• Title/Summary/Keyword: Poly(D

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Synthesis and Biological Activity of Poly[(tri-O-acetyl-D-glucal)-alt-(maleic anhydride)] Derivatives

  • Han, Man-Jung;Lee, Choong-Whan;Kim, Ki-Ho;Lee, Won-Young
    • Bulletin of the Korean Chemical Society
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    • v.12 no.1
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    • pp.85-87
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    • 1991
  • Poly[(tri-O-acetyl-D-glucal)-alt-(maleic anhydride)] was synthesized by free radical copolymerizations of the relevant comonomers. The alternating sequence of the copolymer was confirmed by $^1$H-NMR, elemental analysis, and titration of anhydride groups incorporated into the copolymer. Hydrolysis of the copolymer under different conditions resulted in poly[(2-acetoxymethyl-3,4-diacetoxytetrahydropyran-5,6-diyl) (1,2-dicarboxyethylene)] and poly[(2-hydroxymethyl-3,4-dihydroxytetrahydropyran-5,6-diyl) (1,2-dicarboxyethylene)]. The cytotoxicities of these polymers measured against normal and tumor cells (3LL, B16) in vitro were found to be higher than that of DIVEMA, a prototype polymer having a high antitumor activity.

ON THE (p, q)-POLY-KOROBOV POLYNOMIALS AND RELATED POLYNOMIALS

  • KURT, BURAK;KURT, VELI
    • Journal of applied mathematics & informatics
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    • v.39 no.1_2
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    • pp.45-56
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    • 2021
  • D.S. Kim et al. [9] considered some identities and relations for Korobov type numbers and polynomials. In this work, we investigate the degenerate Korobov type Changhee polynomials and the (p,q)-poly-Korobov polynomials. We give a generalization of the Korobov type Changhee polynomials and the (p,q) poly-Korobov polynomials. We prove some properties and identities and explicit relations for these polynomials.

470 x 235ppi poly-Si TFT LCD for High-Resolution 2D and 3D Autostereoscopic Display

  • Uehara, Shin-Ichi;Ikeda, Naoyasu;Takanashi, Nobuaki;Iriguchi, Masao;Sugimoto, Mitsuhiro;Matsuzaki, Tadahiro;Asada, Hideki
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.783-786
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    • 2004
  • We have developed a 470 x 235ppi poly-Si TFT LCD with a novel pixel arrangement, called HDDP (Horizontally Double-Density Pixels), for high-resolution 2D and 3D autostereoscopic display. 3D image quality is especially high in a lenticular-lens-equipped 3D mode because both horizontal resolution and vertical resolution are high, and because these resolutions are equal. 3D and 2D images can be displayed simultaneously in the same picture. In addition, 3D images can be displayed anywhere and 2D characters can be made to appear at different depths with perfect legibility. No switching of 2D/3D modes is necessary, and the design's thin and uncomplicated structure makes it especially suitable for mobile terminals.

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Saccharide Effect on the Lower Critical Solution Temperature of Poly(organophosphazenes) with Methoxy-poly(ethylene glycol) and Amino Acid Esters as Side Groups

  • Lee, Sang-Beom;Sohn, Youn-Soo;Song, Soo-Chang
    • Bulletin of the Korean Chemical Society
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    • v.24 no.7
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    • pp.901-905
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    • 2003
  • The lower critical solution temperature (LCST) of thermosensitive poly(organophosphazenes) with methoxypoly(ethylene glycol) (MPEG) and amino acid esters as side groups was studied as a function of saccharide concentration in aqueous solutions of mono-, di-, and polysaccharides. Most of the saccharides decreased the LCST of the polymers, and the LCST decrease was more prominently observed by saccharides containing a galactose ring, such as D-galactose, D-galactosamine and D-lactose, and also the polysacccharide, 1-6-linked D-dextran effectively decreased the LCST of the polymers. Such an effect was discussed in terms of intramolecular hydrogen bonding of saccharides in polymer aqueous solution. The saccharide effect was found to be almost independent on the kinds of the amino acid esters and MPEG length of the polymers. Such a result implies that the polymer-saccharide interaction in aqueous solution is clearly influenced by the structure of sacchardes rather than by that of the polymers. The acid saccharides such as D-glucuronic and D-lactobionic acid increased the LCST, which seems to be due to their pH effect.

Hexagonal to Cubic Phase Transition in the $D_2O$-Induced Reverse Micellar Solution of a PEO-b-PPO-b-PEO Block Copolymer

  • Kim, Do-Hyun;Ko, Yoon-Soo;Kwon, Yong-Ku
    • Macromolecular Research
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    • v.16 no.1
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    • pp.62-65
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    • 2008
  • The morphology of the $D_2O$-induced reverse micellar structure of an amphiphilic block copolymer of poly( ethylene oxide )-b-poly(propylene oxide )-b-poly( ethylene oxide )($EO_{76}PO_{29}EO_{76}$) was investigated in hydrophobic media by small angle neutron scattering (SANS). Increasing $D_2O$ in the styrene/divinylbenzene solution of $EO_{76}PO_{29}EO_{76}$ led to a change in morphology of the reverse micelles from a short range ordered molecular aggregate to a hexagonally arranged micelle, and further to a spherical micelle.

