• 제목/요약/키워드: Pore properties

검색결과 1,424건 처리시간 0.022초

용질배제 곡선에 의한 한외여과 막의 세공특성 예측 (Prediction of Intrinsic Pore Properties of Ultrafiltration Membrane by Solute Rejection Curves)

  • 염경호
    • 한국막학회:학술대회논문집
    • /
    • 한국막학회 1991년도 추계 총회 및 학술발표회
    • /
    • pp.4-8
    • /
    • 1991
  • The characterization of pore properties (mean pore size and pore size distribution) of the active layer in a UF membrane is important not only in order to obtain information about the factors affecting pore formation during membrane manufacturing but also to understand deeply the mechanism of solute and solvent transport through pores. Many methods of characterizing quantitatively the pore properties of UF membranes have been suggested in the literature: solvent and gas flow measurement, bubble point determination, electron microscopy, gas adsorption/desorption measurement, rejection measurement etc. But most of these methods involve time-consuming procedures and involve some wellknown problems and uncertainties.

  • PDF

주요제지원료의 특성 및 고해가 종이의 pore structure 및 물성에 미치는 영향 (Effect of raw materials of the papermaking and physical treatment on the pore structure and properties of the paper)

  • 남기영;정순기;원종명
    • 한국펄프종이공학회:학술대회논문집
    • /
    • 한국펄프종이공학회 2007년도 추계학술발표논문집
    • /
    • pp.127-134
    • /
    • 2007
  • Paper is composed network of fibers. Since paper is plain, most cases paper is considered two-dimensional. But network of fibers creates a network of pores, and pores between fibers are most important part of the paper structure. So we have to make an approach to the paper by three-dimensionally. Pore structure in the Z-direction of the paper can affect directly not only basic properties od the paper such as density, porosity, opacity and strength but also coverage of the coating colors during coatong and printing properties. We studied effect of raw materials of the papermaking and physical treatment on the pore structure and properties of the paper.

  • PDF

활성탄의 표면 구조 변화에 따른 흡착 특성 연구 (Adsorption properties of surface - modified activated carbon)

  • 김정렬;서문원;신창호;김영호;이근회;지상운
    • 한국연초학회지
    • /
    • 제16권2호
    • /
    • pp.191-197
    • /
    • 1994
  • Relationships between surface structure and adsorption properties of smoke components were investigated in surface-modified and un-modified activated carbon filter cigarettes. Commercially available activated carbon was treated with nitric acid and hydrogen peroxide as oxidant, and their pore volume, surface structure, BET surface area, pore type and size were studied. BET surface area and pore volume were decreased by nitric acid treatment, but median pore diameter was 8.1 $\AA$, which showed better development of pore compared with that of un-modified activated carbon, 6.9 $\AA$. In case of hydrogen peroxide treatment, BET surface area and pore volume were increased. Their pore was found to be a slit type based on V-t plot analysis. Neutralization capacities for bases of different strength (NaHCO3, Na2CO3, NaOEt and NaOH) showed that the majority of the acidic surface groups are of weak acidity. Modification of the activated carbon surface led to a slight change in adsorption properties when analyzing the smoke of triple-filter cigarette with surface-modified activated carbon.

  • PDF

Computer Tomography as a Tool for Physical Analysis in an Anthropogenic Soil

  • Chun, Hyen Chung;Park, Chan Won;Sonn, Yeon Kyu;Cho, Hyun Joon;Hyun, Byung Keun;Song, Kwan Cheol;Zhang, Yong Seon
    • 한국토양비료학회지
    • /
    • 제46권6호
    • /
    • pp.549-555
    • /
    • 2013
  • Human influence on soil formation has dramatically increased as the development of human civilization and industry. Increase of anthropogenic soils induced research of those soils; classification, chemical and physical characteristics and plant growth of anthropogenic soils. However there have been no reports on soil pore properties from the anthropogenic soils so far. Therefore the objectives of this study were to test computer tomography (CT) to characterize physical properties of an anthropogenic paddy field soil and to find differences between natural and anthropogenic paddy field soils. Soil samples of a natural paddy field were taken from Ansung, Gyeonggi-do (Ansung site), and samples of an anthropogenic paddy field were from Gumi in Gyeongsangnam-do (Gasan) where paddy fields were remodeled in 2011-2012. Samples were taken at three different depths and analyzed for routine physical properties and CT scans. CT scan provided 3 dimensional images to calculate pore size, length and tortuosity of soil pores. Fractal analysis was applied to quantify pore structure within soil images. The results of measured physical properties (bulk density, porosity) did not show differences across depths and sites, but hardness and water content had differences. These differences repeated within the results of pore morphology. Top soil samples from both sites had greater pore numbers and sizes than others. Fractal analyses showed that top soils had more heterogeneous pore structures than others. The bottom layer of the Gasan site showed more degradation of pore properties than ploughpan and bottom layers from the Ansung site. These results concluded that anthropogenic soils may have more degraded pore properties as depth increases. The remodeled paddy fields may need more fundamental remediation to improve physical conditions. This study suggests that pore analyses using CT can provide important information of physical conditions from anthropogenic soils.

