• Korean Chemical Engineering Research
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• v.49 no.1
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• pp.69-74
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• 2011

In this study, it was prepared for nanofiber with high impact polystyrene(HIPS). HIPS is able to crosslinking after electrospinning with crosslinking agent and it could overcome brittle characteristics of polystyrene(PS). After thermal crosslinking, HIPS nanofiber was sulfonated by sulfuric acid. It was investigated FT-IR, XPS, water uptake, ion exchange capacity(IEC), SEM, and contact angle. According to the result of FT-IR and XPS, it was increased due to introduce the hydrophilic group($SO_3H$) in the HIPS nanofiber. The highest water uptake and IEC were 75.6%, 2.67 meq/ g at 120 min sulfonation time with 7.5 wt% DVB.

• Journal of the Korean Ceramic Society
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• v.48 no.3
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• pp.257-262
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• 2011

Dependencies of dielectric properties on $MgTa_2O_6$, $MgNb_2O_6$, and $MgWO_4$ (Mg-based ceramics) fillers of the polystyrene (PS) matrix composites were investigated as a function of frequency. With increasing frequency from 1 GHz to 7.3 GHz, the dielectric constant (K) of the composites was not changed significantly, while the dielectric loss (tan${\delta}$) of the composites was slightly decreased. The K, tan${\delta}$, and temperature coefficient of resonant frequency (TCF) of the composites were dependent on the type and amount of ceramics at 11 GHz. Also, several theoretical models have been employed to predict the effective dielectric constant of the composites and the results were compared with experimental data. Typically, a K value of 6.67, tan${\delta}$ of $0.56{\times}10^{-3}$, and TCF of -4.99 $ppm/^{\circ}C$ were obtained for the PS composites with 0.4 volume fraction of $MgNb_2O_6$ at 11 GHz.

• Applied Chemistry for Engineering
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• v.20 no.5
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• pp.493-499
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• 2009

The properties of polystyrene and styrenic copolymer nanocomposites containing carbon nanotubes (CNT) and nanoclays were studied. Polystyrene and styrenic copolymer containing styrene and vinylbenzyl trimethylammonium chloride (SVTAC) were synthesized by emulsion polymerization. Polystyrene/CNT/clay and SVTAC/CNT/clay nanocomposites with various concentrations of CNT and different types of clay were prepared via mixing of polystyrene emulsion and clay. SVTAC/CNT nanocomposites showed a better electrical conductivity than PS/CNT nanocomposites. Nanocomposites with more surfactant during polymerization showed a better electrical conductivity than the ones with less surfactant. These indicated the positive effect of comonomer and surfactant on the electrical conductivity. Transmission electron microscopy (TEM) was used to analyze the state of CNT dispersion. TEM results showed that CNT loading, comonomer composition and amount of surfactant affected the final dispersion of CNT in nanocomposites. In order to confirm the effects of CNT loading, comonomer composition and the amount of surfactant on the thermal and dynamic mechanical properties, DSC and DMA analyses were conducted.

• Proceedings of the KAIS Fall Conference
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• 2002.05a
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• pp.130-133
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• 2002

금형온도가 사출 성형품에 미치는 영향 중에 결정성수지인 PP(Polypropylene)와 비결정성수지인 PS(Polysyene)는 금형온도가 높아짐에 따라 각기 다른 결과를 나타내었다. PS성형품은 금형온도가 높을수록 수축율이 줄어들고 두께 편차가 적어지는 경향을 관찰할 수 있었고, PP성형품의 경우에는 결정의 생성으로 인한 상반된 경향이 관찰되었다. 또한, 금형온도에 따른 캐비티의 매끄러운 면과 거친 면의 결과로 볼 때 금형온도가 높을수록 캐비티의 충전성 및 전사성이 향상되었다. MmSH(Momentary Mold Surface Heating)조건인 경우는 수축율과 전사성 모두다 양호한 결과를 보여주었다.

