• 한국정보디스플레이학회:학술대회논문집
• /
• 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.II
• /
• pp.823-827
• /
• 2005

Barrier ribs in the plasma display panel (PDP) function to maintain the discharge space between the glass plates as well as to prevent optical crosstalk. Patterning of barrier ribs is one of unique processes for making PDP. Barrier ribs could be formed by screen-printing, sand blasting, etching, and photolithographic process. In this work photosensitive barrier rib pastes were prepared by incorporating binder polymer, solvent, functional monomers photoinitiator, and barrier rib powder of which surface was treated with fumed silica particles. Studies on the function of materials for the barrier rib paste were undertaken. After optimization of paste formulation and photolithographic process, it was applied to the photosensitive barrier rib green sheet and was found that photolithographic patterning of barrier ribs could be formed with good resolution up to $110{\mu}m$ height and $60{\mu}m$ width after sintering.

• 한국도로학회논문집
• /
• 제8권2호
• /
• pp.13-22
• /
• 2006

Surface fog coating methods to porous pavements with a polymer, that contains MMA as a main ingredient, are being widely used in Japan and called 'Top-Coat Processes'. They have lots of effects such as to prevention of the pavement void choking, improvement of the water permeability of the pavements and so on. The purpose of this research is to show the characterization of the polymer to optimize the functions of the polymer fog-coat methods. This study focused on the difference of 'wetting' by water among polymers used for the fog coatings, and calculation the surface free energy from the water contact angle on each material. At the end, the water permeability test were conducted using porous asphalt mixtures that were coated with several kinds of polymers. The permeability was also measured on the specimens that were forcibly choked by muddy water and the resistance to choking was compared. It is concluded that the reduction of the surface free energy between water and a polymer improves the life of the permeability functions of porous pavements. Improvement of water permeation capacity and void-blocking controlling effects can be quantitatively evaluated using the interfacial tension ($\gamma$sl) with water for the coating material (high-viscosity asphalt and hardening resin binder). Consequently, the smaller the $\gamma$sl of the coating material the higher the water permeation capacity and void-blocking controlling effects of the porous asphalt pavements.

• 한국농공학회지
• /
• 제41권5호
• /
• pp.104-105
• /
• 1999

This study was performend to examine Poisson's ration of polymer-modified asphalt concrete due to temperature variatino . Asphalt binder used in this study was an AC85-100, penetration grade of 85-100, and polymer for modifying asphalt were domestic LDPE(Low-density polyethylene) and SBS(Styrene-butadiene-styrene). Aggregate was a crushed gneiss which was most widely used in the middle part of Korea. Using these materias, asphalt mixture slab(340mm$\times$240mm$\times$80mm) with optimum asphalt content from mix design was made and cut into square pillar (80mm$\times$80mm$\times$160mm). Poisson's ration was measured in various temperture (-15$^{\circ}C$, -1$0^{\circ}C$, -5$^{\circ}C$,$0^{\circ}C$,5$^{\circ}C$,1$0^{\circ}C$ and 2$0^{\circ}C$) under the load of one axis repeated compression mode. Poisson's ration of normal asphalt polymer modified asphalt mixtures in normal temperatures. This indicated that AP mixture was more susceptible to temperature effects. From regression aalysis of experimental results, the difference of Poisson's ration between normal and low temperature showed that polymer modified asphalt mixture were lower than AP mixture except for SBS modified asplat mixture.

• Carbon letters
• /
• 제14권2호
• /
• pp.110-116
• /
• 2013

This study investigated a developed process for producing a composite bipolar plate having excellent conductivity by using coal tar pitch and phenol resin as binders. We used a pressing method to prepare a compact of graphite powder mixed with binders. Resistivity of the impregnated compact was observed as heat treatment temperature was increased. It was observed that pore sizes of the GCTP samples increased as the heat treatment temperature increased. There was not a great difference between the flexural strengths of GCTP-IM and CPR-IM as the heat treatment temperature was increased. The resistivity of GPR700-IM, heat treated at $700^{\circ}C$ using phenolic resin as a binder, was $4829{\mu}{\Omega}{\cdot}cm$ which was best value in this study. In addition, it is expected that with the appropriate selection of carbon powder and further optimization of process we can produce a composite bipolar plate which has excellent properties.

• 소성∙가공
• /
• 제12권6호
• /
• pp.521-528
• /
• 2003

Powder injection molding (PIM) uses the shaping advantage of injection molding but is applicable to metals and ceramics. This process combines a small quantity of polymer with an inorganic powder to form a feedstock that can be molded. After shaping, the polymeric binder is extracted and the powder is sintered, often to near-theoretical densities. According1y, PIM delivers structural materials in a shaping technology previously restricted to polymers. The process overcomes the shape limitations of traditional powder compaction, the costs of machining, the productivity limits of isostatic pressing and slip casting, and the defect and tolerance limitations of conventional casting. Since 1980s when major attention was given to PIM process, it has been widening the application area from small parts with complex shape and tailored properties to structural parts requiring strength and ductility as in automotive, military and medical industries.

• 한국광학회:학술대회논문집
• /
• 한국광학회 2006년도 하계학술발표회 논문집
• /
• pp.411-412
• /
• 2006

Photopolymers have been of considerable due to their easy of processing and high sensitivity. Exposure of photopolymers to optical source produce recroding mark where the light initiates a photoreaction that occurs preferentially in regions of high illumination. The photoreaction typically involves polymerization of an acrylic or epoxy monomer dispersed together with a photoinitiators in a polymeric binder. A number of photopolymerizable materials have been developed to apply them in 3D optical recording such as holographic or 3-dimensional data storage. In this presentation, photopolymers derived from sol-gel matrix and transparent polymer binder are summarized. The effect of monomer composition and plasticizers on optical recording will be discussed based on the monomer transport during the photopolymerization.

