• Membrane Journal
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• v.15 no.4
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• pp.281-288
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• 2005

The hyaluronic acid (HA) with excellent biocompatibility can be combined with lactide, the ester dimer of polylactide, with good biodegradability to produce biocompatible materials applicable to drug delivery system. By freeze drying method, HA and lactide were crosslinked with crosslinking agent, 1-ethyl-3-(3-dimethyl aminopropyl) carbodiimide. Degree of lactide and EDC reaction was determined by the analysis of nuclear magnetic resonance (NMR) spectroscopy. The degree of lactide and EDC reaction increased and swelling ratio decreased as the mole ratio of lactide to HA or crosslinking agent concentration increased or reaction temperature decreased. The drug release experiment result from membranes having different degree of lactide reaction showed that drug release rate reduced in proportion to the degree of lactide reaction. The drug release experiment result from drugs having different hyrodphobicity showed that the more hydrophobic drug was released more slowly.

• Membrane Journal
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• v.8 no.4
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• pp.228-234
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• 1998

Among various water contaminents, organic compounds like phenol are difficult to be removed or destroyed by conventional methods under the unusual discharge conditions. The separation of phenol from aqueous solution has been carried out by several methods recently: absorption by an activated carbon, solvent extraction and liquid membrane technology. The liquid membrane based on water-oil emulsification has been tested as an alternative technology of the conventional technology. In this work, tri-n-butyl phosphate(TBP) and liquid polymers were examined as a liquid membrane in the supported liquid membrane(SLM). The feed concentration of phenol was varied and various types of liquid membranes were used to examine their effects on separation of phenol. It was found that TBP, polypropylene glycol 4000(PPG 4000) and polybutytene glycol 500(PBG 500) were proper carriers because mass transfer rates through them were much higher than or similar to that through methyl isobutyl ketone(MIBK) which was used as a conventional solvent in a solvent extraction process.

• Journal of Sensor Science and Technology
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• v.8 no.3
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• pp.247-252
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• 1999

The oxygen electrode of a biosensor needs enzyme immobilized membrane and a dialysis membrane to measure the oxygen concentration that remains after an enzyme reacts with its substrate. Accodingly, a single-layer PVA laminated CTA/PCL membrane was developed as an oxygen biosensor electrode. The enzymes were immobilized on a cellulose triacetate/polycarprolactone membrane using the 1,1'-carbonyl diimidazole(CDI) method, and then laminated with polyvinyl alcohol, aldehyde and acid. The alcohol oxidase and PVA laminated CTA/PCL membrane was tested with various concentration of enzyme substrates using a Yellow Springs Instrument(YSI) oxygen sensor. Under 5-10mmol substrates produced $0.37{\sim}0.83{\mu}A$(r=0.995) currents, and ater 8 weeks the glucose oxidase activity remained at about 56%, while the other activities remained very low. A SEM indicated a smooth surface and tightly attached PVA on the enzyme-immobilized CTA/PCL membranes.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.9
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• pp.6403-6410
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• 2015

Medical polymer PLGA is biocompatible, biodegradation, mechanical characteristic and biostability, and the degradation time can be adjust by controlling the number of monomer. In this paper, PLGA membranes have different composition ratio by L/D type was prepared by phase transition method. And the PLGA membrane in phosphate buffered saline(PBS) at the different test temperatures for different periods of time to examined for change in mass and measured the pH of degradation media. Measurement of Tg and surface structure was performed using a DSC and Stereoscopic microscope. As the molecular weighter increase, hydrolysis rate was decrease in geometrical progression. According to the composition ratio by L/D type, degradation rate and the change of pH are large.

• Membrane Journal
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• v.7 no.3
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• pp.131-135
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• 1997

Polymeric micellar enhanced ultrafiltration method using a new type of polyrmer, $\alpha$-allyl-$\omega$-methoxy polyoxyethlene and maleic anhydride copolymer (AKM-0531, Mw 15, 000), has been proposed to separate 1-naphthylamine as a weak cationic toxic organic solubilizate. Enhancement effect of polymeric micelle was identified by the ultrafiltration runs using polyacryronitrile(PAN) holow fiber membrane with molecular weight cut off 6, 000. The linear dependance of flux on the pressure difference is shown to be valid up to 0.6kg/${cm}^2$ and the rate of flux increase in response to change in the pressure is gradually reduced under the pressure difference. Rejection of 0.96 was observed for f mM of 1-naphthylamine with 2 wt.% polymer solution at the conditions of 0.4kg/${cm}^2$, natural pH. and $25^{\circ}C$ Solubilization of 1-naphthylamine into the polymeric micelle enhanced the separation efficiency.

