• Title/Summary/Keyword: Polyvinylidene fluoride (PVDF)

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Investigation on lamb wave propagation in silicon wafer using large aperture line-focused transducer (대구경 선집속 탐촉자를 이용한 실리콘 웨이퍼에서의 램파 전파 특성 분석)

  • Chung, Yoonjae;Yang, Seung Soo;Yu, Minjae;Kim, Young H.
    • The Journal of the Acoustical Society of Korea
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    • v.37 no.4
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    • pp.174-180
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    • 2018
  • In this study, the propagation characteristics of Lamb waves in anisotropic silicon wafers of (100) and (111) direction were investigated by PVDF (Polyvinylidene Fluoride) line-focused transducer. The modified V(f,z) method was used because the Lamb waves are dispersive. For confirming the anisotropy, a line-focused transducer was used and the silicon wafer was rotated 180 degrees at intervals of 1 degree. As a result, $A_0$ and $S_0$ modes were observed. The speed of $S_0$ mode according to propagation direction showed anisotropy which is associated with the crystal structure, and the speed of $A_0$ mode was isotropic. The result is consistent with the crystal structure of silicon and the mechanism of vibration of each Lamb wave modes.

Separation of Low Molecular Weight of Dye from Aqueous Solution Using the Prepared Nano-composite Hollow Fiber Membranes (중공사형 나노복합막 제조를 이용한 수용액으로부터 저분자량의 염료 분리 연구)

  • Park, Cheol Oh;Lee, Sung Jae;Rhim, Ji Won
    • Membrane Journal
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    • v.28 no.3
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    • pp.180-186
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    • 2018
  • The nano-composite membranes were prepared onto the polyvinylidene fluoride (PVDF) hollow fiber membranes through twice dip-coating known layer-by-layer method. For the first coating, poly(vinylsulfonic acid, sodium salt)(PVSA) and Poly(styrene sulfonic acid)(PSSA) were used with varying the concentration and ionic strength (IS) and the poly(ethyleneimine)(PEI) as the second coating material was fixed at 10,000 ppm and IS = 0.3. To characterize the prepared nano-composite membranes, the permeabilities and rejection ratio were measured for each 100 ppm NaCl, $CaSO_4$, $MgCl_2$, and 25 ppm MO aqueous solution. The rejections were increased as the concentrations of coating materials increased. And it was confirmed that the salt rejections for PSSA as the coating material were higher than for PVSA. Typically, the permeability, 1.848 LMH and the rejection for MO 76.3% were obtained at the coating conditions of PSSA 30,000 ppm and I.S = 1.0.

Electrical power analysis of piezoelectric energy harvesting circuit using vortex current (와류를 이용한 압전 에너지 수확 회로의 전력 분석)

  • Park, Geon-Min;Lee, Chong-Hyun;Cho, Cheeyoung
    • The Journal of the Acoustical Society of Korea
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    • v.38 no.2
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    • pp.222-230
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    • 2019
  • In this paper, the power of the energy harvesting circuit using the PVDF (Polyvinylidene fluoride) piezoelectric sensor transformed by vortex was analyzed. For power analysis, a general bridge diode rectifier circuit and a P-SSHI (Parallel Synchronized Switch Harvesting on Inductor) rectifier circuit with a switching circuit were used. The P-SSHI circuit is a circuit that incorporates a parallel synchronous switch circuit at the input of a general rectifier circuit to improve energy conversion efficiency. In this paper, the output power of general rectifier circuit and P-SSHI rectifier circuit is analyzed and verified through theory and experiment. It was confirmed that the efficiency was increased by 69 % through the experiment using the wind. In addition, a circuit for storing the harvested energy in the supercapacitor was implemented to confirm its applicability as a secondary battery.

