• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 1999년도 추계학술발표대회 논문집
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• pp.149-153
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• 1999

During a hemisphere-type compression molding, the wrinkles are caused by complex stress condition. It is very important to clarify the degree of wrinkles in order to have good products. In this paper, the effects of numbers of needling and initial area on the degree of wrinkles are studied. the degree of wrinkle is expressed as nonhomogeneity.

• 대한기계학회논문집A
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• 제32권11호
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• pp.918-923
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• 2008

Since crack detection for laminated composites in-service is effective to improve the structural reliability of laminated composites, it have been tried to detect cracks of laminated composites by various nondestructive methods. An electric potential method is one of the widely used approaches for detection of cracks for carbon fiber composites, since the electric potential method adopts the electric conductive carbon fibers as reinforcements and sensors and the adoption of carbon fibers as sensors does not bring strength reduction induced by embedding sensors into the structures such as optical fibers. However, the application of the electric method is limited only to electrically conductive composite materials. Recently, a piezoelectric method using piezoelectric characteristics of epoxy adhesives has been successfully developed for the adhesive joints because it can monitor continuously the damage of adhesively bonded structures without producing any defects. Polymeric materials for the matrix of composite materials have piezoelectric characteristics similarly to adhesive materials, and the fracture of composite materials should lead to the fracture of polymeric matrix. Therefore, it seems to be valid that the piezoelectric method can be applied to monitoring the damage of composite materials. In this research, therefore, the feasibility study of the damage monitoring for composite materials by piezoelectric method was conducted. Using carbon fiber epoxy composite and glass fiber composite, charge output signals were measured and analyzed during the static and fatigue tests, and the effect of fiber materials on the damage monitoring of composite materials by the piezoelectric method was investigated.

• 대한화학회지
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• 제62권4호
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• pp.269-274
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• 2018

금속산화물 고분자 복합재료전극 제조기법을 수소이온 감응성이 높은 $RuO_2$에 적용하여 표면연마가 가능한 나노 $RuO_2$ 복합재료 pH전극을 제조하였다. $RuO_2$ 함량 53 wt%을 가지는 나노 $RuO_2$ 복합재료 전극의 경우 나노 $IrO_2$ 복합재료 전극과 비슷한 수소이온 감응특성을 나타내었다. pH 1~9의 범위에서 이론치에 가까운 -58.7 mV/pH의 감응기울기, 1초 이하의 감응속도, 평균 $-57.0{\pm}0.3mV/pH$ (n=5)의 표면재생성, 장기 안정성 등 제반 특성과 전기화학적으로 활성이 높은 화학종에 의한 방해효과도 비슷하게 나타났다. 그러나 pH 10 이상의 염기성 용액에서의 감응기울기와 감응속도는 나노 $IrO_2$ 복합재료전극에 비하여 현저히 떨어지는 결과를 보였으며 이는 복합재료 매질 속의 금속산화물 함량에 따른 물리적 성질 차이에 따른 것으로 추측된다.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2000년도 춘계학술발표대회 논문집
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• pp.76-79
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• 2000

Polymeric composites exhibit highly nonlinear and rate dependent behavior during loading and unloading in off-axis directions. The equilibrium state of stress during loading is lower than the state of stress produced at finite strain rates. The amount of stress relaxation during loading decreases. Interestingly, however, the stress goes up to reach to the equilibrium state of stress for a fixed displacement during unloading. The unloading behavior is quite similar to the loading behavior. The stress relaxation patterns during loading and unloading is also similar, and those depend on the fiber orientation angles and the loading and unloading rates. The AS4/PEEK thermoplastic composite is used to characterize the relaxation behavior for different off-axis angles and loading rates. There exists a transient loading region at the beginning of unloading. The effective stress and effective plastic strain concept is used to establish a master curve of stress recovery pattern for different off-axis angles and unloading rates.

• 한국분말재료학회지
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• 제10권5호
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• pp.310-317
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• 2003

Two-component ceramic (alumina-zirconia) composites were fabricated by a soft-solution process in which polyethylene glycol (PEG) was used as a polymeric carrier. Metal salts and PEG were dissolved in ethyl alcohol without any precipitation in 1:1 volume ratio of alumina and zirconia. In the non-aqueous system, the flammable solvent made explosive, exothermic reaction during drying process. The reaction resulted in formation of volume expanded, porous precursor powders by a vigorous decomposition of organic components in the precursor sol. The PEG content affected the grain size of sintered composites as well as the morphology of precursor powders. The difference of microstructure in sintered composite was attribute to the solubility and homogeneity of metal cations in precursor sol. At the optimum amount of the PEG polymer, the metal ions were dispersed effectively in solution and a homogeneous polymeric network was formed. It made less agglomerated particles in the precursor sol and affected on uniform grain size in sintered composite.

