• 제목/요약/키워드: Polymer Material

검색결과 2,972건 처리시간 0.036초

자기 조립 반응에 의한 그래핀이 코팅된 알루미늄 입자의 합성 방법 (Synthesis of Graphene Coated Aluminum Powders by Self-assemble Reaction)

  • 황진욱;탁우성;남상용;김우식
    • 한국분말재료학회지
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    • 제26권5호
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    • pp.383-388
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    • 2019
  • To improve the mechanical properties of aluminum, graphene has been used as a reinforcing material, yielding graphene-reinforced aluminum matrix composites (GRAMCs). Dispersion of graphene materials is an important factor that affects the properties of GRAMCs, which are mainly manufactured by mechanical mixing methods such as ball milling. However, the use of only mechanical mixing process is limited to achieve homogeneous dispersion of graphene. To overcome this problem, in this study, we have prepared composite materials by coating aluminum particles with graphene by a self-assembly reaction using poly vinylalcohol and ethylene diamine as coupling agents. The scanning electron microscopy and Fourier-transform infrared spectroscopy results confirm the coating of graphene on the Al surface. Bulk density of the sintered composites by spark plasma sintering achieved a relative density of over 99% up to 0.5 wt.% graphene oxide content.

Analysis of rectangular hybrid steel-GFRP reinforced concrete beam columns

  • El-Heloua, Rafic G.;Aboutaha, Riyad S.
    • Computers and Concrete
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    • 제16권2호
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    • pp.245-260
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    • 2015
  • In this study, nominal moment-axial load interaction diagrams, moment-curvature relationships, and ductility of rectangular hybrid beam-column concrete sections are analyzed using the modified Hognestad concrete model. The hybrid columns are primarily reinforced with steel bars with additional Glass Fiber Reinforced Polymer (GFRP) control bars. Parameters investigated include amount, pattern, location, and material properties of concrete, steel, and GFRP. The study was implemented using a user defined comprehensive $MATLAB^{(R)}$ simulation model to find an efficient hybrid section design maximizing strength and ductility. Generating lower bond stresses than steel bars at the concrete interface, auxiliary GFRP bars minimize damage in the concrete core of beam-column sections. Their usage prevents excessive yielding of the core longitudinal bars during frequent moderate cyclic deformations, which leads to significant damage in the foundations of bridges or beam-column spliced sections where repair is difficult and expensive. Analytical results from this study shows that hybrid steel-GFRP composite concrete sections where GFRP is used as auxiliary bars show adequate ductility with a significant increase in strength. Results also compare different design parameters reaching a number of design recommendations for the proposed hybrid section.

Response of lap splice of reinforcing bars confined by FRP wrapping: application to nonlinear analysis of RC column

  • Pimanmas, Amorn;Thai, Dam Xuan
    • Structural Engineering and Mechanics
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    • 제37권1호
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    • pp.111-129
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    • 2011
  • This paper presents a nonlinear analysis of reinforced concrete column with lap splice confined by FRP wrapping in the critical hinging zone. The steel stress-slip model derived from the tri-uniform bond stress model presented in the companion paper is included in the nonlinear frame analysis to simulate the response of reinforced concrete columns subjected to cyclic displacement reversals. The nonlinear modeling is based on a fiber discretization of an RC column section. Each fiber is modeled as either nonlinear concrete or steel spring, whose load-deformation characteristics are calculated from the section of fiber and material properties. The steel spring that models the reinforcing bars consists of three sub-springs, i.e., steel bar sub-spring, lap splice spring, and anchorage bond-slip spring connected in series from top to bottom. By combining the steel stress versus slip of the lap splice, the stress-deformation of steel bar and the steel stress-slip of bars anchored into the footing, the nonlinear steel spring model is derived. The analytical responses are found to be close to experimental ones. The analysis without lap splice springs included may result in an erroneous overestimation in the strength and ductility of columns.

