• 제목/요약/키워드: Poly(D

검색결과 1,085건 처리시간 0.029초

습식 상 역전 방법으로 제조한 아크릴계 고분자 막의 모폴로지 (Morphology of Membrane of Acrylic Polymers by Wet Phase Inversion Method)

  • 최승은;박한수;이광희
    • 폴리머
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    • 제30권2호
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    • pp.108-111
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    • 2006
  • 본 연구에서는 아크릴계 고분자의 소수성 차이에 따른 막 모폴로지 변화를 조사하였다. 막은poly(methyl methacrylate)(PMMA), poly(ethyl methacrylate)(PEMA), poly(butyl methacrylate)(PBMA), poly(isobutyl, methacrylate)(PIBMA) 및 이들의 블렌드를 사용하여 습식 상 역전 방법으로 제조하였다. 상대적으로 소수성이 적은 PMMA와 PEMA는channel-like 형태의 막 구조를, 소수성이 큰 PBMA와 PIBMA는 finger-like 형태의 막 구조를 보여주었다. 이러한 막 구조의 변화는 polymer-rich상의 고상화 과정에서 속도론적 차이가 있었기 때문이었다. 이성분 블렌드 막의 구조는 주 성분 고분자에 의해 결정되었다.

Poly-Si Cell with Preferential Grain Boundary Etching and ITO Electrode

  • Lim, D.G.;Lee, S.E.;Park, S.H.;Yi, J.
    • 태양에너지
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    • 제19권3호
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    • pp.125-131
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    • 1999
  • This paper deals with a novel structure of poly-Si solar cell. A grain boundary(GB) of poly-Si acts as potential barrier and recombination center for photo-generated carriers. To reduce unwanted side effects at the GB of poly-Si, we employed physical GB removal of poly-Si using chemical solutions. Various chemical etchants such as Sirtl, Yang, Secco, and Schimmel were investigated for the preferential GB etching. Etch depth about 10 ${\mu}m$ was achieved by a Schimmel etchant. After a chemical etching of poly-Si, we used $POCl_3$ for emitter junction formation. This paper used an easy method of top electrode formation using a RF sputter grown ITO film. ITO films with thickness of 300 nm showed resistivity of $1.26{\times}10^{-4}{\Omega}-cm$ and overall transmittance above 80%. Using a preferential GB etching and ITO top electrode, we developed a new fabrication procedure of poly-Si solar cells. Employing optimized process conditions, we were able to achieve conversion efficiency as high as 16.6% at an input power of 20 $mW/cm^2$. This paper investigates the effects of process parameters: etching conditions, ITO deposition factors, and emitter doping densities in a poly-Si cell fabrication procedure.

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넙치(Paralichthys olivaceus) 신장에서 Poly (I:C)의 단기 및 장기적인 면역 효과 (Short and long-term immune effects of Poly (I:C) in kidney of Olive flounder (Paralichthys olivaceus))

  • 성민재;박영진
    • 한국어병학회지
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    • 제37권1호
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    • pp.123-132
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    • 2024
  • Viral diseases cause enormous economic losses to the olive flounder (Paralichthys olivaceus) aquaculture industry in Korea. This study aimed to identify immune-related genes expressed in the kidney of olive flounder injected with Polyinosinic-polycytidylic acid (Poly (I:C)). Thirty fish were divided into two groups by intraperitoneal injection of 100µl of diethylpyrocarbonate-treated water or poly I:C per fish. Kidney tissues at day 3 and 30 after the injection were used for RNA-seq analysis to identify differentially expressed genes (DEGs). Poly I:C group upregulated il8, cfh, tnfaip2b, c3b.2, ly6d and cd38 genes at 3 days post-injection. Additionally, cd22, ccl34a.3, c9, cxcl19, ccl27a, ccl7, and cfh genes were upregulated at 30 days post-injection. Differential expression gene analysis showed that poly I:C has both short and long-term immune effects in olive flounder. This study provides a theoretical basis for understanding the molecular mechanism of the short and long-term immune effects of poly I:C.

Development of Rapid Thermal Processor for Large Glass LTPS Production

  • Kim, Hyoung-June;Shin, Dong-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.533-536
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    • 2006
  • VIATRON TECHNOLOGIES has developed Field-Enhanced Rapid Thermal Processor (FERTP) system that enables LTPS LCD and AMOLED manufacturers to produce poly-Si films at low cost, high throughput, and high yield. The FE-RTP allows the diverse process options including crystallization, thermal oxidation of gate oxides and fast pre-compactions. The process and equipment compatibility with a-Si TFT lines is able to provide a viable solution to produce poly-Si TFTs using a-Si TFT lines.

