• Journal of Information Display
• /
• 제9권2호
• /
• pp.1-4
• /
• 2008

In this study, we investigate the capacitance-voltage (C-V) characteristics of metal-insulator-semiconductor (MIS) capacitors consisting of pentacene, as an organic semiconductor, and polymeric insulators such as poly(4-vinylphenol) (PVP) orpolystyrene (PS) prepared by spin-coating process, to analyze the interfacial characteristics between pentacene and polymeric insulators. Compared with the device with PS, the MIS capacitor with PVP exhibited a pronounced shift in the flat-band voltage according to the bias sweep direction. This hysteric feature in the C-V characteristics is thought to be attributed to the trapped charges at the interface between pentacene and PVP owing to the hydrophilicity of PVP. From the experimental results, we can conclude that surface polarity of polymeric insulator has a critical effect on the interfacial properties, thereby affecting the bias stability of organic thin-film transistors.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2002년도 하계학술대회 논문집
• /
• pp.427-430
• /
• 2002

This paper presents on contamination performance of polymeric outdoor insulator with different contaminant accumulation. The ESDD (equivalent salt deposit density), tracking resistance and clean-fog test were performed to investigate the characteristics of contamination performance on polymeric outdoor insulator. Furthermore, we evaluated together with the porcelain samples for its comparison. It is found that ESDD of polymeric and porcelain insulator depends on the installation position. This surface accumulation of contaminant lead to the loss of surface hydrophobicity, expecially upper shed part of polymeric insulator. In addition, the effect of an artificial contaminant on the tracking resistance by inclined-plane method and leakage suppression ability under clean fog was surveyed. The time of tracking failure did not appear to change significantly with a much contaminant accumulation, while leakage current under clean-fog increased.

• Bulletin of the Korean Chemical Society
• /
• 제34권9호
• /
• pp.2747-2752
• /
• 2013

Surface modification of colloidal silica nanoparticles without disrupting the electric double layer of nanoparticles is a major challenge. In the work, silane was employed to modify colloidal silica nanoparticles without inducing bridge flocculation obviously. The effect of pH value of the silica sol, the amount of silane in feed, and reaction temperature on the graft amount and the final size of modified particles was investigated. The increased weight loss by TG and the appearance of $T_2$ and $T_3$ except for $Q_2$ and $Q_3$ signals by CP/MAS $^{29}Si$ NMR of the modified samples verified the successful grafting of silane. The graft amount reached 0.57 mmol/g, which was slightly lower than theory value, and the particle size remained nearly the same as unmodified particles for acidic silica sol at the optimum condition. For alkaline silica sol after modification, aggregates composed of several nanoparticles connected together with silane moleculars as the bridge appeared.

• 대한전기학회논문지:전기물성ㆍ응용부문C
• /
• 제54권3호
• /
• pp.127-131
• /
• 2005

Big fire such as mountain fire may cause the prevention of the functions of the overhead cables and insulators, which may affect the operation of the transmission lines. In the worst case, this kind of disaster may have a huge effect on the whole industry of a country. However, the study on the effect of the mountain fire on the transmission line is very rare. Therefore, in order to understand the effect of the mountain fire on the polymeric insulator for transmission lines, the author observed the deformation of the sheds of the polymeric insulators and the change of the discs of the porcelain insulators under fire, varying the ignition time using the artificial ignition testing equipment which simulates the mountain fire, and investigated the electrical and mechanical characteristics of the insulators after the ignition test. For the test, the miniature insulators made of polymeric material and porcelain have been utilized. As the result, the following conclusions were obtained. First, the porcelain insulator was degraded in electrical characteristics when the insulator was subjected to the fire for approximately 5 minutes; whereas, the polymeric insulator was not degraded though there were some damage on its sheds. Second, after 20 minute exposure to the fire, the polymeric insulator lost a lot of parts of sheds, but the electrical characteristics was lowered by around $20\%$, but the porcelain insulators were electrically degraded by more than $80\%$.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
• /
• pp.637-640
• /
• 2008

The properties of oriented poly(3-hexylthiophene-2,5-diyl) in field effect transistors (FETs) have been investigated through mechanical stretching process as the original. Silicon-based FETs shown high mobility of $0.02\;cm^2/V$ s after thermal treatment and $0.0092\;cm^2/V$ s at r.t. PET-based FETs were expected to show a similar performance in mobility to that of silicon-based FETs.

