• Title/Summary/Keyword: Polarization and stability

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First-Principles Calculations for the Structual and Magnetic Properties of Nin (n=1-4) Nanowire Systems (단위 세포당 n(n=1-4)개의 원자를 갖는 Nin 나노와이어 계의 구조및 자기적 특성에 대한 제일원리 연구)

  • KIM, Dong-Chul
    • Journal of the Korean Magnetics Society
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    • v.16 no.4
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    • pp.193-196
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    • 2006
  • The magnetic properties of Ni nanowires consisting of one to four atoms are investigated by mean of ab initio spin-polarized density functional calculations. Stability of zigzag-square $Ni_4$ nanowire is larger than $Ni_4$ nanowires with square. The magnetic moment of linear $Ni_1$ is $1.34{\mu_B}/atom$, which is the largest magnitude among moments of five Ni nanowires. The magnetic moment of Ninanowires show to be decreased by increasing the number of atoms in unit cell. The smallest moment is $0.91 {\mu_B}/atom$ for square $Ni_4$ nanowire. The spin polarization of zigzag-square $Ni_4$ nanowire is 32% higher than that of fcc bulk Ni.

Detection of Artificial Displacement of a Reflector by using GB-SAR Interferometry and Atmospheric Humidity Correction (GB-SAR 간섭기법을 이용한 반사체의 인위적 변위탐지 및 대기습도보정)

  • Lee, Jae-Hee;Lee, Hoon-Yol;Cho, Seong-Jun;Sung, Nak-Hun;Kim, Jung-Ho
    • Korean Journal of Remote Sensing
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    • v.26 no.2
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    • pp.123-131
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    • 2010
  • In this paper we applied Ground-Based Synthetic Aperture Radar(GB-SAR) interferometry to detect artificial displacement of a reflector and performed an atmospheric humidity correction to improve the accuracy. A series of GB-SAR images were obtained using a center frequency of 5.3 GHz with a range resolution of 25 cm and a azimuth resolution of $0.324^{\circ}$, all in full-polarization (HH, VV, VH, HV) modes. A triangular trihedral corner reflector was located 160 m away from the system, and the artificial displacements of 0-40 mm was implemented during the GB-SAR image acquisition. The result showed that the RMS error between the actual and measured displacements, averaged in all polarization data, was 1.22 mm, while the maximum error in case of the 40 mm displacement was 2.72 mm at HH-polarization. After the atmospheric correction with respect to the humidity, the RMS error was reduced to 0.52 mm. We conclude that a GB-SAR system can be used to monitor the possible displacement of artificial/natural scatterers and the stability assessment with sub-millimeter accuracy.

Stability of TiN and WC Coated Dental Abutment Screw (TiN 및 WC코팅된 치과용 어버트먼트 나사의 안정성)

  • Son, M.K.;Lee, C.H.;Chung, C.H.;Jeong, Y.H.;Choe, H.C.
    • Journal of the Korean institute of surface engineering
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    • v.41 no.6
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    • pp.292-300
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    • 2008
  • Dental implant system is composed of abutment, abutment screw and implant fixture connected with screw. The problems of loosening/tightening and stability of abutment screw depend on surface characteristics, like a surface roughness, coating materials and friction resistance and so on. For this reason, surface treatment of abutment screw has been remained research problem in prosthodontics. The purpose of this study was to investigate the stability of TiN and WC coated dental abutment screw, abutment screw was used, respectively, for experiment. For improving the surface characteristics, TiN and WC film coating was carried out on the abutment screw using EB-PVD and sputtering, respectively. In order to observe the coating surface of abutment screw, surfaces of specimens were characterized, using field emission scanning electron microscope(FE-SEM) and energy dispersive x-ray spectroscopy(EDS). The stability of TiN and WC coated abutment screw was evaluated by potentiodynamic, and cyclic potentiodynamic polarization method in 0.9% NaCl solution at $36.5{\pm}1^{\circ}C$. The corrosion potential of TiN coated specimen was higher than those of WC coated and non-coated abutment screw. Whereas, corrosion current density of TiN coated screws was lower than those of WC coated and non-coated abutment screw. The stability of screw decreased as following order; TiN coating, WC coating and non-coated screw. The pitting potentials of TiN and WC coated specimens were higher than that of non-coated abutment screw, but repassivation potential of WC coated specimen was lower than those of TiN coated and non-coated abutment screws due to breakdown of coated film. The degree of local ion dissolution on the surface increased in the order of TiN coated, non-coated and WC coated screws.