Development of New Stacked Element Piezoelectric Polyvinylidene Fluoride Pressure Sensor for Simultaneous Heartbeat and Respiration Measurements (PVDF 압전소자를 이용한 심장박동 및 호흡수 동시측정센서개발)

  • Park, Chang-Yong;Kweon, Hyun-Kyu;Lee, So-Jin;Manh, Long-Nguyen
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.4
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    • pp.100-108
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    • 2019
  • In this paper, a new stacked element pressure sensor has proposed for heartbeat and respiration measurement. This device can be directly attached to an individual's chest; heartbeat and respiration are detected by the pulsatile vibration and deformation of the chest. A key feature of the device is the simultaneous measurement of heart rate and respiration. The structure of the sensor consists of two stacked elements, in which one element includes one polyvinylidene fluoride (PVDF) thin film bonded on polydimethylsiloxane (PDMS) substrate. In addition, for the measurement and signal processing, the electric circuit and the filter are simply constructed with an OP-amp, resistance, and a capacitor. One element (element1, PDMS) maximizes the respiration signal; the other (element2, PVDF) is used to measure heartbeat. Element1 and element2 had sensitivity of 0.163V/N and 0.209V/N, respectively, and element2 showed improved characteristics compared with element1 in response to force. Thus, element1 and element2 were optimized for measuring respiration heart rate, respectively. Through mechanical and vivo human tests, this sensor shows the great potential to optimize the signals of heartbeat and respiration compared with commercial devices. Moreover, the proposed sensor is flexible, light weight, and low cost. All of these characteristics illustrate an effective piezoelectric pressure sensor for heartbeat and respiration measurements.

Electrical Properties and Self-poling Mechanism of CNT/PVDF Piezoelectric Composite Films Prepared by Spray Coating Method

  • Lee, Sunwoo;Jung, Nak-Chun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.256-256
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    • 2013
  • Carbon nanotubes (CNT) / polyvinylidene fluoride (PVDF) piezoelectric composite films for nanogenerator devices were fabricated by spray coating method. When the CNT/PVDF mixture solution passes through the spray nozzle with small diameter by the compressed nitrogen gas, electric charges are generated in the liquid by a triboelectric effect. Then randomly distributed ${\beta}$ phase PVDF film could be re-oriented by the electric field resulting from the accumulated electrical charges, and might be resulted in extremely one-directionally aligned ${\beta}$ phase PVDF film without additional electric field for poling. X-ray diffraction patterns were used to investigate crystal structure of the CNT/PVDF composite films. It was confirmed that they revealed extremely large portion of the ${\beta}$ phase PVDF crystalline in the film. Therefore we could obtain the poled CNT/PVDF piezoelectric composite films by the spray coating method without additional poling process. Charge accumulation and resulting electric field generation mechanism by spray coating method were shown in Fig. 1. The capacitance of the CNT/PVDF films increased by adding CNTs into the PVDF matrix, and finally saturated. However, the I-V curves didn't show any saturation effect in the CNT concentration range of 0~4 wt%. Therefore we can control the performance of the devices fabricated from the CNT/PVDF composite film by adjusting the current level resulted from the CNT concentration with the uniform capacitance value.

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Performance Analysis of Friction Pendulum System using PVDF/MgO Friction Material (PVDF/MgO 마찰재를 이용한 마찰면진장치의 성능 분석)

  • Kim, Sung-Jo;Kim, Ji-Su;Han, Tong-Seok
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.34 no.4
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    • pp.213-219
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    • 2021
  • Polytetrafluoroethylene (PTFE) is a commercialized friction material in friction pendulum systems used for earthquake hazard mitigation in structures, and it has excellent chemical resistance and frictional performance. However, PTFE has a relatively low wear resistance for the friction pendulum systems in service. As an alternative to PTFE, a cost-effective frictional material, polyvinylidene fluoride (PVDF) strengthened by magnesium oxide (MgO), with enhanced wear resistance performance is proposed in this study. The frictional performance of the developed PVDF/MgO was evaluated through experiments and compared with that of PTFE. Accordingly, a friction pendulum system was designed using the measured friction coefficient. The performance of this friction pendulum system was evaluated via nonlinear time history analyses of bridges. Subsequently, the plausibility of using PVDF/MgO as an alternative to PTFE as a friction material for friction pendulum systems was discussed.

