• Title/Summary/Keyword: Polymer electrode

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Effect of Ag Powder Sources on the Patterning of PDP Electrodes

  • Woo, Chang-Min;Kim, Soon-Hak;Hur, Young-June;Kim, Duck-Gon;Song, Gab-Duk;Lee, Yoon-Soo;Cho, Ho-Young;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.953-955
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    • 2006
  • In this work we compared different sources of composition of Ag powders obtained by dry and wet process on the photolithographic patterning of PDP electrode and resistance of sintered Ag electrode. It was found that 90 : 10 wt% ratio of Ag powder made by dry and wet processes gave optimum result both on the PDP electrode pattern and resistance of PDP electrode after sintering.

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Development of EDLC using aqueous polymeric gel electrolytel (수용성 고분자 젤 전해질을 이용한 전기이중층 커패시터의 개발)

  • Oh, Kil-Hun;Kim, Han-Joo;Choi, Weon-Kyung;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.581-584
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    • 2001
  • For the first time, a totally solid state electric double layer capacitor has been fabricated using an alkaline polymer electrolyte and an activated carbon powder as electrode material. The polymer electrolyte serves both as separator as well as electrode binder. The capacitor has a three-layer structure; electrode-electrolyte-electrode. A cyclic voltammetry and constant current discharge have been used for the determination of the electro chemical performance of capacitors.

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Characteristics of Fabricated MEA(Membrane Electrode Assembly) on Polymer Electrolyte Membrane Fuel Cell Made by the Screen Printing Method (스크린 프린팅법을 이용하여 제조된 고분자 전해질 연료전지에서 MEA(조합 막 전극)의 특성)

  • 임재욱;최대규;류호진
    • Journal of the Semiconductor & Display Technology
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    • v.2 no.4
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    • pp.27-30
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    • 2003
  • The effect of fabrication method of catalytic layer on electrode performance has been investigated. Brush, spray gun and screen printer were used as fabrication tool and catalytic layers were formed by several methods in screen printing. Direct screen printing on polymer membrane, screen printing on carbon paper, and their combined method were applied. In the electrode fabricated by the screen printing method, Pt loading of Pt/C catalysts could be cut down to 50%, compared with results by the brushing and spraying methods. The best result of electrode was obtained as 0.6 V, at 1 A/$\textrm{cm}^2$ when catalytic layer was formed by the combined way.

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An Effect of Ethanol on Polypyrrole-Glucose Oxidase Enzyme Electrode (Polypyrrole-Glucose oxidase 효소전극의 Ethanol 첨가효과)

  • 김현철;구할본;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.147-150
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    • 1999
  • In the case of immobilizing of glucose oxidase in organic polymer using electrosynthesis, the glucose oxidase obstructs charge transfer and mass transport during the film growth. This may lead to short chained polymer and/or make charge-coupling weak between the glucose oxidase and the backbone of the polymer. That is mainly due to insulating property and net chain of the glucose oxidase. Since being the case, it is useless to increase in amount of glucose oxidase more than reasonable in the synthetic solution. We establish qualitatively that amount of immobilization can be improved by adding a little ethanol in the synthetic solution. As ethanol was added by 0.1 rnol dm" in the synthetic solution, Michaelis-Menten constants of the resulting enzyme electrode decreased from 30.7 mmol $dm^{-3}$ to about 2 mmol $dm^{-3}$. That suggests increase in affinity of the enzyme electrode for glucose and in amount of the immobilized enzyme.zyme.

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Oligo(EDOT)/PVdF Blend Electrolyte for All Solid Polymer Battery (전 고체 고분자 전지용 Oligo(EDOT)/PVdF 블렌드 전해질)

  • Kim, Min Su;Gwon, Hyeon-Ju;Jo, Nam-Ju
    • Applied Chemistry for Engineering
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    • v.33 no.3
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    • pp.289-295
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    • 2022
  • In this study, we intend to fabricate an all solid polymer battery with a reduced interfacial resistance between the solid electrolyte and the electrode by applying thiophene based polymers as both electrode and electrolyte materials. In order to minimize the interfacial resistance with the poly(3,4-ethylenedioxy thiophene) (PEDOT) based electrode, 3,4-ethylenedioxy thiophene (EDOT) oligomer was introduced into the solid electrolyte. Also, to improve the lithium salt dissociation ability of the EDOT oligomer [oligo(EDOT)] electrolyte, it was blended with poly(vinylidene fluoride) (PVdF). As a result, the ionic conductivity of the solid polymer electrolyte increased by introducing PVdF into the oligo (EDOT). From the result of evaluating the electrochemical properties of an all solid polymer battery, the interfacial resistance significantly decreased by introducing a thiophene based polymer to the electrode and electrolyte.

