• Title/Summary/Keyword: Polymethyl methacrylate

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Percutaneous Vertebroplasty in the Treatment of Vertebral Body Compression Fracture with Osteoporosis - Preliminary Report - (골다공증을 동반한 척추체 압박골절에 대한 경피적 척추 성형술 - 예비보고 -)

  • Lee, Sang-Gu;Yoo, Chan-Jong
    • Journal of Korean Neurosurgical Society
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    • v.29 no.5
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    • pp.615-622
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    • 2000
  • Objective : Percutaneous vertebroplasty is an effective and minimally invasive procedure consisting of the injection of a PMMA(polymethyl methacrylate) into the vertebral body compression fracture with osteoporosis. Matherials and Methods : Twenty-eight procedures were performed for vertebral body compression fractures with osteoporosis in 25 patients(22 women, 3 men). The mean age was 65.9 years old. The inclusion criteria for percutaneous vertebroplasty were 1) acute vertebral body compression fracture with osteoporosis, 2) expected high operative morbidity in old age, 3) no neurologic deficits, 4) no or minimal canal enchroachment, 5) patient refusal of invasive surgery. All patients underwent MR images before the procedure. Under local anesthesia, after the percutaneous needle puncture of the involved vertebra via a transpedicular approach and venography using the water soluble contrast material, PMMA injection was introduced into the fractured vertebral body. Results : The procedure was technically successful in all patients. All patients experienced excellent pain relief (complete pain relief ; 10, marked pain relief ; 14). One patient experienced marked pain relief, however, the patient died during the follow-up period due to stomach cancer. There were twelve paravertebral tissue leaks, twelve paravertebral venous plexus leaks, four epidural leaks and one intradiskal leak, but no clinically significant complications occurred in all patients. Conclusion : Percutaneous vertebraoplasty is a valuable procedure in the treatment of vertebral body compression fracture with osteoporosis, providing immediate pain relief and early mobilization. MRI is the most reliable diagnostic tool for identifying painful fractured vertebral body.

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[6,6]- phenyl-C85 Butyric Acid Methyl Ester 나노클러스터를 포함한 Polymethyl Methacrylate 고분자박막으로 제작한 비휘발성 메모리의 소자의 휘어짐에 따른 전기적 특성

  • Lee, Min-Ho;Yun, Dong-Yeol;Son, Jeong-Min;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.338-338
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    • 2012
  • 유기물을 이용하여 제작한 비휘발성 메모리 소자는 저전력으로 구동하고 공정이 간단할 뿐만아니라 구부림이 가능한 소자를 만들 수 있다는 장점 때문에 많은 연구가 진행되고 있다. 비록 다양한 유기물 나노 클러스터를 포함한 고분자 박막을 사용한 비휘발성 메모리 소자에 대한 연구가 많이 진행되었으나 [6,6]- phenyl-C85 butyric acid methyl ester (PCBM) 나노 클러스터가 고분자 박막에 분산되어 있는 메모리 소자의 휘어짐에 따른 전기적 특성의 변화에 대한 것은 연구되지 않았다. 본 연구에서는 스핀코팅 방법으로 PCBM 나노 클러스터가 polymethyl methacrylate (PMMA) 박막에 분산되어 있는 소자를 제작하여 휘어짐에 따른 전기적 특성의 변화에 대한 관찰을 수행하였다. 소자를 제작하기 위해서 PCBM 나노 클러스터와 PMMA를 클로로벤젠에 용해시킨 후에 초음파 교반기를 사용하여 PCBM 나노 클러스터와 PMMA가 고르게 섞인 용액을 형성하였다. 전극이 되는 Indium Tin Oxide (ITO) 유리기판 위에 PCBM 나노 클러스터와 PMMA가 섞인 용액을 스핀 코팅하고, 열을 가해 용매를 제거하여 PCBM 나노 클러스터가 PMMA에 분산되어 있는 박막을 형성하였다. PCBM 나노 클러스터가 분산된 PMMA 박막 위에 Al을 상부전극으로 열증착하여 메모리 소자를 완성하였다. 제작한 소자의 휘어짐에 따른 전기적 특성을 알아보기 위해서 10 mm 의 반지름을 갖는 휘어진 홀더를 제작 한 후에 소자를 구부리기 전과 후의 전류-전압 (I-V)을 각각 측정하였다. 또한 소자의 휘어짐에 따른 포획된 전하유지능력과 안정성을 알아보기 위해 $1{\times}105$번의 반복적인 읽기 전압을 가한 후 전기적 특성을 측정하였다. 실험 결과들을 토대로 메모리 소자의 휘어짐에 따른 전기적 특성 변화에 대해서 분석하고 그 원인에 대해서 규명하였다.

