• Title/Summary/Keyword: Porous Composite

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Preparation and Characterization of Cerium Oxide/Silica Composite Particles (세륨 옥사이드/실리카 복합입자 제조 및 특성분석)

  • Koh, Seo Eun;Shim, Jongwon;Jin, Byung Suk
    • Applied Chemistry for Engineering
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    • v.29 no.4
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    • pp.425-431
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    • 2018
  • Composite particles of porous silica and cerium oxide nanoparticles blocking UV/blue light were prepared through a dry coating process. Various composite particles were prepared by varying conditions such as the mixing ratio of cerium oxide and silica, and the chamber rotating speed of mechano fusion system. The surface morphology of the composite particles was observed with SEM and the composition was analyzed using X-ray fluorescence (XRF). When the cerium oxide/silica composite particles were dispersed in water, the transparency and dispersion stability of the colloidal solution were improved. In addition, the fluidity and spreadability of the particle powder were enhanced by making composite particles. These results show that cerium oxide/silica composite particles can be used as functional cosmetic ingredients for UV/blue light protection.

Physical Properties of Insulating Composite Materials Using Natural Cellulose and Porous Ceramic Balls as a Core Materials (천연섬유질과 다공성 세라믹볼을 심재로 사용한 복합단열재의 물성)

  • Hwang, Eui-Hwan;Cho, Soung-Jun;Kim, Jin-Man
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.501-507
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    • 2011
  • To develop environmental-friendly insulating composite materials, natural cellulose and porous ceramic balls were used as core materials and activated Hwangtoh was used as a binder. Various specimens were prepared with different water/binder ratios and core material/binder ratios. The physical properties of these specimens were then investigated through compressive strengths, flexural strengths, absorption test, hot water resistance test, pore analysis, thermal conductivity, and observation of micro-structures using scanning electron microscope. Results showed that the maximum compressive strength varied appreciably with the water/binder ratios and core material/binder ratios, but the flexural strength increased with the core material/binder ratios regardless of water/binder ratios. The compressive strength and the flexural strength measured after the hot water resistance test decreased remarkably compared to those measured before test. The pore analysis measured after the hot water resistance test showed that total pore volume, porosity and average pore diameter decreased, while bulk density increased by the acceleration of hydration reaction of binder in the hot water. The thermal conductivity decreased gradually with an increase of core material/binder ratios. It can be evaluated that the composite insulation materials having good insulating properties and mechanical strengths can be used in the field.

Microstructure Control and Mechanical Properties of Continuously Porous SiC-Si3N4 Composites (연속다공질 SiC-Si3N4 복합체의 미세구조 및 기계적 특성)

  • Paul Rajat Kanti;Gain Asit Kumar;Lee Hee-Jung;Jang Hee-Dong;Lee Byong-Taek
    • Korean Journal of Materials Research
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    • v.16 no.3
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    • pp.188-192
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    • 2006
  • The microstructures and mechanical properties of continuously porous $SiC-Si_3N_4$composites fabricated by multi-pass extrusion were investigated at different Si levels added. Si-powder with different weight percentages (0%, 5%, 10%, 15%, 20%) was added to the SiC powder to make the raw mixture powders, with $6wt%Y_2O_3-2wt%Al_2O_3$ as sintering additives, carbon ($10-15{\mu}m$) as a pore-forming agent, ethylene vinyl acetate as a binder and stearic acid ($CH_3(CH_2)_{16}COOH$) as a lubricant. In the continuously porous $SiC-Si_3N_4$ composites, $Si_3N_4$ whiskers like the hairs of nostrils were frequently observed on the wall of the pores. In this study, the morphology of the $Si_3N_4$ whiskers was investigated with the silicon addition content. In the composites containing of 10 wt% Si, a large number of $Si_3N_4$ whiskers was found at the continuous pore regions. In the sample to which 15 wt% Si powder was added, maximum values of about 101 MPa bending strength and 57.5% relative density were obtained.

