• Title/Summary/Keyword: Polyethylene Terephthalate (PET)

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Improvement of Permeation of Solvent-free Multi-layer Encapsulation of Thin Films on Polyethylene Terephthalate (PET) (고분자 기판위에 유기 용매를 사용하지 않은 다층 박막 Encapsulation 기술 개발)

  • Han Jin-Woo;Kang Hee-Jin;Kim Jong-Yeon;Seo Dae-Shik
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.8
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    • pp.754-757
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    • 2006
  • The inorganic multi-layer thin film encapsulation was newly adopted to protect the organic layer from moisture and oxygen. Using the electron beam, sputter, inorganic multi-layer thin-film encapsulation was deposited onto the Polyethylene Terephthalate (PET) and their interface properties between inorganic and organic layer were investigated. In this investigation, the SiON, $SiO_2$ and parylene layer showed the most suitable properties. Under these conditions, the WVTR for PET can be reduced from level of $0.57g/m^2/day$ (bare subtrate) to $1*10^{-5}g/m^2/day$ after application of a SiON and $SiO_2$ layer. These results indicates that the $PET/SiO_2/SiON/Parylene$ barrier coatings have high potential for flexible organic light-emitting diode(OLED) applications.

Heterologous Expression of Streptomyces PETase Gene Involved in PET Biodegradation (PET 생분해에 관여하는 방선균 유래 PETase 유전자의 이종숙주 발현)

  • Soo-been, Yang;Yeon-jin, Yoo;Eung-Soo, Kim;Sisun, Choi
    • Microbiology and Biotechnology Letters
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    • v.50 no.4
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    • pp.501-507
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    • 2022
  • PET (Polyethylene terephthalate), a representative plastic material, has useful physicochemical properties such as high durability and economic feasibility, and is used in various industrial fields such as bottles, fibers, and containers. Due to the recent increase in plastic usage including disposable products, eco-friendly strategy using microorganisms have drawn attention differentiated from conventional landfill and incineration methods. In this study, a soil-derived Streptomyces javensis Inha503 containing a PETase gene was selected and the ability to hydrolyze PU (Polyurethane) was confirmed through agar plate diffusion assay. This strain was cultured with PET for a month, and PET decomposition ability was also confirmed through a scanning electron microscope. Moreover, cloning and heterologous expression of S. javensis Inha503 PETase gene exhibited PET activity in the PETase non-containing S. coelicolor, confirming for the first time the presence of functional PETase gene in Streptomyces species.

Optical and Hydrophobic Properties of Ag Deposited ZnO Nanorods on ITO/PET (ITO/PET 기판 위에 성장된 산화아연 나노로드에 형성된 은 입자의 광학적 특성 및 소수성 표면 연구)

  • Ko, Yeong-Hwan;Kim, Myung-Sub;Yu, Jae-Su
    • Journal of the Korean Vacuum Society
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    • v.21 no.4
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    • pp.205-211
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    • 2012
  • We investigated the optical and hydrophobic properties of the deposited silver (Ag) zinc oxide (ZnO) nanorods (NRs) on flexible indium tin oxide (ITO) coated polyethylene terephthalate (PET) substrates (i.e., ITO/PET). The ZnO NRs were grown by an electrochemical deposition using a sputtered ZnO seed layer and the Ag was deposited by using a thermal evaporator. For comparison, the same fabrication process was carried out on the bare ITO/PET without ZnO NRAs. Due to the discrete surface of ZnO NRs, the deposited Ag was formed as nano-scale particles, while the Ag became film-like for bare ITO/PET. In order to control the size and amount of Ag particles, the Ag deposition time was changed from 100 to 600 s. When the deposition time was increased, the Ag particles became larger and denser, and the absorptance was increased. This enhanced absorptance may be due to the localized surface plasmon resonance of Ag particles. Furthermore, the relatively high hydrophobicity was observed for the deposited Ag on the ZnO NRs/ITO/PET. These improved optical and surface properties are expected to be useful for flexible photovoltaic and optoelectronic devices.

A Study on the Environment Assessment of Waste Polyethylene Terephthalate (PET) by LCA (LCA기법을 이용한 PET의 환경성평가에 관한 연구)

  • Park, Chan-Hyuk;Chung, Jae-Chun;Choi, Suk-Soon;Kim, Sung-Hwan
    • Journal of the Korea Organic Resources Recycling Association
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    • v.13 no.1
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    • pp.115-123
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    • 2005
  • In this study, life cycle assessment(LCA) technique was employed to evaluate the environmental impact of material recycling of polyethylene terephthalate(PET) bottle. Life cycle inventory was established based on the data collected from recycling companies in Korea. Simapro 5.0 LCA software and Eco-indicator 95 index were used for the analysis. The biggest impact by the material recycling of PET bottle on the environmental category was the global warming. It is because melting and production of the recycled PET product consume a significant amount of electricity and energy. In the environmental pollution discharge, $CO_2$ emission was the highest, followed by NOx. This is probably due to the use of diesel and gasoline in the consumption of electricity and transportation. All the environmental impact showed (-) value except the ozone layer depletion, which means that the material recycling of PET bottle is environmentally fair. The use of recycled PET product greatly reduced the environmental impact.

