Browse > Article
http://dx.doi.org/10.7234/composres.2022.35.6.365

Development of Binder Materials for Si-based Anode in Lithium-ion Batteries  

Jihee, Yoon (Composites Research Division, Korea Institute of Materials Science (KIMS))
Jung-Keun, Yoo (Composites Research Division, Korea Institute of Materials Science (KIMS))
Publication Information
Composites Research / v.35, no.6, 2022 , pp. 365-370 More about this Journal
Abstract
According to the rapid growth of electric vehicle (EVs) and E-mobility market, Li-ion batteries are one of the most progressive technologies. The demand of LIBs with high energy capacity, rate performance and fast charging is continuously increasing, hence high-performance LIBs should be developed. Si is considered as the most promising anode material to improve energy density because of its high theoretical capacity. However, Si suffers large volume chances during the charging and discharge process, leading to the fast degradation of cycle performance. Therefore, polymeric binders play a key role in electrochemical performance of Si anode by efficiently enduring the Si expansion and maintaining the binding networks in electrode. In this review, we explain the role of polymeric binders in electrode and introduce the anode binders with enhanced mechanical and chemical properties which can improve electrochemical performances of Si-based anode.
Keywords
LIBs; Si anode; Binder; Water soluble polymer;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Magasinski, A., Zdyrko, B., Kovalenko, I., Hertzberg, B., Burtovyy, R., Huebner, C.F., Fuller, T.F., Luzinov, I., and Yushin, G., "Toward Efficient Binders for Li-Ion Battery Si-Based Anodes: Polyacrylic Acid," ACS Applied Materials & Interfaces, Vol. 2, No. 11, 2010, pp. 3004-3010.   DOI
2 Koo, B., Kim, H., Cho, Y., Lee, K.T., Choi, N.-S., and Cho, J., "A Highly Cross-Linked Polymeric Binder for High-Performance Silicon Negative Electrodes in Lithium Ion Batteries," Angewandte Chemie International Edition, Vol. 51, No. 35, 2012, pp. 8762-8767.   DOI
3 Jeena, M.T., Lee, J.-I., Kim, S.H., Kim, C., Kim, J.-Y., Park, S., and Ryu, J.-H., "Multifunctional Molecular Design as an Efficient Polymeric Binder for Silicon Anodes in Lithium-Ion Batteries," ACS Applied Materials & Interfaces, Vol. 6, No. 20, 2014, pp. 18001-18007.   DOI
4 Choi, S., Kwon, T.-W., Coskun, A., and Choi, J.W., "Highly Elastic Binders Integrating Polyrotaxanes for Silicon Microparticle Anodes in Lithium Ion Batteries," Science, Vol. 357, No. 6348, 2017, pp. 279-283.   DOI
5 Park, Y., Lee, S., Kim, S.-H., Jang, B.Y., Kim, J.S., Oh, S.M., Kim, J.-Y., Choi, N.-S., Lee, K.T., and Kim, B.-S., "A Photo-crosslinkable Polymeric Binder for Silicon Anodes in Lithium Ion Batteries," RSC Advances, Vol. 3, No. 31, 2013, pp. 12625-12630.   DOI
6 Wu, Z.-H., Yang, J.-Y., Yu, B., Shi, B.-M., Zhao, C.-R., and Yu, Z.-L., "Self-healing Alginate-carboxymethyl Chitosan Porous Scaffold as an Effective Binder for Silicon Anodes in Lithiumion Batteries," Rare Metals, Vol. 38, No. 9, 2019, pp. 832-839.   DOI
7 Kovalenko, I., Zdyrko, B., Magasinski, A., Hertzberg, B., Milicev, Z., Burtovyy, R., Luzinov, I., and Yushin, G., "A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries," Science, Vol. 334, No. 6052, 2011, pp. 75-79.   DOI
8 Yoon, J., Oh, D. X., Jo, C., Lee, J., and Hwang, D.S., "Improvement of Desolvation and Resilience of Alginate Binders for Sibased Anodes in a Lithium Ion Battery by Calcium-mediated Cross-linking," Physical Chemistry Chemical Physics, Vol. 16, No. 46, 2014, pp. 25628-25635.   DOI
9 Wang, S.-F., Shen, L., Zhang, W.-D., and Tong, Y.-J., "Preparation and Mechanical Properties of Chitosan/Carbon Nanotubes Composites," Biomacromolecules, Vol. 6, No. 6, 2005, pp. 3067-3072.   DOI
10 Ling, M., Xu, Y., Zhao, H., Gu, X., Qiu, J., Li, S., Wu, M., Song, X., Yan, C., Liu, G., and Zhang, S., "Dual-functional Gum Arabic Binder for Silicon Anodes in Lithium Ion Batteries," Nano Energy, Vol. 12, 2015, pp. 178-185.