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Characteristics and Risk Assessment of Flame Spreading Over Metal Dust Layers (퇴적금속 분진층을 전파하는 화염의 연소특성과 위험성 평가)

  • Han, Ou-Sup
    • Korean Chemical Engineering Research
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    • v.43 no.1
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    • pp.47-52
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    • 2005
  • The wide use of metal dusts have been found in industrial field and many dust explosion accidents occur by fire spread of dust layer. In this study, we developed a new experimental device to examine fire and explosion characteristics of the dust layer. Aspects of the burning zone over metals(Mg, Zr, Ta, Ti, etc) and PMMA(Polymethyl methacrylate) dust layers have been investigated experimentally to clarify behaviors (Spread rate and quenching distance) and effects of $N_2$ surrounding gas on the fire spread over metal dust layers. From the experimental result, it was found that the spread rate of metal dusts is larger than PMMA, the dependability of spread rate over the thickness of dust layer is small, and the minimum oxygen concentration of spread flame over Mg dust layer is 3.6-3.7 vol%. Since high correlation between the spread rate and the reciprocal of quenching distance was seen, relative risk prediction in those inflammable parameters can be predicted.

Manufacturing of Flexible Patterned Cover Film for Solar Cell by Solution Coating (용액 코팅을 이용한 태양전지용 고분자 유연 패턴필름 제조)

  • Park, Chanwook;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.37 no.5
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    • pp.656-662
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    • 2013
  • The flexible patterned cover film was made by a simple solution coating process using polymethyl methacrylate (PMMA) solution with glass beads. The effect of patterned cover film on the efficiency of solar cell has been investigated. It was found that the relative solar cell efficiency increased up to 3.4% with the incident light angle between $0-90^{\circ}$ by the sphere shape of glass bead coated on the film surface. This was understood that the loss of transmittance and scattering due to the light directional dependency on solar cell were minimized because the light entered glass beads normal to its surface regardless of incident light angle. The maximum relative solar cell efficiency was achieved when glass bead shape on the film is hemisphere and the relative efficiency increased with increasing the amount of glass bead on the film surface. However, too much glass beads on the film surface resulted in the lower relative solar cell efficiency due to the lowering of transmittance as well as the occurring of light interference.

ACCURACY OF THE IMPRESSION TECHNIQUE USING THERMOFORMING POLYMETHYL METHACRYLATE TRAY

  • Miyashita, Yuko;Suzuki, Hiroki;Kishi, Masataka;Ko, Sok-Min
    • The Journal of Korean Academy of Prosthodontics
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    • v.45 no.3
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    • pp.389-400
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    • 2007
  • Statement of problem. Use of the conventional dental impression procedure is problematic in patients who have difficulty opening their mouth, difficulty breathing through their nose or tendency to gag. Purpose. It is necessary to make individual trays more comfortable for patients during impression taking procedure. It was reported at the KAP Annual Meeting 2001 Seoul that an improved impression technique was suitable for this purpose. In this study, the accuracy of the improved dental impression method for implant was compared with the conventional dental impression method. Material and methods. An oral simulator was made from clear acrylic resin block which had similar form of edentulous ridge. For setting up the standard, five fixtures were installed on it. Study casts were made using two kinds of impression techniques. One was the conventional method that was taken using silicone impression material and an individual resin tray under connection of inter-fixture relation. The other was the improved method in which was the connection of the impression coping and the thermoformed polymethyl methacrylate tray. In addition, two different study casts were made from the improved impression body. The coordinates of the fixture on the study model were measured by three-dimensional coordinate measuring equipment. Then the distances between each fixture were calculated and compared with that of oral simulator. Accuracy of the each impression method was also assessed. Results. The differences of inter-fixture dimension between study casts and simulator in the improved impression technique showed $0.014{\pm}0.016mm$ and $0.017{\pm}0.022mm$, respectively and that of the conventional method was $0.017{\pm}0.014mm$. There was no significant difference between the improved impression technique and conventional method. Conclusion. The improved impression technique is useful for multiple support implants.