CO Adsorption on Three-Dimensional and Multilayered Platinum Electrode Prepared through Transfer Printing (전사 인쇄에 의한 3D와 다층의 Pt 전극의 CO가스 흡착)

  • Jeong, Yoon-Seo;Choi, You-Jeong;Shin, Jeong-Hee;Jeong, Young-Hun;Paik, Jong-Hoo;Yoon, Dae-Ho;Cho, Jeong-Ho
    • Journal of Sensor Science and Technology
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    • v.29 no.4
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    • pp.232-236
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    • 2020
  • Three-dimensional (3D) multilayered Pt electrodes were fabricated to develop a porous electrode using a pattern-transfer printing process. The Pt thin films were deposited using a transferred sputtering pattern having a 250 nm line width on the substrate, and the uniform line patterns were efficiently transferred using our proposed method. Temperature-programmed desorption (TPD) analyses were used to evaluate the porosity of the electrodes. It was possible to distinguish between two resolved maxima at 168 and 227 ℃, which could be described in terms of desorption reactions on the Pt (111) planes. The results of the TPD analysis of the 3D and multilayered Pt electrodes prepared through transfer printing were compared to those of an electrode fabricated through screen printing using a commercial Pt-carbon paste commonly used as porous electrodes. It was confirmed that the 3D multilayered electrodes exhibited a desorption concentration approximately 100 times higher than that of the Pt-carbon composite electrode, and the desorption concentration increased by approximately 0.02 mg/mol per layer. The 3D multilayered electrode effectively functions as a porous electrode and a catalyst.

Microstructure Control of Reaction-Sintered Porous Mullite (반응소결된 다공성 뮬라이트의 미세구조 제어)

  • 조범래;윤상렬;강종봉
    • Composites Research
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    • v.13 no.5
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    • pp.31-36
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    • 2000
  • The effect of several important processing variables was investigated on formation of porous mullite with acicular microstructure. Experimental results demonstrated that microstructure and porosity of porous mullite are depending on concentration of $AlF_3$, holding time at $900^{\circ}C$ and starting material. Acicular mullite was developed by increasing amount of $AlF_3$ and holding time at $900^{\circ}C$. Mullite began to be formed at $1200^{\circ}C$ and the resultant microstructure sintered at this temperature is similar to those at higher temperatures. Porosity increases with increase in amounts of $AlF_3$ and holding time at $900^{\circ}C$ . Therefore, it is found that microstructure of reaction-sintered porous mullite can be controlled by governing the amount of $AlF_3$ and holding time at $900^{\circ}C$.

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Vibration analysis of FG porous rectangular plates reinforced by graphene platelets

  • Zhou, Changlin;Zhang, Zhongxian;Zhang, Ji;Fang, Yuan;Tahouneh, Vahid
    • Steel and Composite Structures
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    • v.34 no.2
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    • pp.215-226
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    • 2020
  • The aim of this study is to investigate free vibration of functionally graded porous nanocomposite rectangular plates where the internal pores and graphene platelets (GPLs) are distributed in the matrix either uniformly or non-uniformly according to three different patterns. The elastic properties of the nanocomposite are obtained by employing Halpin-Tsai micromechanics model. The GPL-reinforced plate is modeled using a semi-analytic approach composed of generalized differential quadrature method (GDQM) and series solution adopted to solve the equations of motion. The proposed rectangular plates have two opposite edges simply supported, while all possible combinations of free, simply supported and clamped boundary conditions are applied to the other two edges. The 2-D differential quadrature method as an efficient and accurate numerical tool is used to discretize the governing equations and to implement the boundary conditions. The convergence of the method is demonstrated and to validate the results, comparisons are made between the present results and those reported by well-known references for special cases treated before, have confirmed accuracy and efficiency of the present approach. New results reveal the importance of porosity coefficient, porosity distribution, graphene platelets (GPLs) distribution, geometrical and boundary conditions on vibration behavior of porous nanocomposite plates. It is observed that the maximum vibration frequency obtained in the case of symmetric porosity and GPL distribution, while the minimum vibration frequency is obtained using uniform porosity distribution.

Investigation on the dynamic response of porous FGM beams resting on variable foundation using a new higher order shear deformation theory

  • Atmane, Redhwane Ait;Mahmoudi, Noureddine;Bennai, Riadh;Atmane, Hassen Ait;Tounsi, Abdelouahed
    • Steel and Composite Structures
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    • v.39 no.1
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    • pp.95-107
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    • 2021
  • In this work, the dynamic response of functionally graded beams on variable elastic foundations is studied using a novel higher-order shear deformation theory (HSDT). Unlike the conventional HSDT, the present one has a new displacement field which introduces undetermined integral variables. The FG beams were assumed to be supported on Winkler-Pasternak type foundations in which the Winkler modulus is supposed to be variable in the length of the beam. The variable rigidity of the elastic foundation is assumed to be linear, parabolic and sinusoidal along the length of the beam. The material properties of the FG porous beam vary according to a power law distribution in terms of the volume fraction of the constituents. The equations of motion are determined using the virtual working principle. For the analytical solution, Navier method is used to solve the governing equations for simply supported porous FG beams. Numerical results of the present theory for the free vibration of FG beams resting on elastic foundations are presented and compared to existing solutions in the literature. A parametric study will be detailed to investigate the effects of several parameters such as gradient index, thickness ratio, porosity factor and foundation parameters on the frequency response of porous FG beams.