Preparation and Properties of Poly(vinylidene fluoride) Multilayer Films (Poly(vinylidene fluoride) 다층 필름의 제조 및 특성)

  • Son, Tae-Won;Kim, Jong-Hwan;Choi, Won-Mi;Han, Fei-Fei;Kwon, Oh-Kyeong
    • Polymer(Korea)
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    • v.35 no.2
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    • pp.130-135
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    • 2011
  • Along with the fast development of electronics, the demands of portable electronics and wireless sensors are growing rapidly. The need for self-powering materials capable of powering the electrical devices attached to them is increasing, The piezoelectric effect of polyvinylidene fluoride (PVDF) can be used for this purpose. PVDF has a special crystal structure consisting of a ${\beta}$-phase that can produce piezoelectricity. In this paper, multilayer PVDF films were fabricated to increase the ${\beta}$-phase content. A solution of 10% concentration N;N-dimethylacetamide (DMAc) in PVDF (PVDF/DMAc) was used to fabricate the films via spin coating technique with the following optimum process parameters: a spin rate of 850 rpm, spin time of 60 s, drying temperature of $60^{\circ}C$, and drying time of 30 min, Compared with single-layer PVDF films, the multilayer films exhibited higher ${\beta}$-phase content. The ${\beta}$-phase content of the films increased gradually with increasing number of layers until 4, Maximum ratio of ${\beta}$-phase content was 7.72.

Dielectric Characteristic by Phase Transition of Fabricated PVDF thin film through Vapor Deposition Method (진공증착법에 의해 제조된 PVDF 박막의 상변화에 따른 유전특성)

  • 임응춘;박수홍;조기선;이덕출;성낙진
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.05a
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    • pp.150-153
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    • 1996
  • Polyvinylidene fluoride(PVDF) thin films are fabricated by vapor deposition method and their dielectric characteristics are investigated. At electric field near 4MV/m, a phase transition occur with polar ${\alpha}$ . In accordance to increasing temperature, the dielectric relaxation of PVOF thin films show from 70Hz to 104Hz. This result correspond to Debye's theory[1]. Activation energy of PVDP thin film is 21Kca1/mo1.

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Effects of P(MMA-co-MAA) on the Thermal Transitions and Thermo-Dynamic Mechanical Properties of Nylon 6/PVDF Blend (Nylon6/PVDF블렌드의 열전이 및 동적열역학적 거동에 미치는 P(MMA-co-MAA)의 영향)

  • 김갑진;조항원;윤기종
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.265-269
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    • 2001
  • nylon 6의 단점인 저온에서의 연성 및 내충격성 저하를 개선하는 동시에 nylon 6의 내후성도 개선시키는 방법의 하나로 유리전이온도가 매우 낮고, 내가수분해성, 내후성 및 연성(ductile property)이 뛰어난 불소함유 고분자계의 한 종류인 PVDF(polyvinylidene fluoride)를 nylon 6에 용융블렌드 하는 방법이 제안되었다. [1-5] (중략)

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Preparation and characterization of PVDF/TiO2 composite ultrafiltration membranes using mixed solvents

  • Tavakolmoghadam, Maryam;Mohammadi, Toraj;Hemmati, Mahmood
    • Membrane and Water Treatment
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    • v.7 no.5
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    • pp.377-401
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    • 2016
  • To study the effect of titanium dioxide ($TiO_2$) nanoparticles on membrane performance and structure and to explore possible improvement of using mixed solvents in the casting solution, composite polyvinylidene fluoride (PVDF) ultrafiltration membranes were prepared via immersion precipitation method using a mixture of two solvents triethyl phosphate (TEP) and dimethylacetamide (DMAc) and addition of $TiO_2$ nanoparticles. Properties of the neat and composite membranes were characterized using scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), Atomic force microscopy (AFM) and contact angle and membrane porosity measurements. The neat and composite membranes were further investigated in terms of BSA rejection and flux decline in cross flow filtration experiments. Following hydrophilicity improvement of the PVDF membrane by addition of 0.25 wt.% $TiO_2$, (from $70.53^{\circ}$ to $60.5^{\circ}$) degree of flux decline due to irreversible fouling resistance of the composite membrane reduced significantly and the flux recovery ratio (FRR) of 96.85% was obtained. The results showed that using mixed solvents (DMAc/TEP) with lower content of $TiO_2$ nanoparticles (0.25 wt.%) affected the sedimentation rate of nanoparticles and consequently the distribution of nanoparticles in the casting solution and membrane formation which influenced the properties of the ultimate composite membranes.