• Title/Summary/Keyword: Polarization of water

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The Effects of Surface Condition and Flow Rate to the Cathodic Protection Potential and Current on Steel (강의 음극방식에 미치는 표면상태와 유속의 영향)

  • Kyeong-soo, Chung;Seong- Jong, Kim;Myung-Hoon, Lee;Ki-Joon, Kim;Kyung-Man, Moon
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.6
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    • pp.972-980
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    • 2004
  • Cathodic protection is being widely used to protect steel structures in sea water environment, In order to protect steel structures completely, the flow condition of sea water surrounding with this structures and the surface condition of the structures must be considered for a desirable design of cathodic protection. In this study, the optimum protection potential and current density were investigated in terms of cathodic current density, surface condition and a flow condition of sea water. The optium protection potential of the cleaned specimen was -770 mV(SCE) and below. However in the case of the rusted specimen, its potential was -700 mV(SCE) and below, which was somewhat positive than the cleaned one irrespective of flow condition. The optimum cathodic protection current density for both the cleaned and rusted specimens was 100 mA/$\textrm{m}^2$, however, on the flow condition, 200 mA/$\textrm{m}^2$ to be supplied for cathodic protection of steel structures completely for both cleaned and rusted specimens.

Cavitation Damage Behavior for 431 Stainless Steel by Hybrid Test in Sea Water (해양 환경 하에서 431 스테인리스강의 하이브리드 실험을 통한 캐비테이션 손상 거동)

  • Chong, Sang-Ok;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.46 no.6
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    • pp.271-276
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    • 2013
  • The demand for stainless steel is continuously increasing with the development in offshore industry due to its excellent corrosion resistance characteristics. However, it suffers cavitation-erosion in application of high rotating fluid and the damage accelerates in combination with electrochemical corrosion because of Cl-ion in sea water. This paper investigated the complex damage behavior for 431 stainless steel, that is one of martensite stainless steels, through the hybrid test in sea water. Various experiments were carried out, including potential measurement, anodic/cathodic polarization experiment and Tafel analysis. Surface morphology was observed and damage depth was analyzed by SEM and 3D microscope after each experiment, respectively. The results revealed that more active potential was observed under cavitation condition than static condition due to breakdown of passive film and activation of charge transfer, and that higher corrosion current density was obtained under cavitation condition due to synergistic effect of corrosion and erosion.

Using response surface methodology and Box-Behnken design in the study of affecting factors on the dairy wastewater treatment by MEUF

  • Khosroyar, Susan;Arastehnodeh, Ali
    • Membrane and Water Treatment
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    • v.9 no.5
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    • pp.335-342
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    • 2018
  • Micelle-Enhanced Ultrafiltration (MEUF) is a membrane separation processes that improving ultrafiltration process with the formation of micelles of the surface active agents. Surface active agents are widely used to improve membrane processes due to the ability to trap organic compounds and metals in the treatment of industrial waste water. In this study, surface active agents are used to improve micelle-enhanced ultrafiltration (MEUF) to reduce chemical oxygen demand (COD), total dissolved solid (TDS), turbidity and clogging the membrane in dairy wastewater treatment. Three important operational factors (anionic surface active agent concentration, pressure and pH) and these interactions were investigated by using response surface methodology (RSM) and Box-Behnken design. Results show that due to the concentration polarization layer and increase the number of Micelles; the anionic surface active agent concentration has a negative effect on the flux and has a positive effect on the elimination of contamination indices. pH, and the pressure have the greatest effect on flux. On the other hand, it could be stated that these percentages of separation are in the percentages range of Nano-filtration (NF). While MEUF process has higher flux than NF process. The results have been achieved at lower pressure while NF process needs high pressure, thus making MEUF is the replacement for the NF process.

An Overview of the Pretreatment Processes in Seawater Desalination Plants using Reverse Osmosis Membranes (역삼투막을 이용한 해수담수화 플랜트에서 전처리 공정 기술)

  • Ahn, Chang Hoon;Lee, Wonil;Yoon, Jeyong
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.6
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    • pp.811-823
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    • 2009
  • Seawater desalination process using a reverse osmosis (RO) membrane has been considered as one of the most promising technologies in solving the water scarcity problems in many arid regions around the world. To protect RO membrane in the process, a thorough understanding of the pretreatment process is particularly needed. Seawater organic matters (SWOMs) may form a gel layer on the membrane surface, which will increase a concentration polarization. As the SWOMs can be utilized as a substrate, membrane biofouling will be progressed on the RO membrane surface, resulting in the flux decline and increase of trans-membrane pressure drop and salt passage. In the middle of disinfection, an optimal chlorine dosage and neutralizer (sodium bisulfite, SBS) should be practiced to prevent oxidizing the surface of RO membranes. Additional fundamental research including novel non-susceptible biofouling membranes would be necessary to provide a guide line for the proper pretreatment process.

