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http://dx.doi.org/10.46670/JSST.2020.29.4.232

CO Adsorption on Three-Dimensional and Multilayered Platinum Electrode Prepared through Transfer Printing  

Jeong, Yoon-Seo (Electronic Materials and Components Center, Korea Institute of Ceramic Engineering and Technology)
Choi, You-Jeong (Electronic Materials and Components Center, Korea Institute of Ceramic Engineering and Technology)
Shin, Jeong-Hee (Electronic Materials and Components Center, Korea Institute of Ceramic Engineering and Technology)
Jeong, Young-Hun (Electronic Materials and Components Center, Korea Institute of Ceramic Engineering and Technology)
Paik, Jong-Hoo (Electronic Materials and Components Center, Korea Institute of Ceramic Engineering and Technology)
Yoon, Dae-Ho (Department of Advanced Materials Science & Engineering, Sungkyunkwan University)
Cho, Jeong-Ho (Electronic Materials and Components Center, Korea Institute of Ceramic Engineering and Technology)
Publication Information
Journal of Sensor Science and Technology / v.29, no.4, 2020 , pp. 232-236 More about this Journal
Abstract
Three-dimensional (3D) multilayered Pt electrodes were fabricated to develop a porous electrode using a pattern-transfer printing process. The Pt thin films were deposited using a transferred sputtering pattern having a 250 nm line width on the substrate, and the uniform line patterns were efficiently transferred using our proposed method. Temperature-programmed desorption (TPD) analyses were used to evaluate the porosity of the electrodes. It was possible to distinguish between two resolved maxima at 168 and 227 ℃, which could be described in terms of desorption reactions on the Pt (111) planes. The results of the TPD analysis of the 3D and multilayered Pt electrodes prepared through transfer printing were compared to those of an electrode fabricated through screen printing using a commercial Pt-carbon paste commonly used as porous electrodes. It was confirmed that the 3D multilayered electrodes exhibited a desorption concentration approximately 100 times higher than that of the Pt-carbon composite electrode, and the desorption concentration increased by approximately 0.02 mg/mol per layer. The 3D multilayered electrode effectively functions as a porous electrode and a catalyst.
Keywords
Porous Electrode; Gas Sensor; Pt; TPD; Pattern Transfer;
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1 Z. Wang, P. Lin, G.A. Baker, J. Stetter and X. Zeng, "Ionic liquids as electrolytes for the development of a robust amperometric oxygen sensor", Anal. Chem, pp.7066-7073, 2011.   DOI
2 K.I. Tsceng and M.C. Yang, "Platinum electrodes modified by tin for electrochemical CO Sensors", J. Electrochem, Vol 150, No. 7, pp. H156-H160, 2003.   DOI
3 Z. Yin, Z. Sun, J. Wu, R. Liu, S. Zhang, Y. Qian, and Y. Min, "Facile synthesis of hexagonal single-crystalline ZnCo2O4 nanosheet arrays assembled by mesoporous nanosheets as electrodes for high-performance electrochemical capacitors and gas sensors", Appl. Sci. Surf. Vol 457, pp. 1103-1109, 2018.   DOI
4 H.K. Maleh, A. Bananezhad, M.R. Ganjali, P. Norouzi, and A. Sadrnia, "Surface amplification of pencil graphite electrode with polypyrrole and reduced grapheme oxide for fabrication of a guanine/adenine DNA based electrochemical biosensors for determination of didanosine anticancer drug", Appl. Sci. Surf., Vol 441, pp. 55-60, 2018.   DOI
5 M. Bijad, H.K. Maleh, M. Farsi, and S.A. Shahidi, "An electrochemical-amplifed-platform based on the nanostructure voltammetric sensor for the determination of carmoisine in the presence of tartrazine in dried fruit and soft drink samples", J. Food Meas. Charact. Vol. 12, No. 41, pp. 634-640, 2018.   DOI
6 S. Cheraghi, M.A. Taher, and H.K. Maleh, "A sensitive amplified sensor based on improved carbon paste electrode with 1-methyl-3-octylimidazolium tetrafluoroborate and ZnO/CNTs nanocomposite for differential pulse voltammetric analysis of raloxifene", Appl. Sci. Surf., Vol .420, pp. 882-885, 2017.   DOI
7 D.J. Wales, J. Grand, V.P. Ting, R.D. Burke, K.J. Edler, C.R. Bowen, S. Mintova, and A.D. Burrows, "Gas sensing using porous materials for automotive applications", Chem. Soc. Vol. 44, pp. 4290-4321, 2015.   DOI
8 J. Lai, A. Nsabimana, R. Luque, and G. Xu, "3D porous carbonaceous electrodes for electrocatalytic applications", Joule, Vol. 2, No.1, pp. 76-93, 2018.   DOI
9 H. Fukuda, K. Kasama, and S. Nomura, "Highly sensitive MISFET sensors with porous Pt-SnO2 gate electrode for CO gas sensing applications", Sens. Actuators B, Vol. 64, No.1-3, pp. 163-168, 2000.   DOI
10 H. Qian, W. Lu, X. Wei, W. Chen, and J. Deng, "H2S and SO2 adsorption on Pt-MoS2 adsorbent for partial discharge elimination: A DFT study", Results Phys. Vol 12, pp. 107-112, 2019.   DOI
11 W. Chen, J. Luo, L. Meng, J. Li, J. Xiang, J. Li, W. Wang, D. Chen, T. Ye, and C. Zhao, "Atomic layer deposition assisted pattern transfer technology for ultra-thin block copolymer films", Thin Solid Films Vol. 613, No. 31, pp. 32-37, 2016.   DOI
12 H. Wan, H. Yin, L. Lin, X. Zeng, and A.J. Mason, "Miniaturized planar room temperature ionic liquid electrochemical gas sensor for rapid multiple gas pollutants monitoring", Sens. Actuators B, Vol. 255, pp. 638-646, 2018   DOI
13 E.M. Hetrick and M.H. Schoenfisch, "Analytical chemistry of nitric oxide", Annu. Rev. Anal. Vol. 2, pp. 4409-433, 2009.
14 D. Qin, Y. Xia, and G.M. Whitesdies, "Soft lithography for micro- and nanoscale patterning", Nat. Protoc., Vol 5, No.3, pp.491-502, 2010.   DOI
15 L. Zu, J. He, X. Liu, L. Zhang, and K. Zhou, "Effect of pore orientation on the catalytic performance of porous NiMo electrode for hydrogen evolution in alkaline solutions", Int. J. Hydrogen Energy. Vol.44, No.10, pp. 4650-4655, 2019.   DOI
16 McCabe, R. W., and L. D. Schmidt. "Binding states of CO on single crystal planes of Pt." Sci. Surf., Vol. 66, No. 1, pp. 101-124, 1977.   DOI
17 K. Foger, and J. R. Anderson, "Temperature programmed desorption of carbon monoxide adsorbed on supported platinum catalysts", Appl. Sci. Surf., Vol. 2, No.3, pp. 335-351, 1979.   DOI
18 W. L. Winterrottom, "Application of thermal desorption methods in studies of catalysis - I. Chemisorption of carbon monoxide on platinum", Sci. Surf., Vol. 37, No.1, pp. 195-201, 1973.   DOI
19 S. Dey, and G. C. Dhal, "Property and structure of various platinum catalysts for lowtemperature carbon monoxide oxidations", Mater. Today, Vol. 16, pp. 100228(1)-100228(24), 2020.