11 Zubi, G., Dufo-Lopez, R., Carvalho, M., and Pasaoglu, G., "The Lithium-ion Battery: State of the Art and Future Perspectives," Renewable and Sustainable Energy Reviews, Vol. 89, 2018, pp. 292-308.   DOI
12 Lingappan, N., Kong, L., and Pecht, M., "The Significance of Aqueous Binders in Lithium-ion Batteries," Renewable and Sustainable Energy Reviews, Vol. 147, 2021, 111227.
13 Ko, M., Chae, S., and Cho, J., "Challenges in Accommodating Volume Change of Si Anodes for Li-Ion Batteries," ChemElectroChem, Vol. 2, No. 11, 2015, pp. 1645-1651.   DOI
14 Choi, J.W., and Aurbach, D., "Promise and Reality of Post-lithium-ion Batteries with High Energy Densities," Nature Reviews Materials, Vol. 1, No. 4, 2016, 16013.
15 Pejovnik, S., Dominko, R., Bele, M., Gaberscek, M., and Jamnik, J., "Electrochemical Binding and Wiring in Battery Materials," Journal of Power Sources, Vol. 184, No. 2, 2008, pp. 593-597.   DOI
16 Goodenough, J.B., and Park, K.-S., "The Li-Ion Rechargeable Battery: A Perspective," Journal of the American Chemical Society, Vol. 135, No. 4, 2013, pp. 1167-1176.   DOI
17 Buqa, H., Holzapfel, M., Krumeich, F., Veit, C., and Novak, P., "Study of Styrene Butadiene Rubber and Sodium Methyl Cellulose as Binder for Negative Electrodes in Lithium-ion Batteries," Journal of Power Sources, Vol. 161, No. 1, 2006, pp. 617-622.   DOI
18 Kim, J.S., Choi, W., Cho, K.Y., Byun, D., Lim, J., and Lee, J.K., "Effect of Polyimide Binder on Electrochemical Characteristics of Surface-modified Silicon Anode for Lithium Ion Batteries," Journal of Power Sources, Vol. 244, 2013, pp. 521-526.   DOI
19 Wang, R., Feng, L., Yang, W., Zhang, Y., Zhang, Y., Bai, W., Liu, B., Zhang, W., Chuan, Y., Zheng, Z., and Guan, H., "Effect of Different Binders on the Electrochemical Performance of Metal Oxide Anode for Lithium-Ion Batteries," Nanoscale Research Letters, Vol. 12, No. 1, 2017, p. 575.
20 Park, H.-K., Kong, B.-S., and Oh, E.-S., "Effect of High Adhesive Polyvinyl Alcohol Binder on the Anodes of Lithium Ion Batteries," Electrochemistry Communications, Vol. 13, No. 10, 2011, pp. 1051-1053.   DOI
21 Song, J., Zhou, M., Yi, R., Xu, T., Gordin, M.L., Tang, D., Yu, Z., Regula, M., and Wang, D., "Interpenetrated Gel Polymer Binder for High-Performance Silicon Anodes in Lithium-ion Batteries," Advanced Functional Materials, Vol. 24, No. 37, 2014, pp. 5904-5910.   DOI