Study on the Corrosion and Cavitation Erosion Control of Glass Flake Lining for Mild Steel in Marine Environment (해양환경 중에서 Glass Flake 라이닝 강재의 부식과 캐비테이션 침식 방지에 관한 연구)

  • Lim, Uh Joh;Kim, Seong Hoon
    • 유체기계공업학회:학술대회논문집
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    • 2000.12a
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    • pp.359-365
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    • 2000
  • Port facilities and marine structures used in marine environment were encountered to corrosion damages because of the influence of $Cl^-$. Generally, to protect these accidents, mainly applied anti-corrosion paint and epoxy coating. But it was still remained erosion-corrosion damage such as impingement erosion, cavitation erosion, deposit attack. There was needs to develope the new coating materials to protective those corrosion damages. This paper, polyester glass flake, vinylester glass flake lining and epoxy coating for SS were investigated electrochemical tests and cavitation erosion test for corrosion behaviour under sea water. The main results obtained are as follows, 1) Surface of epoxy coating appear erosion pin hole but surface of polyester glass flake and vinylester glass flake lining do not appear erosion pin hole after impingement-cavitation erosion test in sea water. 2) Weight loss of polyester glass flake and vinylester glass flake lining do not occur after impingement-cavitation erosion test in sea water. 3) Corrosion current density of polyester glass flake lining less drained than epoxy coating and substrate under corrosion potential.. 4) Corrosion current density of vinylester glass flake lining with three coating less drained than that of polyester glass flake lining with two coating.

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Experimental Verification on Factors Affecting Core Resistivity Measurements (코어 비저항 측정에 미치는 영향요소에 대한 실험적 고찰)

  • Kim, Yeong Hwa;Choe, Ye Gwon
    • Journal of the Korean Geophysical Society
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    • v.2 no.3
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    • pp.225-233
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    • 1999
  • Electrical resistivity of a rock-sample is dependant on not only formation factor of rock itself but also many parameters such as fluid type, measuring device, temperature, water saturation, electrical contact between electrode and core section, induced polarization, and frequency of electric source. In this study, we attempt to verify various affecting factors in core resistivity measurements and to find a better environment for core resistivity measurement. Particularly great attention has been paid to understanding the effects of temperature, water saturation, contact condition between sample and electrodes, and frequency of electric source. Precise measurement of resistivity can be achieved by utilizing silver paste for better contacts, taping samples for constant moisture contents, and using time-series resistivity data.

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Analysis of Degradation Behavior of Structural Steels Depending on Environment (환경에 따른 구조용 강의 열화거동 분석)

  • Lee Chang-Soon;Park In-Gyu;Kim Yong-Ki;Chang Se-Ky
    • Proceedings of the KSR Conference
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    • 2004.06a
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    • pp.171-176
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    • 2004
  • Electro chemical corrosion tests were conducted on two structural steels, SS400 and SM490A, in various solutions with different pH values, All materials showed typical active corrosion behaviors in the solutions, and corrosion potential and current density were measured from the slopes obtained from the Tafel curves using linear polarization method. Corrosion potential increased in the acidic region and then decreased depending on the pH values of the solutions. All materials showed the fast corrosion rate in artificial acid rain(pH=4.7), but the slower corrosion rate was observed in NaOH solution(pH=12.0) for SS400 and in distilled water(pH=7.0) for SM490A, respectively, which is thought to come from the difference in chemical composition of two alloys. Generally homogeneous corrosion occurred in acid rain condition, and almost no corrosion was observed in distilled water in both alloys. NaOH solution produced more corrosion than distilled water, and more corrosion had progressed in SS400 than in SM490A in $3.5\%$ NaCl solution.