Mechanical properties by resin injection method of orthdontic acrylic resin (교정용 레진장치의 레진주입방법에 따른 기계적 특성)

  • Jo, Jeong-Ki
    • Journal of Digital Convergence
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    • v.18 no.4
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    • pp.341-346
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    • 2020
  • Polymethyl methacrylate (PMMA), a self-curing resin mainly used in removable orthodontic appliances, is an acrylic resin mainly used in the field of modern dentistry. As an advantage, it has been used for a long time as a material for orthodontic devices in dentistry due to its color and volume, tissue affinity, and stability. The production of PMMA can be divided into self-polymerization method and thermal polymerization method according to activation method. Self-curing resins have long been used as orthodontic devices. The resin injection method is largely divided into a sprinkle-on method and a mixing method. In this study, we intend to test the mechanical properties according to the resin injection method of the orthodontic device, such as strength, modulus of elasticity, and surface roughness. There was no significant difference in strength as a result of three-point bending strength test on rectangular specimens (1.4 × 3.0 × 19.0 mm) of orthodontic PMMA. There was also no significant difference in hardness. There was no significant difference in surface roughness. It was confirmed that the orthodontic PMMA had no significant difference in mechanical properties according to the resin injection method of the orthodontic device.

Characteristics of Resin on Antimicrobial Properties of Calibration Devices. (교정장치의 항균에 따른 레진상의 특성)

  • Jo, Jeong-Ki
    • Journal of Digital Convergence
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    • v.18 no.4
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    • pp.309-314
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    • 2020
  • Polymethyl methacrylate (PMMA) is concerned with promoting oral infection due to its low antibacterial activity. To overcome this, the nanoparticles of Ag-MSN, nGO, and CNP were mixed with MMA liquid in a weight ratio of 0, 0.25, 0.5, 1.0, 2.0% compared to resin powder using Orthocryl from Dentarum, a calibration resin, and then instructed by the manufacturer. Accordingly, a specimen for calibration was prepared by mixing PMMA: MMA (1.2: 1) ratio, and physical properties of the calibration resin, antifungal experiments, and statistical analysis were performed. As a result of antibacterial experiments, the antibacterial properties of Ag-MSN increased. In nGO, the antibacterial adhesive effect increased hydrophilicity, not a change in surface roughness. The higher the CNP concentration, the higher the antibacterial activity. This suggests its potential usefulness as an antibacterial dental material for orthodontic devices and temporary restorations.

Computer modeling to forecast accurate of efficiency parameters of different size of graphene platelet, carbon, and boron nitride nanotubes: A molecular dynamics simulation

  • Farazin, Ashkan;Mohammadimehr, Mehdi
    • Computers and Concrete
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    • v.27 no.2
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    • pp.111-130
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    • 2021
  • In the present work, an extensive study for predicting efficiency parameters (��i) of various simulated nanocomposites including Polymethyl methacrylate (PMMA) as matrix and different structures including various sizes of graphene platelets (GPLs), single, double, and multi-walled carbon nanotubes (SWCNTs-DWCNTs-MWCNTs), and single and double-walled boron nitride nanotubes (SWBNNTs-DWBNNTs) are investigated. It should be stated that GPLs, carbon and boron nitride nanotubes (CNTs, BNNT) with different chiralities (5, 0), (5, 5), (10, 0), and (10, 10) as reinforcements are considered. In this research, molecular dynamics (MDs) method with Materials studio software is applied to examine the mechanical properties (Young's modulus) of simulated nanocomposite boxes and calculate η1 of each nanocomposite boxes. Then, it is noteworthy that by changing length (6.252, 10.584, and 21.173 nm) and width (7.137, 10.515, and 19.936) of GPLs, ��1, ��2, and ��3 approximately becomes (0.101, 0.114, and 0.124), (1.15, 1.22, and 1.26), (1.04, 1.05, and 1.07) respectively. After that efficiency parameters of SWCNTs, DWCNTs, and MWCNTs are calculated and discussed separately. Finally efficiency parameters of SWBNNTs and DWBNNTs with different chiralities by PMMA as matrix are determined by MD and discussed separately. It is known that the accurate efficiency parameters helps a lot to calculate the properties of nanocomposite analytically. In particular, the obtained results from this research can be used for analytical work based on the extended rule of mixture (ERM) in bending, buckling and vibration analysis of structure in future study.

