• 한국환경복원기술학회지
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• 제9권3호
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• pp.17-25
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• 2006

To increase freeze-thaw resistance of porous concrete, this study examined physical properties of polymer by replacing paste used as a binding material with polymer, using unsaturated polyester and epoxy resin, and changing the mixing ratio of polymer. According to the result of this study, when the mixing ratio of resin paste to aggregates was 11 to 16%, voids volume was 33 to 37% and unit weight was about 1620 to 1720kg/$m^3$. In comparison with previous studies using cement paste, voids volume increased by about 7 to 16%, while unit weight decreased by about 100 to 300kg/$m^3$. Compressive strength was 90 to 155kg/$cm^2$ at the age of 7 days, which was 5-40kg/$cm^2$ bigger than porous concrete using cement paste. From a viewpoint of freeze-thaw resistance, it was identified that pluse velocity fell by 0.23km/sec, about 7% of the original velocity, when the cycle of freeze-thaw was repeated 300 times. In spite of 300 repetitions of the cycle, relative dynamic modulus of elasticity was more than 60%, which suggested that its freeze-thaw resistance was more excellent compared with the result that relative dynamic modulus of elasticity of porous concrete using cement paste was 60 % or less under the condition of 80 repetitions of freeze-thaw cycle.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 1999년도 추계학술발표대회 논문집
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• pp.68-72
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• 1999

In an effort to construct a structure under the design principle of minimal use of materials for maximum performances, a discrete gradient structure has been introduced in laminate composite systems. Using a sequential linear programming method, the gradient structure of composites to maximize the buckling load was optimized in terms of fiber volume fraction and thickness of each layer. Theoretical optimization results were then verified with experimental ones. The buckling load of laminate composite showed maximum value with the outmost [$0^{\circ}$] layer concentrated by almost all the fibers when the ratio of length to width(aspect ratio) was less than 1.0. But when the aspect ratio was 2.0, the optimum was determined in a structure where the thickness and fiber volume fraction were well balanced in each layer. From the optimization of gradient structure, the optimal fiber volume fraction and thickness of each layer were proposed. Experimental results agreed well with the theoretical ones. Gradient structures have also shown an advantage in the weight reduction of composites compared with the conventional homogeneous structures.

• Computers and Concrete
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• 제24권5호
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• pp.413-422
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• 2019

In this study, 3D Meso-scale finite-element model is presented to study the mechanical behavior of steel microfiber-reinforced polymer concrete considering the random distribution of fibers in the matrix. The composite comprises two separate parts which are the polymer composite and steel microfibers. The polymer composite is assumed to be homogeneous, which its mechanical properties are measured by performing experimental tests. The steel microfiber-polymer bonding is simulated with the Cohesive Zone Model (CZM) to offer more-realistic assumptions. The CZM parameters are obtained by calibrating the numerical model using the results of the experimental pullout tests on an individual microfiber. The accuracy of the results is validated by comparing the obtained results with the corresponding values attained from testing the steel microfiber-reinforced polymer concrete incorporating 0, 1 and 2% by volume of microfibers, which indicates the excellent accuracy of the current proposed model. The results show that the microfiber aspect ratio has a considerable effect on the mechanical properties of the reinforced polymer concrete. Applying microfibers with a higher aspect ratio improves the mechanical properties of the composite considerably especially when the first crack appears in the polymer concrete specimens.

• 공업화학
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• 제8권6호
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• pp.979-984
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• 1997

폴리머 혼화제로서 styrene-butadiene rubber(SBR)라텍스, ethylene-vinyl acetate(EVA)에멀젼 및 polyacrylic ester(PAE)에멀젼을 사용하여 동일한 스럼프에서 폴리머-시멘트비를 변화시켜 공시체를 제조하여, 압축과 휨강도시험, 흡수시험, 세공분포측정 및 미세구조 관찰 등을 실시하였다. 그 결과 폴리머-시멘트비의 증가와 더불어 압축과 휨강도 모두 향상되었고, 동해에 큰 영향을 주는 모세관 공극범위의 세공량은 감소되었으며, 폴리머 시멘트비 15wt% 이상에서 연속적인 폴리머필름이 형성되었다.

• 한국공작기계학회논문집
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• 제17권3호
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• pp.101-107
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• 2008

A composite mechanics for discontinuous fiber reinforced polymer matrix composites(PMC) is analysed in order to predict fiber axial stresses. In continuum approach. frictional slip which usually takes place between fibers and polymers is accounted to derive PMC equations. The interfacial friction stress is treated by the product of the coefficient of friction and the compressive stress norma1 to the fiber/matrix interface. The residual stress and the Poisson's contraction implemented by the rule of mixture(ROM) are considered for the compressive stress normal to the fiber/matrix interface. In addition. the effects of fiber aspect ratio and fiber volume fraction on fiber axial stresses are evaluated using the derived equations. Results are illustrated numerically using the present equations with reasonable materials data. It is found that the fiber axial stress in the center region shows no great discrepancy for different fiber aspect ratios and fiber volume fractions while some discrepancies are shown in the fiber end region.