A Polymer Interface for Varying Electron Transfer Rate with Electrochemically Formed Gold Nanoparticles from Spontaneously Incorporated Tetrachloroaurate(III) Ions

  • Song, Ji-Seon;Kang, Chan
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1683-1688
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    • 2007
  • This paper presents a novel simple method for introducing gold nanoparticles in a poly(4-vinylpyridine) (PVP) polymer layer over a glassy carbon (GC) electrode with the aim of forming a tunable electrochemical interface against a cationic ruthenium complex. Initially, AuCl4 ? ions were spontaneously incorporated into a polymer layer containing positively charged pyridine rings in an acidic media by ion exchange. A negative potential was then applied to electrochemically reduce the incorporated AuCl4 ? ions to gold nanoparticles, which was confirmed by the FE-SEM images. The PVP layer with an appropriate thickness over the electrode blocked electron transfer between the electrode and the solution phase for the redox reactions of the cationic Ru(NH3)6 2+ ions. However, the introduction of gold nanoparticles into the polymer layer recovered the electron transfer. In addition, the electron transfer rate between the two phases could be tuned by controlling the number density of gold nanoparticles.

The Preparation of Polyaniline Electrode Modified by Copper Phthalocyanine on Supporting Carbon Paper

  • Park, Jin-Seok;Kim, Jeong-Soo
    • Macromolecular Research
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    • v.9 no.3
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    • pp.179-183
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    • 2001
  • Cathode materials for the polymer electrolyte membrane fuel cell was prepared by electropoly-merization of aniline at carbon paper in the presence of copper tetrasulfonato-phthalocyanine (CuTsPc) and their electrocatalytic behavior was studied. The amount of polyaniline and CuTsPc in the carbon paper was determined by UV spectroscopy of residual solution in electrochemical cell. The redox process of the prepared electrodes was investigated with cyclic voltammetry. The highest reversible current density was observed at the electrode that contains 27.6 wt% of polyaniline and 19.7 wt% of CuTsPc. The morphology of composite electrode from SEM showed the presence of large cluster of polyaniline with CuTsPc, which should be more finely interpenetrated into macropores of carbon for the better electrocatalytic activity.

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Electrochemical Properties of Novel Metal Powder Electrodes for Polymer Electrolyte Membrane Electrolysis

  • Kim, Chang-Hee;Kang, Kyung-Soo;Park, Chu-Sik;Hwang, Gab-Jin;Bae, Ki-Kwang
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1227-1228
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    • 2006
  • The electrochemical properties of novel metal powders were investigated for the electrode materias of polymer electrolyte memebrane electrolysis. Two types of Pt black and $IrO_2$ powder electrodes were hot-pressed on the polymer electrolyte membrane to form membrane electrode assembly. The galvanodynamic polarization methode was used to characterize the electrochemical properties of both electrodes. From the experimental results, we concluded that the $IrO_2$ powder electrode exhibits better electrochemical performance than Pt black as cathode material for the electrolysis.

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Formation of Copper Electroplated Electrode Patterning Using Screen Printing for Silicon Solar Cell Transparent Electrode (실리콘 태양전지 투명전극용 스크린 프린팅을 이용한 구리 도금 전극 패터닝 형성)

  • Kim, Gyeong Min;Cho, Young Joon;Chang, Hyo Sik
    • Korean Journal of Materials Research
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    • v.29 no.4
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    • pp.228-232
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    • 2019
  • Copper electroplating and electrode patterning using a screen printer are applied instead of lithography for heterostructure with intrinsic thin layer(HIT) silicon solar cells. Samples are patterned on an indium tin oxide(ITO) layer using polymer resist printing. After polymer resist patterning, a Ni seed layer is deposited by sputtering. A Cu electrode is electroplated in a Cu bath consisting of $Cu_2SO_4$ and $H_2SO_4$ at a current density of $10mA/cm^2$. Copper electroplating electrodes using a screen printer are successfully implemented to a line width of about $80{\mu}m$. The contact resistance of the copper electrode is $0.89m{\Omega}{\cdot}cm^2$, measured using the transmission line method(TLM), and the sheet resistance of the copper electrode and ITO are $1{\Omega}/{\square}$ and $40{\Omega}/{\square}$, respectively. In this paper, a screen printer is used to form a solar cell electrode pattern, and a copper electrode is formed by electroplating instead of using a silver electrode to fabricate an efficient solar cell electrode at low cost.