Rock Mass Stability of the Buddha Statue on a Rock Cliff using Fracture Characteristics and Geological Face-Mapping (마애불 암반의 단열특성과 지질맵핑을 이용한 안정성 해석)

  • Ihm, Myeong Hyeok
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.1
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    • pp.539-544
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    • 2023
  • The subject of this study is the Maae Buddha statue in granodiorite of the Mesozoic Cretaceous period, which is concerned about stability as a standing stone cultural property located in ◯◯-dong, Gyeongsangbuk-do. For stability analysis, three-dimensional face mapping, geological properties of joints, three-dimensional scanning, ultrasonic velocity, polarization microscopy, electron microscopy analysis and XRD analysis were performed. In addition, the safety factor of the Maaebul was calculated by analyzing the damage status investigation, stereographic projection analysis, rock classification, and limit equilibrium analysis. The types and scales of damage and possible collapse by section depend on the degree of weathering of the rock and the orientation and characteristics of the joints, but wedge-failure and toppling-failure are expected to be small-scale. The safety factor of Maaebul in dry and wet conditions is less than 1.2, so stability is concerned. The types of damage were mainly observed, such as exfoliation, cracking, granular decomposition, and vegetation growth. The Maaebul rock is granodiorite, and the surface discoloration materials are K, Fe, and Mg. The 4 sets of joints are developed, J1 is tensile joint and the others are shear joint. The uniaxial compressive strength estimated by ultrasonic exploration is 514kgf/cm2, which corresponds to most soft rocks and some weathered rocks. Rock classification(RMR) is estimated to be grade 5, very poor rock mass. These technique along with the existing methods of safety diagnosis of cultural properties are expected to be a reasonable tool for objective interpretation and stability review of stone cultural properties.

Performance of Modified-Silicon Carbide Fiber Composites Membrane for Polymer Exchange Membrane Fuel Cells (표면처리된 실리콘 카바이드 섬유 복합막의 고분자 전해질 막 연료전지 성능)

  • Park, Jeong Ho;Kim, Taeeon;Juon, Some;Cho, Yongil;Cho, Kwangyeon;Shul, Yonggun
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.1
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    • pp.28-38
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    • 2014
  • The organic-inorganic composite membrane in polymer exchange membrane fuel cells (PEMFCs) have several fascinating technological advantages such as a proton conductivity, thermal stability and mechanical properties. As the inorganic filler, silicon carbide (SiC) fiber have been used in various fields due to its unique properties such as thermal stability, conductivity, and tensile strength. In this study, composite membrane was successfully fabricated by modified-silicon carbide fiber. Modified process, as a novel process in SiC, takes reaction by phosphoric acid after oxidation process (generated homogeniusly $SiO_2$ layer on SiC fiber). The mechanical property which was conducted by tensile test of the 5wt% modified-$SiO_2@SiCf$ composite membrane was better than that of Aquivion casting membrane as well as ion cxchange capacity(IEC) and proton conductivity. In addition, the single cell performance was observed that the 5wt% modified-$SiO_2@SiCf$ composite membrane was approximately $0.2A/cm^2$ higher than that of a Aquivion casting electrolyte membrane and electrochemical impedance was improved with the charge transfer resistance and membrane resistance.

STABILIZATION OF REFERENCE SIGNAL TRANSMISSION SYSTEM IN RADIO TELESCOPE FOR VLBI (VLBI 전파망원경 기준 신호 전송시스템 안정화)

  • Je, Do-Heung;Lee, Won-Kyu;Kim, Soo-Yeon;Chung, Moon-Hee;Song, Min-Kyu;Jung, Taehyun;Byun, Do-Young;Kim, Seung-Rae;Sohn, Bong-Won;Wi, Seog-Oh;Han, Seog-Tae;Kang, Yong-Woo
    • Publications of The Korean Astronomical Society
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    • v.28 no.3
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    • pp.95-100
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    • 2013
  • A fiber-optic reference signal transmission system, which transmits the 1.4 GHz reference signal from H-maser to receiver cabin in radio telescopes, was adopted for compensating the phase changes due to temperature variation and antenna movement. At the first experiment, the remote signal's phase changed more than 15 degrees at 1.4 GHz. We found unstable components in sub-system experiments and replaced them. The main cause of unstable phase stability was the unaligned polarization axis between Laser Diode and Mach-Zehnder Modulator (MZM). The improved system stability showed $1{\times}10^{-16}$ allan standard deviation at 1,000 sec integration time with the antenna fixed. When the antenna moves in the azimuth axis, the 1.4 GHz remote signal showed the phase change smaller than 0.2 degrees.