• Macromolecular Research
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• 제10권6호
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• pp.345-358
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• 2002

The electrical conductivity during vulcanization process was measured as a function of time for the system of TiC loaded styrene-butadiene rubber (SBR) composites. The phenomenon of negative and positive temperature coefficients of conductivity and its conduction mechanism were also studied for the SBR polymeric composites. The current-voltage characteristics of the polymeric composites were non-linear in high voltage and showed a switching effect. The effects of temperature on the thermal conductivity and effective dielectric constant were measured. The measured parameters were found to be dependent on TiC concentration. The electromagnetic wave shielding (EMS) of the SBR-TiC polymeric composite was also examined. The SBR filled with TiC could be expected to be promising novel smart polymeric composites for self-electrical heating, temperature sensor, time delay switching, and electro-magnetic wave shielding effectiveness.

• 전기화학회지
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• 제9권4호
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• pp.137-140
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• 2006

In order to overcome the weak actuation and relaxation problems during the deformation of IPMC actuator, polymeric anion (polystyrenesulfonate)-doped polypyrrole(Ppy(PSS)) was electrodeposited onto IPMC actuator. Electrochemical quartz crystal microbalance study showed that hydrated cations were instilled into Ppy(PSS) film and polymeric-anion dopants introduced during polymerization were not expelled. Ppy(PSS)-coated IPMC actuator formed two electrode/electrolyte interfaces, Pt/nafion and Ppy(PSS)/bulk solution, and additive volume expansion phenomena at interfaces induced the large deformation compensating the relaxation of actuation by back diffusion of water.

• 대한기계학회논문집
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• 제15권1호
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• pp.163-168
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• 1991

본 연구에서는 여러가지의 성형조건에서 미끄름을 지배하는 상수를 측정하고, 유동 선단(flow front)에 미치는 이 상수의 영향을 검토한다. 또 측정된 상수를 가 지고 사각형 및 중공 원형 평판 압축성형에 대해서 2차원 유한 요소해석을 하고 실험 결과와 비교 검토한다.

• Journal of Microbiology and Biotechnology
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• 제21권1호
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• pp.28-36
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• 2011

Diblock copolymers composed of poly(${\varepsilon}$-caprolactone) (PCL) and poly(N,N-dimethylamino-2-ethyl methacrylate) (PDMAEMA), or methoxy polyethylene glycol(PEG), were synthesized via a combination of ring-opening polymerization and atom-transfer radical polymerization in order to prepare polymeric nanoparticles as an antifungal drug carrier. Amphotericin B (AmB), a natural antibiotic, was incorporated into the polymeric nanoparticles. The physical properties of AmB-incorporated polymeric nanoparticles with PCL-b-PDMAEMA and PCL-b-PEG were studied in relation to morphology and particle size. In the aggregation state study, AmB-incorporated PCL-b- PDMAEMA nanoparticles exhibited a monomeric state pattern of free AmB, whereas AmB-incorporated PCL-b- PEG nanoparticles displayed an aggregated pattern. In in vitro hemolysis tests with human red blood cells, AmBincorporated PCL-b-PDMAEMA nanoparticles were seen to be 10 times less cytotoxic than free AmB (5 ${\mu}g$/ml). In addition, an improved antifungal activity of AmBincorporated polymeric nanoparticles was observed through antifungal activity tests using Candida albicans, whereas polymeric nanoparticles themselves were seen not to affect activity. Finally, in vitro AmB release studies were conducted, proving the potential of AmB-incorporated PCL-b-PDMAEMA nanoparticles as a new formulation candidate for AmB.

• 대한기계학회논문집A
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• 제23권6호
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• pp.1001-1010
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• 1999

Thermo-mechanical behavior of discontinuous shape memory alloy(SMA) reinforced polymeric composite has been studied using modified shear lag theory and finite element(FE) analysis with 2-D multi-fiber model. The aligned and staggered models of short-fiber arrangement are employed. The effects of fiber overlap and aspect ratio on the thermomechanical responses such as the thermal expansion coefficient are investigated. It is found that the increase of both tensile stress(resistance stress) in SMA fiber and compressive stress in polymer matrix with increasing aspect ratio is the main cause of low thermal deformation of the composite.