• Bulletin of the Korean Chemical Society
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• v.22 no.11
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• pp.1255-1260
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• 2001

The expansion of two different kinds of hydrodynamic size of polymethyl methacrylate (PMMA Mw: 1.56- 2.04 ${\times}$ 106 g/mol) has been measured by dynamic light scattering and viscometry above the Flory $\theta$ temperature of the variou s solvents such as n-butyl chloride, 3-heptanone, and 4-heptanone. The expansion of PMMA chains was analyzed in terms of universal temperature parameters and also compared with previous results of polystyrene (PS) system. First it was found that simple $\tau/{\tau}c$ parameter no longer had its universality for the expansion behavior of hydrodynamic size in the chemically different linear polymer chains. However after modifying ${\tau}/{\tau}c$ parameter into $(Mw/Ro2)3}2(\tau/\tauc)$, we observed a much better universality for both PMMA and PS systems. Here Mw, Ro, $\tau[=(T-{\theta}$)/${\theta}$]$, and ${\tau}c[=({\theta}-Tc)/Tc]$ are defined as the weight average molecular weight, the unperturbed end-to-end distance, the reduced temperature and the reduced critical temperature, respectively.

• Macromolecular Research
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• v.15 no.1
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• pp.51-58
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• 2007

The approach studied in the present work produced an exfoliated state of clay layers via confinement of the charged nano-sized polystyrene (PS) beads within the gallery of swollen pristine clay. It was demonstrated that adsorption of the polymer nanobeads dramatically promotes expansion of the clay gallery. A comparative study of incorporation was conducted by employing organo-modified clay along with two different colloid polymer systems: electrostatically stabilized PS nanobeads and cationic monomer-grafted PS nanobeads. The mechanism of adsorption of the monomer-grafted polymer beads onto clay via cationic exchange between the alkyl ammonium group of the polymer nanobeads and the interlayer sodium cation of the layered silicate was verified by using several techniques. As distinct from the polymer nanobeads formed using conventional miniemulsion polymerization method, competitive adsorption of stabilizing surfactant molecules was be prevented by grafting the surface functional groups into the polymer chain, thereby supporting the observed effective adsorption of the polymer beads. The presence of surface functional groups that support the establishment of strong polymer-clay interactions was suggested to improve the compatibility of the clay with the polymer matrix and eventually play a crucial role in the performance of the final nanocomposites.

• Macromolecular Research
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• v.15 no.7
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• pp.656-661
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• 2007

The effects of a neutral solvent of dioctyl phthalate (DOP) on the phase behavior of symmetric polystyrene-block-poly(n-butyl methacrylate) copolymers (PS-b-PnBMA) were assessed herein. Closed-loop phase behavior with a lower disorder-to-order transition (LDOT) and an upper order-to-disorder transition (UODT) was observed for PS-b-PnBMA/DOP solution when the quantity of DOP was carefully controlled. When the molecular weight of PS-b-PnBMA became larger, the LDOT did not appreciably change at smaller quantities of DOP. With larger quantities of DOP, the reduction in the UODT is greater than the increase in the LDOT. This behavior is discussed in accordance with a molecular theory predicated on a compressible random-phase approximation.

• Proceedings of the Korean Society of Rheology Conference
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• 2000.05a
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• pp.92-95
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• 2000

• Macromolecular Research
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• v.14 no.2
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• pp.194-198
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• 2006

Polystyrene, PS, particles of 450 nm diameter and poly(styrene-co-styrene sulfonate), PSS, particles of 140-160 nm diameter were prepared by emulsifier-free emulsion polymerization. The surfaces of the PS and PSS particles were coated with Ag nanoparticles for the application of antimicrobial agents by reduction of Ag ions using ${\gamma}$-irradiation. The Ag-PS and Ag-PSS were characterized by High-Resolution Transmittance Electron Microscopy (HR-TEM), Field-Emission Scanning Electron Microscopy (FE-SEM), and Energy Dispersive X-ray Spectroscopy (EDXS). The HR-TEM and EDXS data showed that the Ag nanoparticles were loaded on the surface of the PS and PSS particles, respectively. The antimicrobial efficiency of the Ag-PS and Ag-PSS particles (0.4 g) with ca. 100 ppm Ag, which was coated onto yam (KS K 0905-1996 rule), was tested against Staphylococcus aureus ATCC 6538 and Klebsiella pneumoniae ATCC 4352 after 100 washing cycles (KS K 0432-1999 rule). The antimicrobial efficiency of the Ag-PS particles against Staphylococcus aureus ATCC 6538 and Klebsiella pneumoniae ATCC 4352 was 99.9% after 100 cycles washing., confirming that the Ag-PS particles can be used as antimicrobial agents.

• Resources Recycling
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• v.6 no.2
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• pp.60-69
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• 1997

The paper lists various polymcr materials and lheir usage. It also presents the current stahls and projected estimation of the production of thzse resins and problems associated with these resins. A special section has been dedicated towards the problems associated with and recycle strategies for EPS. It also reviews various technologies treating PS resins.