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Experimental Study on Coating Corrosion Characteristics of Heat Exchanger for Sea Water (해수용 열교환기의 코팅 부식특성 실험연구)

  • Kwon, Young-Chul;Kim, Ki-Young;Huh, Cheol;Cho, Meang-Ik;Kwon, Jeong-Tae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.9
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    • pp.4117-4123
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    • 2013
  • In the present study, coating corrosion characteristics of the heat exchanger for sea water are experimentally investigated. Coating types by a teflon, an electrodeposition and a ceramic+silicon were tested and compared with the corrosion characteristics of an aluminum. For the acceleration of corrosion by sea water, the temperature of sea water $70^{\circ}C$ and the concentration of salt 3.5% were considered. And the specimens were immersed in sea water during 9 weeks. Coating corrosion characteristics were measured by using the impedance method and SEM. Experimental results showed that polarization resistances obtained from Bode plot were related to the corrosion resistance of coating types, and the corrosion resistance of double coating were maintained during 4 weeks. From SEM photograph, we saw that blisters was generated on the interface between metal and coating.

Phellinus linteus Extract Regulates Macrophage Polarization in Human THP-1 Cells (상황버섯 추출물의 인간 유래 THP-1 단핵구 세포주의 분극화 조절)

  • Lee, Sang-Yull;Park, Sul-Gi;Yu, Sun-Nyoung;Kim, Ji-Won;Hwang, You-Lim;Kim, Dong-Seob;Ahn, Soon-Cheol
    • Journal of Life Science
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    • v.30 no.2
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    • pp.113-121
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    • 2020
  • Macrophages are initiators for regulating a host's defenses to eliminate pathogens and trigger tissue repair. Macrophages are classified into two types: classically (M1) activated macrophages and alternatively (M2) activated macrophages. M1-phenotype macrophages directly or indirectly kill infectious organisms and tumor cells via pro-inflammatory responses, whereas M2-phenotype macrophages remodel wounded tissue through anti-inflammatory responses. In this paper, we investigated how Phellinus linteus hot water extract passed from Diaion HP-20 resin (PLEP) regulates polarization of M1-like or M2-like macrophages in human THP-1 cells. PLEP did not have cytotoxicity at a high concentration of 300 ㎍/ml. We observed morphological alteration of the THP-1 cells, which are stimulated by PLEP, LPS/INF-γ (M1 stimulators) or IL-4/IL13 (M2 stimulators). PLEP exposure induced morphology contiguous with LPS/INF-γ. qPCR was also performed to determine whether PLEP influences M1 or M2 polarization-related genes. M1-phenotype macrophage-specific genes, such as TNF-α, IL-1β, IL-6, IL-8, CXCL10 and CCR7, were enhanced by PLEP in a dose-dependent manner similar to LPS/INF-γ. Conversely, M2-phenotype-specific genes, such as MRC-1, DC-SIGN, CCL17 and CCL22, were suppressed by PLEP. PLEP also significantly up-regulated secretory inflammation cytokines related to M1 polarization of macrophages, including TNFα, IL-1β and IL-6, which was similar to the gene expression. Further, MAPK and NF-κB signaling were increased by treatment with PLEP, resulting in enhancement of cytokine secretion. PLEP might therefore be used as a promising booster of pro-inflammatory responses through M1 polarization of human THP-1 cells.

Coolant Leak Effect on Polymer Electrolyte Membrane Fuel Cell (고분자전해질연료전지의 냉각수 누설에 대한 연구)

  • Song, Hyun-Do;Kang, Jung-Tak;Kim, Jun-Bom
    • Journal of the Korean Electrochemical Society
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    • v.10 no.4
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    • pp.301-305
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    • 2007
  • The performance of polymer electrolyte membrane fuel cell could be decreased due to coolant leaked from connection part. Micro pump was used to put small amount of coolant and investigate the effect on fuel cell. The stoichiometric ratio of hydrogen/air was 1.5/2.0, both side of gas was fully humidified, and current density of $400mA/cm^2$ was used as standard condition in this experiment. Constant current method was used to check performance recovery from coolant effect in 3 cell stack. The performance was recovered when coolant was injected in cathode side. On the other hand, the performance was not recovered when coolant was injected in anode side. Ethylene glycol could be converted to CO in oxidation process and cause poisoning effect on platinum catalyst or be adhered on GDL and cause gas diffusion block effect resulting performance decrease. Water with nitrogen gas was supplied in anode side to check performance recovery. Polarization curve, cyclic voltammetry, electrochemical impedance spectroscopy was used to check performance, and gas chromatography was used to check coolant concentration. Constant current method was not enough in full recovery of performance. However, water injection method was proved good method in full recovery of performance.