• Fibers and Polymers
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• 제7권2호
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• pp.89-94
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• 2006

Ionic conductivity and mechanical properties of a mixed polymer matrix consisting of poly(ethylene glycol) (PEG) and cyanoresin type M (CRM) with various lithium salts and plasticizer were examined. The CRM used was a copolymer of cyanoethyl pullulan and cyanoethyl poly(vinyl alcohol) with a molar ratio of 1:1, mixed plasticizer was ethylene carbonate (EC) and propylene carbonate (PC) at a volume ratio of 1:1. The conductive behavior of polymer electrolytes in the temperature range of $298{\sim}338\;K$ was investigated. The $PEG/LiClO_4$ complexes exhibited the highest ionic conductivity of ${\sim}10^{-5}S/cm$ at $25^{\circ}C$ with the salt concentration of 1.5 M. In addition, the plasticized $PEG/LiClO_4$ complexes exhibited improvement of ionic conductivity. However, their complexes showed decreased mechanical properties. The improvement of ionic conductivity and mechanical properties could be obtained from the polymer electrolytes by using CRM. The highest ionic conductivity of PEG/CRM/$LiClO_4$/(EC-PC) was $5.33{\time}10^{-4}S/cm$ at $25^{\circ}C$.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2007년도 추계 학술논문 발표대회
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• pp.75-78
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• 2007

The steel slag, a by-product which is produced by refining pig iron during the manufacture of steel, is mainly used as road materials after aging. It is necessary to age steel slag for long time in air because the reaction with water and free-CaO in steel slag could make the expansion of volume. This problem prevents steel slag from being used as aggregate for concrete. However, steel slag used in this study was controled by a air-jet method which rapidly cools substance melted at a high temperature. The rapidly-chilled method would prevent from generation of free-CaO in steel slag. Also, Molten steel slag rapidly-chilled by air in high speed becomes a fine aggregate of nearly spherical shape. This study dealt with the influence of the using rate of rapidly-chilled steel slag and polymer resin on fluidity of polymer concrete, as a results Since RCSS has spherical shape and high density, up to replacement ratio of 100%, increases concrete fluidity under same polymer content and decrease polymer content in order to secure the same fluidity

• 한국소음진동공학회논문집
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• 제19권3호
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• pp.301-312
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• 2009

This paper presents a theoretical approach to calculate the resonant frequency of a thickness vibration mode in the radial direction for a 1-3 piezoelectric composite transducer of circular arch shape. For the composite transducer composed of a piezoelectric ceramic and a polymer, vibration parameters were derived according to the volume ratio of a ceramic, and a vibration characteristic equation was derived from the piezoelectric governing equations with adequate boundary conditions. The fundamental resonant frequencies were calculated numerically and verified by comparing them with those obtained from the finite element analysis and the experiment. The volume ratio and the thickness are more substantial than the curvature radius to determine the fundamental resonant characteristics, and the fundamental resonant frequency becomes higher for the larger volume ratio of the piezoelectric ceramic and for the smaller thickness.

• Macromolecular Research
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• 제16권3호
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• pp.247-252
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• 2008

Lithium gel electrolytes based on a mixed polymer matrix consisting of poly(vinylidenefluoride-hexafluoropropylene) (PVDF-HFP) and cyanoresin type M (CRM) were prepared using an in situ blending process. The CRM used in this study was a copolymer of cyanoethyl pullulan and cyanoethyl poly(vinyl alcohol) (PVA) with a mole ratio of 1:1. The mixed plasticizer was ethylene carbonate (EC) and propylene carbonate (PC) with a volume ratio of 1:1. In this study, the presence of PVDF in the electrolytes helps to form a dimensionally stable film over a broad composition range, and decreases the viscosity. In addition, it provides better rheological properties that are suitable for the extrusion of thin films. However, the presence of HFP has a positive effect on generating an amorphous domain in a crystalline PVDF structure. The ionic conductivity of the polymer electrolytes was investigated in the range 298-333 K. The introduction of CRM into the PVDF-HFP/$LiPF_6$, complex produced a PVDF-HFP/CRM/$LiPF_6$ complex with a higher ionic conductivity and improved thermal stability and dynamic mechanical properties than a simple PVDF-HFP/$LiPF_6$, complex.

• 한국세라믹학회지
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• 제31권9호
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• pp.949-956
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• 1994

In order to investigate the relationship between pore size distribution and freezing-thawing resistance of mortars, polymer-cement mortars were prepared by using styrene-butadiene rubber latex, ethylene-vinyl acetate emulsion and polyacrylic ester emulsion with various polymer-cement ratios at constant flow. From the results of the test, polymer-cement mortars had a good pore size distribution for freezing-thawing resistance compared with unmodified mortars because of having a small pore volume in the pore radius range of 103~104 $\AA$ affecting on the frost damage. And the freezing-thawing resistance of polymer-cement mortars was improved with increasing polymer-cement ratio.