• 한국전기전자재료학회:학술대회논문집
• /
• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
• /
• pp.588-591
• /
• 2002

Radiation technology is an effective way for regulating polymeric materials to physicochemical and mechanical properties. The effect of radiation on mechanical and electrochemical properties of new rubber-like polymeric composite materials based on poly(vinyl ether of ethyleneglycol : PVEEG) have been studied for investigating mechanical and electric property of polymer composites applications.

• Bulletin of the Korean Chemical Society
• /
• 제23권10호
• /
• pp.1409-1412
• /
• 2002

Polymeric membrane electrodes for acetate anion based on meso-(${\alpha}$,${\alpha}$,${\alpha}$,${\alpha}$)-5,10,15,20-tetrakis[2-(penta-fluorophenylurea) phenyl]porphyrin I and similar urea-functionalized porphyrins Ⅱ-Ⅳ as neutral ionophores were prepared. The membrane based on porphyrin I exhibits the best potentiometric properties in pH 6.0 rather than pH 7.0: linear stable response over a wide concentration range (6.0 ${\times}$$10^{-5}$-1.0 ${\times}$$10^{-2}$) with a slope of -59.6 mV/decade and a detection limit of log[CH3CO$O^-$] = -5.32. Selectivity coefficients obtained from the matched potential method (MPM) in pH 6.0 indicate that interferences of hydrophobic anions are very small for the membranes of porphyrins I and II having the strong withdrawing group. The electronic effect of urea-functionalized porphyrins and pH effect of buffer solutions are discussed on the potentiometric response.

• 한국세라믹학회지
• /
• 제28권1호
• /
• pp.37-45
• /
• 1991

The critical current density, electrical conductivity, critical magnetic field, Meissner effect, apparent density, and microstructure of YBa2Cu3O7-x ceramic superconductor prepared by polymeric precursor, while varing calcining and sintering conditions, were investigated. The best superconducting properties could be obtained from the body sintered at 93$0^{\circ}C$ for 10h after calcining at 90$0^{\circ}C$ for 10h, which gave 383A/$\textrm{cm}^2$ of critical current density(Jc), 96K of onset temperature(Tonset), 94. 8K of zero temperature (Tzero) 225 Oe of critical magnetic field (Hc1), 72.8% of superconducting volume fraction measured by Meissner effect and 6.28g/㎤ of apparent density.

• Advances in nano research
• /
• 제10권4호
• /
• pp.327-337
• /
• 2021

In this review, composite structures are used for many industries for at least four decades. Polymeric composites are one of the important structures in the aerospace and aviation industry because of their high strength and low weight. In this comprehensive review, mechanical behaviors, physical and mechanical properties of polymeric composites, different types of reinforcements, different methods to fabricate polymeric composites, historical structural composite materials for aviation and aerospace industries, and also different methods for the characterization are reported. How to use various methods of composite preparation using different nanofillers as reinforcements and its effect on the physical properties and mechanical behavior of composites are discussed as well.

• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2002년도 International Meeting on Information Display
• /
• pp.788-791
• /
• 2002

The phosphors of high luminous efficiency for PDP application must have high purity, single phase, and dense surface. In this work, the polymeric reaction was applied to preparation of spherical phosphor by aerosol pyrolysis in order to enhance mechanical and optical characteristics. The red phosphor of (Y,Gd)$BO_3$:Eu was prepared from polymeric precursor, in which citric acid and ethylene glycol were used as ion carriers, i.e monomers. For enhancing the luminescence intensity and mechanical characteristics. optimum synthesizing condition were investigated through concentration of monomers, synthetic temperature. doped activator concentrations, and annealing process. The phosphors synthesized with monomers showed quite different morphology from those without monomers. It was observed that polymeric precursor made an effect on particle formation mechanism and status of particles surface. The resultant spherical phosphors show the comparable luminescent properties to the commercial product (product by Nichia co.). Also, they were observed to have the rigid surface.