Buckling of 2D FG Porous unified shear plates resting on elastic foundation based on neutral axis

  • Rabab, Shanab;Salwa, Mohamed;Mohammed Y., Tharwan;Amr E., Assie;Mohamed A., Eltaher
    • Steel and Composite Structures
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    • v.45 no.5
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    • pp.729-747
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    • 2022
  • The critical buckling loads and buckling modes of bi-directional functionally graded porous unified higher order shear plate with elastic foundation are investigated. A mathematical model based on neutral axis rather than midplane is developed in comprehensive way for the first time in this article. The material constituents form ceramic and metal are graded through thickness and axial direction by the power function distribution. The voids and cavities inside the material are proposed by three different porosity models through the thickness of plate. The constitutive parameters and force resultants are evaluated relative to the neutral axis. Unified higher order shear plate theories are used to satisfy the zero-shear strain/stress at the top and bottom surfaces. The governing equilibrium equations of bi-directional functionally graded porous unified plate (BDFGPUP) are derived by Hamilton's principle. The equilibrium equations in the form of coupled variable coefficients partial differential equations is solved by using numerical differential integral quadrature method (DIQM). The validation of the present model is presented and compared with previous works for bucking. Deviation in buckling loads for both mid-plane and neutral plane are developed and discussed. The numerical results prove that the shear functions, distribution indices, boundary conditions, elastic foundation and porosity type have significant influence on buckling stability of BDFGPUP. The current mathematical model may be used in design and analysis of BDFGPU used in nuclear, mechanical, aerospace, and naval application.

Characterization of Composite Ground Reinforced with Recycled-Aggregate Porous Concrete Pile (RAPP) (순환골재 다공질 콘크리트말뚝(RAPP)에 의해 보강된 복합지반의 거동 특성)

  • You, Seung-Kyong;Kim, Se-Won;Lee, Chul-Ho;Choi, Hang-Seok
    • Journal of the Korean Geotechnical Society
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    • v.25 no.11
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    • pp.117-130
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    • 2009
  • In this paper, a series of laboratory chamber tests were carried out to evaluate the applicability of a porous concrete pile fabricated with recycled aggregates (RAPP) for the soft ground improvement. While performing the laboratory chamber tests for the RAPP, the surface settlement, excess pore pressure and vertical stress distribution with time were compared with those of SCP provided by You (2003) under the same experimental condition. In addition, the experimental results were compared with the numerical simulation using ABAQUS in this study. The results show that the settlement reduction is significantly enhanced due to the stress-sharing mechanism between the RAPP and soil formation by stress concentration on the RAPP. Furthermore, the comparison of consolidation rate shows that the RAPP can accelerate consolidation as well, which behaves as a vertical drain.

Mathematical formulations for static behavior of bi-directional FG porous plates rested on elastic foundation including middle/neutral-surfaces

  • Amr E. Assie;Salwa A. Mohamed;Alaa A. Abdelrahman;Mohamed A. Eltaher
    • Steel and Composite Structures
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    • v.48 no.2
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    • pp.113-130
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    • 2023
  • The present manuscript aims to investigate the deviation between the middle surface (MS) and neutral surface (NS) formulations on the static response of bi-directionally functionally graded (BDFG) porous plate. The higher order shear deformation plate theory with a four variable is exploited to define the displacement field of BDFG plate. The displacement field variables based on both NS and on MS are presented in detail. These relations tend to get and derive a new set of boundary conditions (BCs). The porosity distribution is portrayed by cosine function including three different configurations, center, bottom, and top distributions. The elastic foundation including shear and normal stiffnesses by Winkler-Pasternak model is included. The equilibrium equations based on MS and NS are derived by using Hamilton's principles and expressed by variable coefficient partial differential equations. The numerical differential quadrature method (DQM) is adopted to solve the derived partial differential equations with variable coefficient. Rigidities coefficients and stress resultants for both MS and NS formulations are derived. The mathematical formulation is proved with previous published work. Additional numerical and parametric results are developed to present the influences of modified boundary conditions, NS and MS formulations, gradation parameters, elastic foundations coefficients, porosity type and porosity coefficient on the static response of BDFG porous plate. The following model can be used in design and analysis of BDFG structure used in aerospace, vehicle, dental, bio-structure, civil and nuclear structures.