• 제목/요약/키워드: Polymer Material

검색결과 2,949건 처리시간 0.029초

Mechanical and Biological Characteristics of Reinforced 3D Printing Filament Composites with Agricultural By-product

  • Kim, Hye-Been;Seo, Yu-Ri;Chang, Kyeong-Je;Park, Sang-Bae;Seonwoo, Hoon;Kim, Jin-Woo;Kim, Jangho;Lim, Ki-Taek
    • 산업식품공학
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    • 제21권3호
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    • pp.233-241
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    • 2017
  • Scaffolds of cell substrates are biophysical platforms for cell attachment, proliferation, and differentiation. They ultimately play a leading-edge role in the regeneration of tissues. Recent studies have shown the potential of bioactive scaffolds (i.e., osteo-inductive) through 3D printing. In this study, rice bran-derived biocomposite was fabricated for fused deposition modeling (FDM)-based 3D printing as a potential bone-graft analogue. Rice bran by-product was blended with poly caprolactone (PCL), a synthetic commercial biodegradable polymer. An extruder with extrusion process molding was adopted to manufacture the newly blended "green material." Processing conditions affected the performance of these blends. Bio-filament composite was characterized using field emission scanning electron microscopy (FE-SEM) and energy dispersive X-ray spectroscopy (EDX). Mechanical characterization of bio-filament composite was carried out to determine stress-strain and compressive strength. Biological behaviors of bio-filament composites were also investigated by assessing cell cytotoxicity and water contact angle. EDX results of bio-filament composites indicated the presence of organic compounds. These bio-filament composites were found to have higher tensile strength than conventional PCL filament. They exhibited positive response in cytotoxicity. Biological analysis revealed better compatibility of r-PCL with rice bran. Such rice bran blended bio-filament composite was found to have higher elongation and strength compared to control PCL.

하수슬러지 BIO-SRF (Solid Recovered Fuel) 생산을 위한 NIR (Near Infrared Ray) 건조시 응집제 주입비율이 미치는 영향 (Effect of Flocculant Injection Ratio in NIR (Near-Infrared Ray) Drying for BIO-SRF (Solid Recovered Fuel) of Swage Sludge)

  • 이강민;이승원
    • 한국환경과학회지
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    • 제30권2호
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    • pp.135-143
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    • 2021
  • This study executed evaluation of drying characteristics based on the polymer injection rate (8%, 10% and 12%) and the drying method[NIF(near-infrared ray). According to this study analyzed VS, VS/TS, and calorific value compared with 'the auxiliary fuel standard of the thermoelectric power plant and the combined heat & power plant'. The results are as follows. In the case of NIR, the VS was slightly changed at the early stage of the material preheating period and the constant drying rate period with low moisture evaporation. But VS reduction was shown higher as moisture was dried. In the case of non-digested sludge with high VS content, the VS reduction rate by drying was shown lower than that of digested sludge. As the flocculant injection rate increased, the VS loss due th drying was found to be small. Also, the higher the flocculant injection rate was the longer the drying time. Especially, in the case of the NIR drying equipment, as the moisture content of sewage sludge decreased(moisture content 20~40%), the loss of net VS also showed a tendency to increase sharply. It is shown that the high calorific value according to the drying time of the non-digested sludge was changed from 590 kcaℓ/kg to 3,005 kcaℓ/kg and from 539 kcaℓ/kg to 2,796 kcaℓ/kg.

Optimization and modification of PVDF dual-layer hollow fiber membrane for direct contact membrane distillation; application of response surface methodology and morphology study

