Also, based on the distribution of the maximum principal stress in the specimen, Weibull fracture probability was obtained for particle sizes and particle-coating layer materials. The probability was useful to predict the trend of more susceptible failure of a brittle coating layer than a particle without an interphase in metal matrix composites.

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방전플라즈마 소결법으로 제작한 β-FeSi2 소결체의 고온 내산화성 (Oxidation Resistance of SPS (Spark Plasma Sintering) Sintered β-FeSi2Bodies at High Temperature)

  • 장세훈;홍지민;오익현
    • 한국재료학회지
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    • 제17권3호
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    • pp.132-136
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    • 2007
  • Oxidation resistance of sintered ${\beta}-FeSi_{2}$ was investigated at intermediate temperature range in air atmosphere. Fully dense and porous bodies of ${\beta}-FeSi_{2}$ samples were fabricated by using the Spark Plasma Sintering (SPS). They were annealed at $900^{\circ}C$ for 5days to obtain ${\beta}-FeSi_{2}$ phase. The bulk samples were oxidized at $800,\;900\;and\;950^{\circ}C$ in air atmosphere. The high temperature oxidation tests reveal that amorphous $SiO_{2}$ layer, similar to Si was formed and grew parabolically on ${\beta}-FeSi_{2}$. Accelerated oxidation is not observed as well as cracks and grain boundary oxidation. Granular ${\varepsilon}-FeSi$ was developed below the oxide layer as a result of oxidation of ${\beta}-FeSi_{2}$. Oxidation resistance of sintered ${\beta}-FeSi_{2}$ was excellent for high-temperature thermoelectric application.

벽식구조 공동주택의 바닥충격음 개선에 대한 연구 (A Study on the Improvement of the Floor Impact Sound Insulation Performance in Wall Slab Type Apartment)

  • 김선우
    • KIEAE Journal
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    • 제12권1호
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    • pp.73-81
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    • 2012
  • Floor impact sound has been most annoying for years among the noises which are produced in apartment. This study aims to analyze the improvement of floor impact sound by comparing the results of the test which was carried out for the wall slab type apartment and moment frame apartment, and also for the effect of advanced vibration isolation layer. Moment frame structure that main structure consists of column and slab has shown better performance for the heavyweight impact sound comparing with wall slab type structure which is general type in Korea. Stiffness of floor system was raised by reinforcing the stiffness of vibration isolation layer, and it was analyzed how much the floor impact sound performance was improved. The result showed that the reinforced floor had better performance than the existing floor system that uses lightweight porous concrete as vibration isolation material. In addition, a system used wire mesh in mortar showed improvement of floor impact sound than a system without wire mesh, and better performance for the frequency bands lower than 160 Hz which causes floor impact problem in wall slab type apartment.

해빈내의 흐름장 해석을 위한 침투류 모형 (Seepage Flow Model for Analysis of the Flow Field within the Beach)

  • 김규한;박창근;한상대;편종근
    • 한국해안해양공학회지
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    • 제9권3호
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    • pp.125-131
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    • 1997
  • 해빈 보존공법중 배수층설지 공법의 타당성 분석을 위하여 파랑모형과 침투류모형을 결합한 복합모형을 구성하여 수치실험을 수행하였다 파랑모형으로는 Shuto(1972)의 해석해를 사용하였고, 침투류모형으로는 포화-비포화흐름의 지배방정식인 Richards식을 사용하였다. 구성된 복합모형의 민감도 분석에 의하면 포화투수계수가 해빈내부의 지하수 흐름장에 가장 민감한 영향을 미치고 있음을 알 수 있었다. 또한 보다 많은 현지의 실측자료들이 수집 된다면 개발된 모형은 해빈내에 배수층 설치시 필요로 되는 제요소 해석에 효율적으로 이용될 수 있을 것이다

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금속기질에 앓은 마이크로 다공질 스케폴드 코팅에 관한 연구 (Thin Micro-Porous Scaffold Layer on Metallic Substrate)

  • 신동춘;자이젱 미아오;김원철
    • 동력기계공학회지
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    • 제14권5호
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    • pp.41-47
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    • 2010
  • 티타늄과 티타늄 합금은 재료적 특이성 때문에 심장 혈관 임플란트에서 일반적으로 사용되어 왔다. 일찍이 적용된 예로는 인공심장판막, 심박조율기의 보호케이스, 혈액 순환 장치 등이 있다. 하지만 물질유도혈전증(Material-induced thrombosis)은 혈전폐색에 의해 기인한 기능 손실로 심장혈관 임플란트 장치의 주된 합병증으로 존재하고 있으며, 심장혈관 임플란트의 혈전유전자는 심장혈관장치의 발달에 주된 난관 중 하나로 남아있다. 그리고 텍스처 혈액 접합 물질(Textured blood-contacting material)은 1960년대 초반 이후부터 혈액순환 보조 장치의 임상실험에 사용되고 있다. 접합 물질에 내장된 텍스처 섬유조직 표면은 형성, 성장, 안정적 부착, 생물학적 내벽(neointimal layer) 등 유도 혈액(entrapping blood) 성분에 의해 형성된다. 공동(cavity) 형상의 용해 가능한 미립자를 사용하는 SCPL법(Solvent casting/particulate leaching method)은 티타늄 기질 이전에 형성된 폴리우레탄 위에 텍스처(texture)를 생성하기 위해 사용되었다. 또한 콜라겐의 부동화(不動化)에 의한 공동(cavity)은 혈액 접합면에 잔존하기 위한 내피세포를 고정할 수 있는 효과가 있다. cpTi로 층화된 PU 기소공성(microporous)은 구조적 특성과 혈전증 감소를 위한 생물학적 내벽 사용의 잠재성을 평가하기 위한 세포 공동체 실험을 통해서 평가되었다.