Electrical characteristics of 3-D stacked CMOS Inverters using laser crystallization method (레이저 결정화 방법을 적용한 3차원 적층 CMOS 인버터의 전기적 특성 개선)

  • Lee, Woo-Hyun;Cho, Won-Ju;Oh, Soon-Young;Ahn, Chang-Geun;Jung, Jong-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.118-119
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    • 2007
  • High performance three-dimensional (3-D) stacked poly-Si complementary metal-oxide semiconductor (CMOS) inverters with a high quality laser crystallized channel were fabricated. Low temperature crystallization methods of a-Si film using the excimer-laser annealing (ELA) and sequential lateral solidification (SLS) were performed. The NMOS thin-film-transistor (TFT) at lower layer of CMOS was fabricated on oxidized bulk Si substrate, and the PMOS TFT at upper layer of CMOS was fabricated on interlayer dielectric film. The 3-D stacked poly-Si CMOS inverter showed excellent electrical characteristics and was enough for the vertical integrated CMOS applications.

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An offset algorithm with forward tracing of tangential circle for open and closed poly-line segment sequence curve (접원의 전방향 경로이동에 의한 오프셋 알고리즘)

  • Yun, Seong-Yong;Kim, Il-Hwan
    • Proceedings of the KIEE Conference
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    • 2003.11c
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    • pp.1022-1030
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    • 2003
  • In this paper we propose a efficient offset curve construction algorithm for $C^0$-continuous Open and Closed 2D sequence curve with line segment in the plane. One of the most difficult problems of offset construction is the loop problem caused by the interference of offset curve segments. Prior work[1-10] eliminates the formation of local self-intersection loop before constructing a intermediate(or raw) offset curve, whereas the global self-intersection loop are detected and removed explicitly(such as a sweep algorithm[13]) after constructing a intermediate offset curve. we propose an algorithm which removes global as well as local intersection loop without making a intermediate offset curve by forward tracing of tangential circle. Offset of both open and closed poly-line segment sequence curve in the plane constructs using the proposed approach.

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Effect of Co-monomer on the Physical Properties of Poly(ethylene naphthalate) Copolymer (단량체의 종류에 따른 폴리(에틸렌 나프탈레이트) 공종합체의 물성 연구)

  • Kim, Jae-Hyun;Heo, Hye-Young;Jung, Tae-Houng;Han, Joon-Hee;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.35 no.2
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    • pp.146-151
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    • 2011
  • The physical properties of poly (ethylene 2,6-naphthalate) (PEN) copolymers were studied. PEN copolymers were synthesized successfully from the mixtures of ethylene glycol(EG), 1,3-propanediol (PD) and l,4-butanediol (BD) with 2,6-dimethyl naphthalene dicarboxylate. The results indicated that PEN copolymers showed an amorphous state when the content of BD(PD) in applied EG/BD(EG/PD) mixtures was less than 40% during the polycondensation. As a result, the lowering of thermal properties, orientation, and mechanical properties was found, however, the dimensional stability was improved. This is a promising result to apply the synthesized PEN copolymers as flexibles substrates.

Dimensional Stability of Poly(ethylene/propylene naphthalate) as a Flexible Substrate Application (유연 기판 소재로 응용을 위한 폴리(에틸렌/프로필렌 나프탈레이트)의 치수안정성 연구)

  • Kim, Jae-Hyun;Heo, Hye-Young;Jung, Tae-Houng;Han, Joon-Hee;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.33 no.4
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    • pp.371-376
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    • 2009
  • The 1,3-propane diol has been introduced as a co-monomer with ethylene glycol to polymerize the poly(ethylene/propylene naphthalate) in order to improve the dimensional stability of poly(ethylene naphthalate) for a possible flexible substrate material. Based on $^1H$-NMR results, it was found that poly (ethylene/propylene naphthalate) has been synthesised successfully. Introducing 1,3-propane diol resulted in the amorphous state in polyester as well as lowering of glass transition and thermal degradation temperature. Coexisting relatively longer propylene segment compared with ethylene in synthesized polyester caused less orientation behavior and reducing thermal expansion coefficient. This is a promising result for poly (ethylene/propylene naphthalate) to apply a flexible substrate.

poly(D,L-lactide-co-glycolide) nanoparticles제조와 약물방출 거동 및 생분해도

  • Yu, Jeong-Jun;Jeong, Yeong-Il;O, Dong-Seok;Im, Gyun-Taek
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.550-553
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    • 2000
  • The polymeric matrices made with poly(D,L-lactide-co-glycolide) were prepared using copolymer of poly(D,L-lactide) and poly(ethylene glycol) for application of drug delivery systems. Catalyst made use of stannous actoate. Particle size were differ greatly$(435.3{\pm}11.2{\sim}2284.1{\pm}188.5)$ that nanoparticle made use of according to solvent of various kinds. Polymer could a sharp distinction with copolymerized among LE-1, LE-2 and LE-3 of PLA and PEG of content that to examine $^1H-NMR$ of copolymer make refine and reprecipitation. Drug delivery effect at PLGA nanoparticle : PLA amount more then proved highly drug delivery amount that each LE-1, LE-2, LE-3, drug and solvent was 40mg, 20mg and 10mg. Drug delivery effect proved higher 20mg that change(10mg, 20mg, 40mg) at drug feeding amount with LE-2. The first a lot of drug proved delivery. LE-3 most lactide content proved much delivery since biodegradable on PLGA copolymer result from lactide. Also biodegradable rate was highest at LE-3 much of lactide content, because influence at biodegradable effect of lactide by inclusive of soft PEG.

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