The effect of micro pore on the characteristics of crack tip plastic zone in concrete

  • Haeri, Hadi;Sarfarazi, V.
    • Computers and Concrete
    • /
    • 제17권1호
    • /
    • pp.107-127
    • /
    • 2016
  • Concrete is a heterogeneous material containing many weaknesses such as micro-cracks, pores and grain boundaries. The crack growth mechanism and failure behavior of concrete structures depend on the plastic deformation created by these weaknesses. In this article the non-linear finite element method is used to analyze the effect of presence of micro pore near a crack tip on both of the characteristics of crack tip plastic zone (its shape and size) and crack growth properties (such as crack growth length and crack initiation angle) under pure shear loading. The FE Code Franc2D/L is used to carry out these objectives. The effects of the crack-pore configurations and the spacing between micro pore and pre-excising crack tip on the characteristics of crack tip plastic zone and crack growth properties is highlighted. Based on the obtained results, the relative distance between the crack tip and the micro pore affects in very significant way the shape and the size of the crack tip plastic zone. Furthermore, crack growth length and crack initiation angle are mostly influenced by size and shape of plastic zone ahead of crack tip. Also the effects of pore decrease on the crack tip by variation of pore situation from linear to perpendicular configuration. The critical position for a micro pore is in front of the crack tip.

Effects of the Pore Size of Graphite on the Mechanical Properties and Permeability of a Porous Nozzle for Continuous Casting Process

  • Cho, Yong-Ho;Kim, Juyoung;Yoon, Sanghyeon;Lee, Heesoo
    • 대한금속재료학회지
    • /
    • 제49권7호
    • /
    • pp.530-534
    • /
    • 2011
  • To analyze the effect of the pore size of graphite in a pore-forming agent, graphite was added to porous ceramics of $Al_2O_3-SiO_2-ZrO_2$ systems. The graphite had 45~75, 100~125, 150~180, and 75~180${\mu}m$ dimensions. The properties of the ceramics, such as apparent porosity, density, dynamic elastic modulus, mechanical strength, and permeability, were investigated. The average pore size increased from 15.35${\mu}m$ to 22.32${\mu}m$ with the increase of the graphite size. The sample with the largest average pore size showed the highest mechanical strength and gas permeability. This was due to the sample with the largest pore size at the same porosity having fewer pores and larger distance between the pores than the sample with the smallest pore size, making cracks less likely to propagate. In addition, the large pore size reduced the repulsive power originating from the drag force between the gas and internal pore walls.

수축공극크기분포를 이용한 지반의 수리학적 물성치 산정 (Estimating Hydraulic Properties of Soil from Constriction-pore Size Distribution)

  • 신호성
    • 한국지반공학회논문집
    • /
    • 제38권3호
    • /
    • pp.27-34
    • /
    • 2022
  • 지반내 물의 흐름은 입자 사이의 공극 분포에 의존하므로 입자의 크기를 이용한 수리학적 물성치의 예측은 정확도가 낮다. 본 논문은 Silveria의 방법을 이용하여 입도분포곡선으로부터 수축 공극크기분포를 산정하고, 포화-불포화 수리학적 물성치를 산정하는 방법을 제시하였다. 입도분포가 양호한 흙은 단봉의 공극크기분포를 보이고, 입도분포가 불량한 흙은 쌍봉의 공극크기분포를 보였다. 공극크기분포를 이용한 이론적 포화투수계수 모델식 중에서 Marshall 모델이 실내실험결과와 가장 부합되었다. 불포화토 수리해석에 필요한 함수특성곡선과 불포화투수계수에 대한 모델식을 공극크기분포를 이용하여 제안하였다. 개발된 모델식을 다양한 흙에 적용하여 수리학적 물성치의 예측에 적합한 모델을 선정하는 지속적인 연구가 필요하다.