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Compatibilization of Linear PPS/PET Blends with SEBS Copolymers (SEBS 공중합체를 이용한 선형 PPS/PET 블렌드의 상용화)

  • Kim, Sungki;Hong, In-Kwon;Lee, Sangmook
    • Polymer(Korea)
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    • v.37 no.3
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    • pp.405-410
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    • 2013
  • The effect of styrene-ethylene/butylene-styrene (SEBS) on the blend of polyphenylene sulfide (PPS) and polyethylene terephthalate (PET) was investigated. The blends were extruded by a single screw extruder equipped with a Maddock mixing screw, and their molded properties were examined. After the binary blends were prepared on the whole compositions of PPS/PET (80/20, 60/40, 40/60, 20/80), the thermal, rheological, mechanical properties and morphology of the blends were analyzed. The results showed the significant decline in the properties of the blends owing to the incompatibility between PPS and PET phases. As a basic blend composition, the PPS/PET (40/60) blend was selected by considering cost efficiency. To this basic blend, SEBS was added as a compatibilizer. With increasing SEBS addition, the mechanical properties were improved. From the domain size reduction observed in morphology, it might be due to the enhancement of compatibility between linear PPS and PET phases by addition of SEBS.

Identification of the Volatile Compounds in Polyethylene Terephthalate Bottles and Determination of Their Migration Content into Mineral Water (PET 생수병 내 휘발성 물질의 동정 및 이행량 분석)

  • Jung, Eui Min;Kim, Dong Joo;Lee, Keun Taik
    • Korean Journal of Food Science and Technology
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    • v.46 no.1
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    • pp.19-24
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    • 2014
  • This study was carried out to identify the volatile organic compounds (VOCs) in polyethylene terephthalate (PET) bottles and to determine the extent to which VOCs migrate into mineral water during the bottling process and storage. A greater amount of nonanal and decanal was generated from the PET bottles than from the PET preforms. Benzene, ethylbenzene, nonanal, and vinyl benzoate were identified from the PET bottles when the incubation temperature of the headspace solid-phase microextraction (HS-SPME) sampler was set to 60, 80, and $100^{\circ}C$. As the incubation temperature increased, the concentrations of nonanal, vinyl benzoate, and decanal increased significantly. When the high-density polyethylene (HDPE) PET bottle caps were extracted with dichloromethane, the level of Irgafos 168 was found to be $206{\pm}20.1\mu}g/g$. The concentration of 2,4-di-tert-butylphenol in water was $4.80{\pm}0.2{\mu}g/L$. Therefore, it is necessary to avoid exposing PET and HDPE resins to high temperatures during the manufacturing process and storage of bottled water.

Annealing Effect in the Cold-Plastic Deformation of Amorphous PET Material (무정형 PET 재료의 플라스틱 냉간 변형에서의 열처리 효과)

  • Lee, Jong-Young;Park, Seong-Soo
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.56-62
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    • 2001
  • When polyethylene terephthalate(PET) film specimen were stepwise elongated under tension with various speeds of about 0.5~500 mm/min, the necking area, consisted of transparent and opaque bands, was formed during plastic deformation. Stress oscillation was apparently obtained in the stress-strain curve of above specimen. However, stress oscillation was not obtained in the stress-strain curve of annealing specimen. Microstructure was examined dynamically using an optical microscopy and thermal analysis was carried out in a differential scanning calorimeter at a heating rate of 10${\circ}$/min. Also, orientation and crystallization were examined using monochromatic-pinhole technique and elastic modulus was measured by a dynamic mechanical analyzer in the temperature range of -150~70 ${\circ}$ with the frequency of 1 Hz. Transparent PET products were fabricated by use of the PET pellets annealed at 83${\circ}$ for 30 min in an electric furnace.

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Depolymerization of Polyethylene Terephthalate with Supercritical Methanol (초임계메탄올을 이용한 PET의 분해)

  • Ahn, Jae-Myoung;Ihm, Bang-Hyun;Kim, Sun-Wook;Shim, Jae-Jin
    • Clean Technology
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    • v.13 no.1 s.36
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    • pp.46-53
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    • 2007
  • We depolymerized PET in supercritical methanol and observed the yield of DMT at various reaction conditions. At subcritical state below $240^{\circ}C$, the yield of DMT was very low, about only 50%. It increased dramatically to 80% at supercritical state above $260^{\circ}C$, thereafter the increasing rate was reduced significantly. Similarly, at subcritical state of 6.89 MPa, the DMT yield was only 50%, but it increased abruptly to 85% at supercritical state of 10.34 MPa, yielding no further increase above the pressure. Within 10 minutes after the beginning of the reaction, the DMT yield reached 80%, indicating that the significant portion of the reaction has proceeded, and then, the yield increased slowly. The methanol/PET ratio of 8 showed the maximum DMT yield. We found the optimum depolymerization condition fur PET methanolysis is temperature $300^{\circ}C$, pressure 10.34 MPa, reaction time 40 minutes, and methanol/PET ratio of 8.

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Electrical Properties of Polyethyleneterephthalate Film for Transducer (변환기용 PET 박막의 전기적 특성)

  • Ko, Keel-Young;Kim, Gyun-Sik;Byun, Doo-Gyoon;Park, Ha-Vong;Lee, Chung-Ho;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.510-513
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    • 2003
  • In this paper, we have investigated the physical, dielectric and electrical conduction properties of polyethylene terephthalate(PET) film due to temperature variation. From FT-IR spectrum as an analysis of physical properties, the strong absorption in wavenumber 1019[$cm^{-1}$], 1266[$cm^{-1}$], and 1752[$cm^{-1}$] observed by the C=O and benzene ring. the characteristics of volume resistivity used to highmegohm meter is measured from 1 to 10 minutes when the specimen applied the voltage according to the step voltage appling method. and dielectric characteristics were measured in the temperature range from room temperature to 120[$^{\circ}C$] due to frequency variation.. also we measured in the voltage rang of 1[V] to 20[V] according to the voltage application method.

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