• Membrane Journal
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• v.22 no.1
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• pp.62-71
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• 2012

In this study, for preparation of gas separation membrane with high permeability, hydroxy polyimide was synthesized using 6FDA and APAF. Synthesis of HPI was confirmed by H-NMR and FT-IR, thermal property of membrane was characterized by Differential scanning calorimetric (DSC) and thermogravimetric analyzer (TGA). Especially, the synthesized HPI can possible to search conversion to PBO at $450^{\circ}C$. To obtain the membrane having high permeability, ternary system consist of polymer, solvent and non-solvent additive was introduced, asymmetric HPI flat sheet membrane was prepared by phase inversion method. Finally, the change of morphology with each component was observed through FE-SEM.

• Membrane Journal
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• v.31 no.5
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• pp.304-314
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• 2021

Climate change results in unusual weather pattern and affects annual rain fall severely. At the same time, growing industrialization leads to higher energy demand and leakage from petrochemical industry and tanker leads to water pollution. In this scenario, finding out solution to generate clean water is highly essential. For oil/water separation, there are several methods available such as chemical precipitation and adsorption but membrane separation technique is considered to be a more cost and energy efficient process. Amphiphilicity nature of membrane are enhanced by making composite membrane with 2D material such as MXene, resulting in good electrical conductivity and hydrophilicity. This review is mainly classified into two sections: pure MXene and modified MXene. A variety of polymer is used to prepare composite membranes and MXene is modified to further enhance the properties suitable for particular applications.

• Journal of the Korean Geosynthetics Society
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• v.17 no.4
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• pp.93-102
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• 2018

A sprayable waterproofing membrane which is composed of polymer-based material is relatively easy to install due to its construction method comparing with sheet-type membranes. And a sprayable waterproofing membrane has very similar material composition to the TSL which is for a permanent support. In this study, material composition of the sprayable waterproofing membrane was changed to enhance structural properties of membrane while maintaining waterproofing performance. In order to compare with a previous research for the TSL, series of tests were performed according to the performance criteria used for permanent support material (TSL) by EFNARC (2008). From the test result, the structural performance of the sprayable waterproofing membrane considered in this study showed a performance that could be used as a permanent support material.

• Membrane Journal
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• v.29 no.3
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• pp.140-146
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• 2019

In this study, a selective layer of poly styrene sulfonic acid (PSSA) and polyethyleneimine (PEI) was formed by layer-by-layer method onto a porous polyacrylonitrile (PAN) hollow fiber membrane as the suppoter membrane. The salting out method was used by adding Mg salt to the coating solution. Several experimental conditions of the ionic strength, polymer concentration, and coating time were investigated, and the flux and rejection were measured at the operating pressure of 2 atm for 100 mg/L of NaCl, $MgCl_2$, and $CaSO_4$ as the feed solution. The membranes coated with PSSA 20,000 ppm, coating time 3 minutes, ionic strength 1.0, PEI 30,000 ppm, coating time 1 minute, and ionic strength 0.1 were observed the best. In the 100 ppm NaCl, $MgCl_2$, and $CaSO_4$ feed solutions, the flux of 20.4, 19.4, and 18.7 LMH, and the rejection of 67, 90, and 66.6%, respectively.

• Membrane Journal
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• v.31 no.4
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• pp.241-252
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• 2021

Rapid industrialization with growing population leads to environmental water pollution. Demand in generation of clean water from waste water is ever increasing by scarcity of rain water due to change in weather pattern. Colorimetric detection of heavy metal present in clean water is very simple and effective technique. In this review membrane based colorimetric detection of mercury (II) ions are discussed in details. Membrane such as cellulose, polycaprolactone, chitosan, polysulfone etc., are used as support for metal ion detection. Nanofiber based materials have wide range of applications in energy, environment and biomedical research. Membranes made up of nanofiber consist up plenty of functional groups available in the polymer along with large surface area and high porosity. As a result, it is easy for surface modification and grafting of ligand on the fiber surface enhanced nanoparticles attachment.