  • Bahrami, Mehdi;Karimi-Sabet, Javad;Hatamnejad, Ali;Dastbaz, Abolfazl;Moosavian, Mohammad Ali
    • Korean Journal of Chemical Engineering
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    • 제35권11호
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    • pp.2241-2255
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    • 2018
  • RSM methodology was applied to present mathematical models for the fabrication of polyvinylidene fluoride (PVDF) dual-layer hollow fibers in membrane distillation process. The design of experiments was used to investigate three main parameters in terms of polymer concentration in both outer and inner layers and the flow rate of dope solutions by the Box-Behnken method. According to obtained results, the optimization was done to present the proper membrane with desirable properties. The characteristics of the optimized membrane (named HF-O) suggested by the Box-Behnken (at the predicted point) showed that the proposed models are strongly valid. Then, a morphology study was done to modify the fiber by a combination of three types of a structure such as macro-void, sponge-like and sharp finger-like. It also improved the hydrophobicity of outer surface from 87 to $113^{\circ}$ and the mean pore size of the inner surface from 108.12 to 560.14 nm. The DCMD flux of modified fiber (named HF-M) enhanced 62% more than HF-O when it was fabricated by considering both of RSM and morphology study results. Finally, HF-M was conducted for long-term desalination process up to 100 hr and showed stable flux and wetting resistance during the test. These stepwise approaches are proposed to easily predict the main properties of PVDF dual-layer hollow fibers by valid models and to effectively modify its structure.

Effects of Injection Molding Parameters and their Interactions on Mechanical Properties of PMMA/PC Blend

  • Hoang, Van Thanh;Luu, Duc Binh;Toan Do, Le Hung;Tran, Ngoc Hai;Nguyen, Pham The Nhan;Tran, Minh Sang;Tran, Minh Thong
    • 한국재료학회지
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    • 제30권12호
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    • pp.650-654
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    • 2020
  • A combination of Polycarbonate (PC) material and Polymethylmethacrylate (PMMA), fabricated using an injection molding machine, has been investigated to determine its advantages, as studied in Ref. 1). This paper aims to investigate the optimization of PMMA/PC blend for both tensile yield strength and impact strength. Furthermore, interaction effects of process conditions on mechanical properties including tensile yield strength and impact strength of PMMA/PC blend by injection molding process are interpreted in this study. Tensile and impact specimens are designed following ASTM, type V, and are fabricated by injection molding process. The processing conditions such as melt temperature, mold temperature, packing pressure, and cooling time are applied; each factor has three levels. As a result, in comparison with optimization of separated responses, mechanical properties of PMMA/PC are found to decrease when optimizing both tensile and impact strengths simultaneously. The melt temperature is found to be the most significant interaction parameter with the mold temperature and packing pressure. In addition, there is more interaction between the mold temperature and cooling time. This investigation provides a useful understanding of the control of injection molding processing of polymer blends in optical application.

Vibration analysis of damaged core laminated curved panels with functionally graded sheets and finite length

  • Zhao, Li-Cai;Chen, Shi-Shuenn;Xu, Yi-Peng;Tahouneh, Vahid
    • Steel and Composite Structures
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    • 제38권5호
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    • pp.477-496
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    • 2021
  • The main objective of this paper is to study vibration of sandwich open cylindrical panel with damaged core and FG face sheets based on three-dimensional theory of elasticity. The structures are made of a damaged isotropic core and two external face sheets. These skins are strengthened at the nanoscale level by randomly oriented Carbon nanotubes (CNTs) and are reinforced at the microscale stage by oriented straight fibers. These reinforcing phases are included in a polymer matrix and a three-phase approach based on the Eshelby-Mori-Tanaka scheme and on the Halpin-Tsai approach, which is developed to compute the overall mechanical properties of the composite material. Three complicated equations of motion for the panel under consideration are semi-analytically solved by using 2-D differential quadrature method. Several parametric analyses are carried out to investigate the mechanical behavior of these multi-layered structures depending on the damage features, through-the-thickness distribution and boundary conditions. It is seen that for the large amount of power-law index "P", increasing this parameter does not have significant effect on the non-dimensional natural frequency parameters of the FG sandwich curved panel. Results indicate that by increasing the value of isotropic damage parameter "D" up to the unity (fully damaged core) the frequency would tend to become zero. One can dictate the fiber variation profile through the radial direction of the sandwich panel via the amount of "P", "b" and "c" parameters. It should be noticed that with increase of volume fraction of fibers, the frequency parameter of the panels does not increase necessarily, so by considering suitable amounts of power-law index "P" and the parameters "b" and "c", one can get dynamic characteristics similar or better than the isotropic limit case for laminated FG curved panels.