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Basis Set Superposition Error on Structures and Complexation Energies of Organo-Alkali Metal Iodides

  • Kim, Chang-Kon;Zhang, Hui;Yoon, Sung-Hoon;Won, Jon-Gok;Kim, Chan-Kyung
    • Bulletin of the Korean Chemical Society
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    • 제31권8호
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    • pp.2228-2234
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    • 2010
  • Theoretical studies have been performed to study the binding characteristics of the alkali metal iodides, M-I (M = Li, Na, K), to poly(ethylene oxide) (PEO, I), poly(ethylene amine) (PEA, II) and poly(ethylene N-methylamine) (PEMA, III) via the B3LYP method. In this study, two types of complexes, singly-coordinated systems (SCS) and doubly-coordinated systems (DCS), were considered, and dissociation energies (${\Delta}E_D$) were calculated both with and without basis set superposition error (BSSE). Two types of counterpoise (CP) approach were investigated in this work, but the ${\Delta}E_D$ values corrected by using the function CP (fCP) correction exhibited an unusual trend in some cases due to deformation of the sub-units. This problem was solved by including geometry relaxation in the CP-corrected (GCP) interaction energy. On the other hand, the effects of the BSSE on the structures were very small when the complexes were re-optimized on the CP-corrected (RCP) potential energy surface (PES), even if the bond lengths between X and $M^+$ ($d_{{X-M}^+}$) and between $M^+$ and $I^-$ ($d_{M^+-I^-}$) were slightly lengthened. Therefore, neither the GCP nor RCP corrections made much difference to the dissociation energies.

폴리게이트의 양자 효과에 따른 Double-Gate MOSFET의 단채널 효과 분석 (Analysis of Short-Channel Effect due to the 2D QM effect in the poly gate of Double-Gate MOSFETs)

  • 박지선;신형순
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2003년도 하계종합학술대회 논문집 II
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    • pp.691-694
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    • 2003
  • Density gradient method is used to analyze the quantum effect in MOSFET, Quantization effect in the poly gate leads to a negative threshold voltage shift, which is opposed to the positive shift caused by quantization effect in the channel. Quantization effects in the poly gate are investigated using the density gradient method, and the impact on the short channel effect of double gate device is more significant.

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Poly(fluorene)s for LED Applications

  • Lee, Jeong-Ik;Zyung, Tae-Hyoung;Klaerner, Gerrit;Miller, Robert D.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2000년도 제1회 학술대회 논문집
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    • pp.129-130
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    • 2000
  • The emission color stability of poly(fluorene) derivatives upon thermal annealing or passage of current in an electroluminescent device is affected by the structure of the main chain polymer unit and particularly by the polymer chain end substituents. Proper attention to these features leads to colorfast blue emission in both photo- and electoluminescence. Furthermore, the spectral emission characteristics can be tuned by the incorporation of various comonomers. Preliminary single layer device studies validate the potential utility of poly(fluorene) homo and copolymers for OLED applications.

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Photorefractive Performance of Poly[methyl-3-(9-carbazolyl) propylsiloxane] Based Composites Sensitized with Poly(3-hexylthiophene) in a 0.2-1wt % Range

  • Oh, Jin-Woo;Kim, Nak-Joong
    • Bulletin of the Korean Chemical Society
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    • 제31권1호
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    • pp.41-46
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    • 2010
  • In this work, we report on the characterization of six low-$T_g$ poly[methyl-3-(9-carbazolyl) propylsiloxane] based photorefractive (PR) composites sensitized with poly(3-hexylthiophene) (P3HT) in different concentrations, ranging from 0.2 to 1 wt %. At 632.8 nm, photoconductivity, space charge field, refractive index modulation, and grating buildup time were measured versus external electric field. The photoconductivity was strongly dependent on the visible light absorption and mobility. The magnitude of space charge field was affected by the conductivity contrast $\sigma_{ph}/(\sigma_{ph}+\sigma_d)$. The refractive index modulation increased with the magnitude of space charge field and the PR grating buildup speed increased with the photoconductivity.

A new anti-bacterial colloidal system from tailored control of colloidal silver deposition onto functionalized porous

  • Kang, Hak-Hee;Oh, Seong-Geun
    • 대한화장품학회지
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    • 제29권1호
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    • pp.89-101
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    • 2003
  • A new collolidal silver (Ag) system is present in which a fine colloidal Ag is in situ deposited onto functionalized porous poly(ethylene glycol dimethacrylate) (poly (EGDMA)) microspheres. The effectiveness of Ag deposition was investigated considering the surface characteristics of poly (EGDMA) microspheres, The result reported in this study illustrates that the control of surface area and surface functionality (in this study, a hydroxyl group) of poly (EGDMA) microspheres is an important factor that determines practically the degree of deposition of colloidal Ag. The x-ray analysis showed that Ag nanoparticles were dispersed evenly inner and outer surfaces and has a face center cubic(fcc) phase. In the preservation test, the Ag-containing poly (EGDMA) microspheres had a powerful anti-bacterial performance, showing a high potential for a new preservative.

The Characterization of Poly-Si Thin Film Transistor Crystallized by a New Alignment SLS Process

  • Lee, Sang-Jin;Yang, Joon-Young;Hwang, Kwang-Sik;Yang, Myoung-Su;Kang, In-Byeong
    • Journal of Information Display
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    • 제8권4호
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    • pp.15-18
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    • 2007
  • In this paper, we investigated the SLS process to control grain boundary(GB) location in TFT channel region, and it has been found to be applicable for locating the GB at the same location in the channel region of each TFT. We fabricated TFT by applying a new alignment SLS process and compared the TFT characteristics with a normal SLS method and the grain boundary location controlled SLS method. Also, we have analysed degradation phenomena under hot carrier stress conditions for n-type LDD MOSFETs.