• 멤브레인
• /
• 제30권1호
• /
• pp.57-65
• /
• 2020

본 연구에서는 고분자 전해질막을 구성하고 있는 고분자 주쇄의 반복단위 개수를 변경해 가며 수화채널 모폴로지와 이온전도도의 변화를 비교하였고, 최종적으로 분자동역학 전산모사 수행 시에 적정한 고분자 모델을 선정하기 위한 기준을 제시하고자 하였다. 고분자 주쇄의 길이가 가장 짧은 모델에서 주쇄 및 술폰산기의 움직임이 커지는 것을 관찰할 수 있었지만, 수화채널 모폴로지는 특별한 상관관계를 발견할 수 없었다. 또한, 수화채널 모폴로지에 가장 큰 영향을 받는 수소이온 전달 능력의 특성 상, 수소이온 전도도에서도 고분자 주쇄의 길이와 큰 상관관계를 보이지는 않았다. 이러한 결과는 특히 바인더용 이오노머 제조에 대한 중요한 정보를 제공한다. 일반적으로 바인더용 이오노머의 경우 고분자 전해질막 소재를 저분자량으로 합성하여 사용하게 되는데, 이때 주쇄/술폰산기의 움직임이 향상되므로 촉매층을 잘 둘러싸는 역할을 할 수 있는 반면에, 수소이온 전달 능력 자체에 있어서는 특별한 변화가 없을 것을 예상할 수 있다. 결론적으로, 바인더용 이오노머 제조시에는 수소이온 전달 성능보다는 물성에 좀 더 초점을 맞추어 분자량 및 구조 설계가 필요할 것이다.

• 공업화학
• /
• 제26권1호
• /
• pp.104-110
• /
• 2015

폴리머 콘크리트는 보통 포틀랜드 시멘트 콘크리트에 비하여 가격이 8~10배 비싼 것으로 알려져 있다. 그러므로 폴리머 콘크리트 제품 생산에 있어서 생산비의 대부분을 차지하는 폴리머 결합재의 사용량을 절감하는 것이 매우 중요하다. 폴리머 결합재의 절감기술을 개발하기 위하여 철강 산업에서 발생되는 제강 산화공정 슬래그와 환원공정 슬래그를 사용하여 아토마이징 공법으로 표면이 매끄러운 구형의 골재를 제조하였다. 폴리머 콘크리트 제조에 일반적으로 사용되는 탄산칼슘(충전재)과 강모래(잔골재) 대신 구형의 아토마이징 산화공정 슬래그와 환원공정 슬래그를 사용하면 최밀 충전효과와 볼베어링 효과로 작업성이 향상되어 폴리머 결합재의 절감효과를 기대할 수 있다. 폴리머 콘크리트 복합재료의 물성을 조사하기 위하여 폴리머 결합재의 첨가율과 아토마이징 제강 환원슬래그의 대체율에 따라 다양한 배합의 폴리머 콘크리트 공시체를 제조하였다. 시험결과, 아토마이징제강 슬래그의 대체율이 증가됨에 따라 공시체의 압축강도는 증가되었으나 휨강도는 폴리머 결합재의 첨가율에 따라 최대값이 다르게 나타났다. 내열수성시험에서 압축강도, 휨강도, 밀도 및 세공의 평균직경은 감소되었으나 총세공량과 공극률은 증가되었다. 탄산칼슘과 강모래대신 구형의 아토마이징 제강 산화슬래그와 아토마이징 제강 환원슬래그를 사용하여 만든 폴리머 콘크리트는 작업성이 현저히 개선되어 종래의 제품보다 폴리머 결합재의 사용량을 19.0% 절감할 수 있는 것으로 나타났다.

• 한국군사과학기술학회지
• /
• 제12권5호
• /
• pp.660-666
• /
• 2009

Thermoplastic polyurethane elastomer(PU-TPE) and energetic thermoplastic polyurethane Elastomer(E-PU-TPE) were prepared from Hexamethylene diisocyanate(HDI), 1,4-BD/AA ester polyol and glycidyl azide polymer(GAP-2400) as an energetic material by the addition polymerization. The PU-TPE and E-PU-TPE were characterized by FT-IR and GPC. Viscometer, DSC and UTM were used to investigate the viscose behavior with a various solvent, thermal properties and mechanical properties of PU-TPE and E-PU-TPE, which are of potential interest for the development of high performance binder of energetic solid propellants. It was found that $M_w$ of PU-TPE and E-PU-TPEs are over 100,000 and decreased with increase of GAP-2400 contents. $T_m$ and ${\Delta}H$ as thermal properties decreased and also tensile strength and elongation at break as mechanical properties decreased with increase of GAP-2400 contents.

• 한국펄프종이공학회:학술대회논문집
• /
• 한국펄프종이공학회 2009년도 추계학술발표회 논문집
• /
• pp.79-84
• /
• 2009

Understanding the polymer adsorption in particle/binder/solvent system is important to achieve successful film products. While most of the reported work has dealt with the suspension microstructure, a few studies have focused on film formation. We investigated the effect of adsorption on film formation through measurement of adsorption amount in suspension and stress development in drying film with respect to mixing time ($t_m$). All of the adsorption amount (PVA), characteristic stress ($\sigma_{ch}$) exhibited similarities expressed by the form of $1-e^{t_m/{\tau}}$. The porous and non-unifonn dried film at short tm became close-packed and uniform with longer $t_m$. We found that polymer adsorption plays the key role in film fonnation as it introduces steric repulsion in suspension and suppresses the flocculation during solvent evaporation. We also found that the mixing time for the saturated polymer adsorption is the important variable to acquire the consolidated and uniform film microstructure.