Seismic response of NFRP reinforced RC frame with shape memory alloy components

  • Varkani, Mohamad Motalebi;Bidgoli, Mahmood Rabani;Mazaheri, Hamid
    • Advances in nano research
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    • 제13권3호
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    • pp.285-295
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    • 2022
  • Creation of plastic deformation under seismic loads, is one of the most serious subjects in RC structures with steel bars which reduces the life threatening risks and increases dissipation of energy. Shape memory alloy (SMA) is one of the best choice for the relocating plastic hinges. In a challenge to study the seismic response of concrete moment resisting frame (MRF), this article investigates numerically a new type of concrete frames with nano fiber reinforced polymer (NFRP) and shape memory alloy (SMA) hinges, simultaneously. The NFRP layer is containing carbon nanofibers with agglomeration based on Mori-Tanaka model. The tangential shear deformation (TASDT) is applied for modelling of the structure and the continuity boundary conditions are used for coupling of the motion equations. In SMA connections between beam and columns, since there is phase transformation, hence, the motion equations of the structure are coupled with kinetic equations of phase transformation. The Hernandez-Lagoudas theory is applied for demonstrating of pseudoelastic characteristics of SMA. The corresponding motion equations are solved by differential cubature (DC) and Newmark methods in order to obtain the peak ground acceleration (PGA) and residual drift ratio for MRF-2%. The main impact of this paper is to present the influences of the volume percent and agglomeration of nanofibers, thickness and length of the concrete frame, SMA material and NFRP layer on the PGA and drift ratio. The numerical results revealed that the with increasing the volume percent of nanofibers, the PGA is enhanced and the residual drift ratio is reduced. It is also worth to mention that PGA of concrete frame with NFRP layer containing 2% nanofibers is approximately equal to the concrete frame with steel bars.

다양한 식물에서의 PDRN(Polydeoxyribonucleotide) 추출 수율 비교 및 상처치유 효능 분석 (Efficiency of PDNR (Polydeoxyribonucleotide) extraction from various plant species and its in vitro wound healing activity)

  • 송미희;최문혁;정진형;이상식;정우영
    • 한국정보전자통신기술학회논문지
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    • 제15권5호
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    • pp.387-395
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    • 2022
  • PDRN(Polydeoxyribonucleotide)은 조직재생 활성물질로 손상된 세포 및 조직의 자가 재생을 촉진하는 DNA 유래의 중합물질이다. PDRN은 DNA를 다양한 물리적 또는 화학적 방법으로 작은 크기로 절단한 DNA 조각으로 체내 투여시 조직세포 표면의 adenosine A2A receptor 수용체를 자극하여 세포 재생을 촉진하며 상처를 빠르게 회복시키고, 통증도 감소시키는 효과가 있다. 보통 어류의 정소나 정액으로부터 PDRN 추출을 하지만 본 연구에서는 다양한 식물에서 PDRN 추출 실험을 진행하였다. 실험 결과, 7종의 식물에서 PDRN 수율과 순수도는 단위 식물 중량 당 쑥갓이 가장 높았고, 브로콜리가 그 다음으로 우수했다. 이 두 식물의 PDRN을 대상으로 시험관에서 wound healing assay를 진행하여 PDRN의 효능을 분석한 결과, ㎍/ml 수준의 쑥갓과 브로콜리의 PDRN가 유의하게 wound healing 활성이 높음을 확인하였다. 본 연구의 결과는 이들 식물 유래 PDRN이 연어와 같은 어류 유래의 PDRN의 대체제로 사용할 수 있음을 의미한다.

리튬이온전지 실리콘계 음극 바인더 소재 개발 (Development of Binder Materials for Si-based Anode in Lithium-ion Batteries)