박막의 조성비율에 따른 유기태양전지의 효율성 연구 (A Study about the Efficiency of Organic Photovoltaic Device as a function of the Material Concentration)

  • 김승주;이동근;박재형;공수철;김원기;류상욱
    • 반도체디스플레이기술학회지
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    • 제8권3호
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    • pp.1-5
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    • 2009
  • In this study, we have shown the power conversion efficiency of organic thin film photovoltaic devices utilizing a conjugated polymer/fullerene bulk-hetero junction structure. We use MDMO-PPV(Poly[2-methoxy-5-(3,7-dimethyloctyloxy -1,4-phenylenevinylene) as an electron donor, PCBM([6,6]-Phenyl C61 butyric acid methyl ester) as an electron accepter, and PEDOT:PSS used as a HTL(Hole Transport Layer). We have fabricated OPV(Organic Photovoltaic) devices as a function of the MDMO-PPV/PCBM concentration from 1:1 to 1:5. The electrical characteristics of the fabricated devices were investigated by means of I-V, P-V, F·F(Fill Factor) and PCE(power conversion efficiency). The power conversion efficiency was gradually increased until 1:4 ratio, also the highest efficiency of 0.4996% was obtained at the ratio.

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Trends in Monoclonal Antibody Production Using Various Bioreactor Systems

  • Jyothilekshmi, I.;Jayaprakash, N.S.
    • Journal of Microbiology and Biotechnology
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    • 제31권3호
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    • pp.349-357
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    • 2021
  • Monoclonal antibodies are widely used as diagnostic reagents and for therapeutic purposes, and their demand is increasing extensively. To produce these proteins in sufficient quantities for commercial use, it is necessary to raise the output by scaling up the production processes. This review describes recent trends in high-density cell culture systems established for monoclonal antibody production that are excellent methods to scale up from the lab-scale cell culture. Among the reactors, hollow fiber bioreactors contribute to a major part of high-density cell culture as they can provide a tremendous amount of surface area in a small volume for cell growth. As an alternative to hollow fiber reactors, a novel disposable bioreactor has been developed, which consists of a polymer-based supermacroporous material, cryogel, as a matrix for cell growth. Packed bed systems and disposable wave bioreactors have also been introduced for high cell density culture. These developments in high-density cell culture systems have led to the monoclonal antibody production in an economically favourable manner and made monoclonal antibodies one of the dominant therapeutic and diagnostic proteins in biopharmaceutical industry.

Effects of Inorganic Fillers on Mechanical Properties of Silicone Rubber

  • Kim, Gyu Tae;Lee, Young Seok;Ha, KiRyong
    • Elastomers and Composites
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    • 제54권2호
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    • pp.142-148
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    • 2019
  • In this study, the effects of filler particle size and shape on the physical properties of silicone rubber composites were investigated using inorganic fillers (Minusil 5, Celite 219, and Nyad 400) except silica, which was already present as a reinforcing filler of silicone rubber. Fillers with small particle sizes are known to facilitate the formation of the bound rubber by increasing the contact area with the polymer. However, in this experiment, the bound rubber content of Celite 219-added silicone composite was higher than that of Minusil 5-added silicone composite. This was attributed to the porous structure of Celite 219, which led to an increase in the internal surface area of the filler. When the inorganic fillers were added, both thermal decomposition temperature and thermal stability were improved. The bound rubber formed between the silicone rubber and inorganic filler affected the degree of crosslinking of the silicone composite. It is well-known that as the size of the reinforcing filler decreases, the reinforcing effect increases. However, in this experiment, the hardness of the composite material filled with Celite 219 was the highest compared to the other three composites. Furthermore, the highest value of 2.19 MPa was observed for 100% modulus, and the fracture elongation was the lowest at 469%. This was a result of excellent interaction between Celite 219 filler and silicone rubber.

Fabrication of an Automatic Color-Tuned System with Flexibility Using a Dry Deposited Photoanode

  • Choi, Dahyun;Park, Yoonchan;Lee, Minji;Kim, Kwangmin;Choi, Jung-Oh;Lee, Caroline Sunyong
    • International Journal of Precision Engineering and Manufacturing-Green Technology
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    • 제5권5호
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    • pp.643-650
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    • 2018
  • A self-powered electrochromic device was fabricated on an indium tin oxide-polyethylene naphthalate flexible substrate using a dye-sensitized solar cell (DSSC) as a self-harvesting source; the electrochromic device was naturally bleached and operated under outdoor light conditions. The color of the organic electrochromic polymer, poly(3,4-ethylenedioxythiophene) polystyrene sulfonate, was shifted from pale blue to deep blue with an antimony tin oxide film as a charge-balanced material. Electrochromic performance was enhanced by secondary doping using dimethyl sulfoxide. As a result, the device showed stable switching behavior with a high transmittance change difference of 40% at its specific wavelength of 630 nm for 6 hrs. To improve the efficiency of the solar cell, 1.0 wt.% of Ag NWs in the photoanode was applied to the $TiO_2$ photoanode. It resulted in an efficiency of 3.3%, leading to an operating voltage of 0.7 V under xenon lamp conditions. As a result, we built a standalone self-harvesting electrochromic system with the performance of transmittance switching of 29% at 630 nm, by connecting with two solar cells in a device. Thus, a self-harvesting and flexible device was fabricated to operate automatically under the irradiated/dark conditions.