도공층의 공극과 인쇄적성에 관한 연구(제3보) -라텍스의 특성이 미치는 영향- (Studies on the Pore of Coating Layer and Printability(III) -Effects of Properties of Latices on Pore of Coating Layer-)

  • 이용규;김창근
    • 펄프종이기술
    • /
    • 제33권2호
    • /
    • pp.41-48
    • /
    • 2001
  • This paper was made to evaluate the effect of the type of latex for coating on the printability by investigating the structure of pore such as the pore fraction, the number of pores, pore size and distribution of coated paper. The coated structure is mainly depend on the results of interaction between pigment and binder. It means that the structure of pore formed is chiefly affected by the type of latex. This physical properties of pore have a close relation with ink set-off associated with the drying rate, the speed of penetration of ink into base paper and printing gloss. Therefore it was necessary to find out the relationship between pore structure and the performance of printability by modifying the type of latex to vary the pore structure of coated paper. Acrylic latex was superior to S/B latex in the sedimentation volume, compressibility, smoothness, pore fraction and its number, the weight of transferred ink onto the coated paper and ink repellance. In contrast, water retention and ink setting were not good. in the comparison of anionic and amphoteric latex, amphoteric latex showed better performance in the thickness, smoothness, pore fraction and its number, pore size, the weight of ink transmitted and K&N ink receptivity, etc.

  • PDF

Monte Carlo Simulation on Adsorption Properties of Benzene, Toluene, and p-Xylene in MCM-41

  • Moon, Sung-Doo
    • Bulletin of the Korean Chemical Society
    • /
    • 제33권8호
    • /
    • pp.2553-2559
    • /
    • 2012
  • The adsorption properties of benzene, toluene, p-xylene in MCM-41 with heterogeneous and cylindrical pore were studied using grand canonical ensemble Monte Carlo simulation. The simulated isotherms were compared with experimental ones, and the different adsorption behaviors in MCM-41 with pore diameters of 2.2 and 3.2 nm were investigated. The simulated adsorption amounts above the capillary-condensation pressure agreed with the experimental ones. The simulation results showed that most molecular planes were nearly parallel to the pore axis. This orientation was not affected by the molecular position in the pore. The molecular planes were nearly parallel to the pore surface for the adsorbate molecules close to the pore wall, and the molecules in the MCM-41 with the pore diameter of 3.2 nm were ordered along the pore axis.

Comparison of Soil Pore Properties between Anthropogenic and Natural Paddy Field Soils From Computed Tomographic Images

  • Chun, Hyen Chung;Jung, Ki-Yuol;Choi, Young Dae;Jo, Su-min;Lee, Sanghun;Hyun, Byung-Keun;Shin, Kooksik;Sonn, Yeonkyu;Kang, Hang-Won
    • 한국토양비료학회지
    • /
    • 제48권5호
    • /
    • pp.351-360
    • /
    • 2015
  • Human influence on soil formation has dramatically increased with human civilization and industry development. Increase of anthropogenic soils induced researches on the anthropogenic soils; classification, chemical and physical characteristics of anthropogenic soils and plant growth from anthropogenic soils. However there have been no comprehensive analyses on soil pore or physical properties of anthropogenic soils from 3 dimensional images in Korea. The objectives of this study were to characterize physical properties of anthropogenic paddy field soils by depth and to find differences between natural and anthropogenic paddy field soils. Soil samples were taken from two anthropogenic and natural paddy field soils; anthropogenic (A_c) and natural (N_c) paddy soils with topsoil of coarse texture and anthropogenic (A_f) and natural (N_f) paddy soils with topsoil of fine texture. The anthropogenic paddy fields were reestablished during the Arable Land Remodeling Project from 2011 to 2012 and continued rice farming after the project. Natural paddy fields had no artificial changes or disturbance in soil layers up to 1m depth. Samples were taken at three different depths and analyzed for routine physical properties (texture, bulk density, etc.) and pore properties with computer tomography (CT) scans. The CT scan provided 3 dimensional images at resolution of 0.01 mm to calculate pore radius size, length, and tortuosity of soil pores. Fractal and configuration entropy analyses were applied to quantify pore structure and analyze spatial distribution of pores within soil images. The results of measured physical properties showed no clear trend or significant differences across depths or sites from all samples, except the properties from topsoils. The results of pore morphology and spatial distribution analyses provided detailed information of pores affected by human influences. Pore length and size showed significant decrease in anthropogenic soils. Especially, pores of A_c had great decrease in length compared to N_c. Fractal and entropy analyses showed clear changes of pore distributions across sites. The topsoil layer of A_c showed more degradation of pore structure than that of N_c, while pores of A_f topsoil did not show significant degradation compared with those of N_f. These results concluded that anthropogenic soils with coarse texture may have more effects on pore properties than ones with fine texture. The reestablished paddy fields may need more fundamental remediation to improve physical conditions.