  • 윤지희;유정근
    • Composites Research
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    • 제35권6호
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    • pp.365-370
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    • 2022
  • 전기자동차 및 E-모빌리티 시장이 급속히 성장함에 따라 리튬이온전지는 현재 가장 주목받는 기술 중 하나로 여겨지고 있다. 따라서 높은 용량 및 출력, 급속 충전 성능을 가지는 고에너지밀도 전극 개발이 매우 중요한 상황이다. 고에너지밀도 전극 구현을 위해서 음극의 경우 실리콘, 주석 등 고용량 활물질 소재에 대한 연구가 진행되고 있는 상황이다. 하지만 이러한 고용량 활물질 소재는 전지의 충방전 과정 시 발생하는 부피팽창이 전지의 성능을 저하시키는 주된 원인이 된다고 알려져 있다. 따라서 활물질의 부피팽창을 완화할 수 있는 바인더 소재 개발이 매우 중요한 상황이며, 기존 PVDF, CMC/SBR계 바인더 뿐만 아니라 수용성 고분자(polyacrylic acid, polyvinyl alcohol, aliginate 등)를 이용한 바인더 소재 개발 연구가 많이 보고되고 있다. 이처럼 앞으로 리튬이온전지의 고성능화를 위해서 바인더는 매우 중요한 기술이 되었으며, 본 논문에서는 리튬이온전지용 음극 바인더 소재의 연구 동향을 살펴보고자 한다.

효모를 사용한 한지직물의 천연인디고 염색 : 효모농도와 반복염색 효과 (Natural Indigo Dyeing of Hanji Fabric using Baker's Yeast: Effect of Yeast Concentration and Repeat Dyeing)

  • 손경희;신윤숙;류동일
    • 한국염색가공학회지
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    • 제33권4호
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    • pp.191-201
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    • 2021
  • In this study, an eco-friendly indigo reduction system(scale up reduction, use of buffer solution, and pH control) using baker's yeast(Saccharomyces cerevisiae) was applied for natural indigo(Polygonum tinctorium) dyeing of Hanji fabric and Hanji-mixture fabric(Hanji/Cotton, Hanji/Silk). The effect of concentration of baker's yeast, repeat dyeing, and bath reuse was investigated in terms of dye uptake indicating reduction power. And the oxidation-reduction potential(ORP) was monitored. We also evaluated color properties and colorfastness according to the color strength. The yeast concentration did not significantly affect the maximum reduction power. However, the highest yeast concentration was effective in improving the initial dye uptake, and its the reduction retention power was the most excellent. Even on the last reduction day, the effect of increasing the dye uptake by repeat dyeing was observed. And it was confirmed that the reduction bath could be reused for up to 30 days by supplementing yeast at the end of reduction. For all the fabrics used, deeper and darker PB color were obtained by repeat dyeing. As dyeing was repeated, purplish tint got stronger on the Hanji/Silk fabric compared to other fabrics. Regardless of the composition of Hanji fabrics and color strength, washing and dry cleaning fastness were relatively good with above rating 4-5, and fastness to rubbing and light were acceptable with a rating 3-4 ~ 4-5. The eco-friendly natural indigo dyeing process using niram and baker's yeast would offer global marketability and diversity of Hanji product as a sustainable high value-added material.

마이크로스트립 패치 안테나를 이용한 습도 센서 (Humidity Sensor Using Microstrip Patch Antenna)

  • 여준호
    • 한국항행학회논문지
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    • 제27권1호
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    • pp.71-76
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    • 2023
  • 본 논문에서는 마이크로스트립 패치 안테나와 폴리비닐알코올(PVA; polyvinyl alcohol)을 이용한 습도 센서에 대하여 연구하였다. PVA는 습도에 따라 유전율이 변하는 고분자 물질이며, 전계 변화에 민감한 마이크로스트립 패치 안테나의 방사면에 직사각형 슬롯을 추가하여 비유전율 변화에 대한 감도를 높였다. 0.76 mm 두께의 RF-35 기판에 제작된 안테나의 직사각형 슬롯이 추가된 방사면 주변을 PVA로 얇게 코팅한 후, 온습도 챔버를 사용하여 25도에서 상대습도를 40%에서 80%까지 10% 간격으로 증가시켜 안테나 입력 반사 계수의 공진 주파수와 크기의 변화를 측정하였다. 실험 결과, 상대습도가 40%에서 80%로 증가할 때 안테나 입력 반사 계수의 공진 주파수는 2.447 GHz에서 2.418 GHz로 감소하였고, 입력 반사 계수의 크기는 -7.112 dB에서 -3.428 dB로 증가하였다.