Irreversible Charge Trapping at the Semiconductor/Polymer Interface of Organic Field-Effect Transistors (유기전계효과 트랜지스터의 반도체/고분자절연체 계면에 발생하는 비가역적 전하트래핑에 관한 연구)

  • Im, Jaemin;Choi, Hyun Ho
    • Journal of Adhesion and Interface
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    • v.21 no.4
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    • pp.129-134
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    • 2020
  • Understanding charge trapping at the interface between conjugated semiconductor and polymer dielectric basically gives insight into the development of long-term stable organic field-effect transistors (OFET). Here, the charge transport properties of OFETs using polymer dielectric with various molecular weights (MWs) have been investigated. The conjugated semiconductor, pentacene exhibited morphology and crystallinity, insensitive to MWs of polymethyl methacrylate (PMMA) dielectric. Consequently, transfer curves and field-effect mobilities of as-prepared devices are independent of MWs. Under bias stress in humid environment, however, the drain current decay as well as transfer curve shift are found to increase as the MW of PMMA decreases (MW effect). The charge trapping induced by MW effect is irreversible, that is, the localized charges are difficult to be delocalized. The MW effect is caused by the variation in the density of polymer chain ends in the PMMA: the free volumes at the PMMA chain ends act as charge trap sites, corresponding to drain current decay depending on MWs of PMMA.

Safety and Efficacy of Bone Cement (Spinofill®) for Verte-broplasty in Patients with Osteoporotic Compression Fracture : A Preliminary Prospective Study

  • Park, Han Byeol;Son, Seong;Jung, Jong Myung;Lee, Sang Gu;Yoo, Byung Rhae
    • Journal of Korean Neurosurgical Society
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    • v.65 no.5
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    • pp.730-740
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    • 2022
  • Objective : Although several commercialized bone cements are used during percutaneous vertebroplasty (PVP) for patients with osteoporotic vertebral compression fracture (OVCF), there are no reports using domestic products from South Korea. In this study, we investigated the safety and efficacy of Spinofill® (Injecta Inc., Gunpo, Korea), a new polymethyl methacrylate product. Methods : A prospective, single-center, and single-arm clinical trial of 30 participants who underwent PVP using Spinofill® for painful thoracolumbar OVCF was performed with 6-months follow-up. Clinical and surgical outcomes included the Visual analog scale (VAS), Korean-Oswestry disability index (K-ODI), and Odom's criteria, complication rate, and recurrence rate. Radiological outcomes were evaluated by measuring the findings of postoperative computed tomography and simple radiograph. Results : The pain of VAS (from 8.95±1.05 to 4.65±2.06, p<0.001) and the life quality based on K-ODI (from 33.95±5.84 to 25.65±4.79, p<0.001) improved significantly, and successful patient satisfaction were achieved in 20 patients (66.7%) 1 day after surgery. These immediate improvements were maintained or more improved during the follow-up. There was no surgery- or product-related complications, but OVCF recurred in two patients (6.7%). Favorable cement interdigitation was reported in 24 patients (80.0%), and extra-vertebral cement leakage was reported in 13 patients (43.0%). The mean vertebral height ratio (from 60.49%±21.97% to 80.07%±13.16%, p<0.001) and segmental kyphotic angle (from 11.46°±8.50° to 7.79°±6.08°, p=0.002) improved one day after surgery. However, these short-term radiological findings somewhat regressed at the end. Conclusion : The overall outcomes of PVP using Spinofill® were as favorable as those of other conventionally used products.