차폐 재료의 융합과 개질제 특성에 따른 의료방사선 차폐 시트 물리적 특성 고찰 (Physical Properties of Medical Radiation Shielding Sheet According to Shielding Materials Fusion and Resin Modifier Properties)

  • 김선칠
    • 한국융합학회논문지
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    • 제9권12호
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    • pp.99-106
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    • 2018
  • 의료방사선 방어를 위해 사용되는 차폐 시트의 제조과정에서 인장강도를 유지하면서 차폐 재료의 충전율을 높여 차폐 성능을 향상시키는 방안을 제시하고자 한다. 본 연구에서 제안된 개질제는 고분자 수지재료와의 융합에 있어서 분자량을 높여 재료의 친화성을 높이는 역할을 수행한다. 차폐시트의 산화텅스텐의 충전율과 인장강도, 차폐 성능 등을 평가하였다. 공정과정에서 개질제는 분자량과 밀도를 증가시켰고, 성형 과정에서 퍼짐 형상이 적용되었고, 성능 향상과 재료와의 친화성, 인장강도를 유지하기 위해 사용된 개질제 PMMA는 20%를 혼합할 경우 가장 우수한 효과를 얻을 수 있다. 본 연구에서 제시된 재료의 융합과 개질제를 통해 차폐시트의 대량생산이 가능하며, 향후 경량의 차폐복 제작에 기여할 것입니다.

Web buckling behavior of FRP composite box-beams: Governing parameters and their effect

  • Kasiviswanathan, M.;Upadhyaya, Akhil
    • Advances in Computational Design
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    • 제6권1호
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    • pp.55-75
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    • 2021
  • The lightweight superstructure is beneficial for bridges in remote areas and emergency erection. In such weight-sensitive applications, the combination of fiber-reinforced polymer (FRP) as a material and box-beams as a structural system have enormous scope. This combination offers various advantages, but as a thin-walled structure, their designs are often governed by buckling criteria. FRP box-beams lose their stability either by flange or web buckling mode. In this paper, the web buckling behavior of simply supported FRP box-beam subjected to transverse load has been studied by modeling full box-beam to consider the effect of real state of stress (stress variation in length direction) and boundary conditions (rotational restraint at web-flange junction). A parametric study by varying the sectional geometry and fiber orientation is carried out by using ANSYS software. The accuracy of the FE models was ensured by verifying them against the available results provided in the literature. With the help of developed database the influential parameters (i.e., αs, βw, δw and γ) affecting the web bucklings are identified. Design trends have been developed which will be helpful to the designers in the preliminary stage. Finally, the importance of governing parameters and design trends are demonstrated through pedestrian bridge design.

Experimental and analytical study on continuous GFRP-concrete decks with steel bars

  • Tong, Zhaojie;Chen, Yiyan;Huang, Qiao;Song, Xiaodong;Luo, Bingqing;Xu, Xiang
    • Structural Engineering and Mechanics
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    • 제76권6호
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    • pp.737-749
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    • 2020
  • A hybrid bridge deck is proposed, which includes steel bars, concrete and glass-fiber-reinforced-polymer (GFRP) plates with channel sections. The steel bar in the negative moment region can increase the flexural stiffness, improve the ductility, and reduce the GFRP ratio. Three continuous decks with different steel bar ratios and a simply supported deck were fabricated and tested to study the mechanical performance. The failure mode, deflection, strain distribution, cracks and support reaction were tested and discussed. The steel bar improves the mechanical performance of continuous decks, and a theoretical method is proposed to predict the deformation and the shear capacity. The experimental results show that all specimens failed with shear failure in the positive moment region. The increase of steel bar ratio in the negative moment region can achieve an enhancement in the flexural stiffness and reduce the deflection without increasing GFRP. Moreover, the continuous deck can achieve a yield load, and the negative moment can be carried by GFRP plates after the steel bar yields. Finally, a nonlinear analytical method for the deflection calculation was proposed and verified, with considering the moment redistribution, non-cracked sections and nonlinearity of material. In addition, a simplified calculation method was proposed to predict the shear capacity of GFRP-concrete decks.