Gold functionalized-graphene oxide-reinforced acrylonitrile butadiene rubber nanocomposites for piezoresistive and piezoelectric applications

  • Mensah, Bismark;Kumar, Dinesh;Lee, Gi-Bbeum;Won, Joohye;Gupta, Kailash Chandra;Nah, Changwoon
    • Carbon letters
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    • v.25
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    • pp.1-13
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    • 2018
  • Gold functionalized graphene oxide (GOAu) nanoparticles were reinforced in acrylonitrile-butadiene rubbers (NBR) via solution and melt mixing methods. The synthesized NBR-GOAu nanocomposites have shown significant improvements in their rate of curing, mechanical strength, thermal stability and electrical properties. The homogeneous dispersion of GOAu nanoparticles in NBR has been considered responsible for the enhanced thermal conductivity, thermal stability, and mechanical properties of NBR nanocomposites. In addition, the NBR-GOAu nanocomposites were able to show a decreasing trend in their dielectric constant (${\varepsilon}^{\prime}$) and electrical resistance on straining within a range of 10-70%. The decreasing trend in ${\varepsilon}^{\prime}$ is attributed to the decrease in electrode and interfacial polarization on straining the nanocomposites. The decreasing trend in electrical resistance in the nanocomposites is likely due to the attachment of Au nanoparticles to the surface of GO sheets which act as electrical interconnects. The Au nanoparticles have been proposed to function as ball rollers in-between GO nanosheets to improve their sliding on each other and to improve contacts with neighboring GO nanosheets, especially on straining the nanocomposites. The NBR-GOAu nanocomposites have exhibited piezoelectric gauge factor (${GF_{\varepsilon}}^{\prime}$) of ~0.5, and piezo-resistive gauge factor ($GF_R$) of ~0.9 which clearly indicated that GOAu reinforced NBR nanocomposites are potentially useful in fabrication of structural, high temperature responsive, and stretchable strain-sensitive sensors.

Mn-Modified PMN-PZT [Pb(Mg1/3Nb2/3)O3-Pb(Zr,Ti)O3] Single Crystals for High Power Piezoelectric Transducers

  • Oh, Hyun-Taek;Lee, Jong-Yeb;Lee, Ho-Yong
    • Journal of the Korean Ceramic Society
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    • v.54 no.2
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    • pp.150-157
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    • 2017
  • Three types of piezoelectric single crystals [PMN-PT (Generation I $[Pb(Mg_{1/3}Nb_{2/3})O_3-PbTiO_3]$), PMN-PZT (Generation II $[Pb(Mg_{1/3}Nb_{2/3})O_3-Pb(Zr,Ti)O_3]$), PMN-PZT-Mn (Generation III)] were grown by the solid-state single crystal growth (SSCG) method, and their dielectric and piezoelectric properties were measured and compared. Compared to (001) PMN-PT and PMN-PZT single crystals, the (001) PMN-PZT-Mn single crystals exhibited a higher transition temperature between the rhombohedral and tetragonal phases ($T_{RT}=144^{\circ}C$), as well as a higher coercive electric field ($E_C=6.3kV/cm$) and internal bias field ($E_I=1.6kV/cm$). The (011) PMN-PZT-Mn single crystals showed the highest coercive electric field ($E_C=7.0kV/cm$), and the highest stability of $E_C$ and $E_I$ during 60 cycles of polarization measurement. These results demonstrate that both Mn doping (for higher electromechanical quality factor ($Q_m$)) and a (011) crystallographic orientation (for higher coercive electric field and stability) are necessary for high power transducer applications of these piezoelectric single crystals. Specifically, the (011) PMN-PZT-Mn single crystal (Gen. III) had the highest potential for application in the fields of SONAR transducers, high intensity focused ultrasound (HIFU), ultrasonic motors, and others.

Corrosion Behavior of As-Cast and Solution-Treated AZ91-4%RE Magnesium Alloy (주조 상태 및 용체화처리한 AZ91-4%RE 마그네슘 합금의 부식 거동)

  • Han, Jin-Gu;Hyun, Soong-Keun;Jun, Joong-Hwan
    • Journal of the Korean Society for Heat Treatment
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    • v.31 no.5
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    • pp.220-230
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    • 2018
  • The objective of this study is to investigate the effect of solution treatment on the microstructure and corrosion behavior of cast AZ91-4%RE magnesium alloy. In the as-cast state, microstructure of the AZ91-4%RE alloy was characterized by intermetallic ${\beta}(Mg_{17}Al_{12})$, $Al_{11}RE_3$ and $Al_2RE$ phase particles distributed in ${\alpha}-(Mg)$ matrix. After solution treatment, the ${\beta}$ particles with low melting point dissolved into the matrix, but Al-RE phases still remained due to their high thermal stabilities. It was found from the immersion and potentiodynamic polarization tests that corrosion rate of the AZ91-4%RE alloy increased after the solution treatment. On the contrary, EIS tests and EDS compositional analyses on the surface corrosion products indicated that the stability of the corrosion product was improved after the solution treatment. Examinations on the corroded microstructures for the ascast and solution-treated samples revealed that dissolution of the ${\beta}$ particles which play a beneficial role in suppressing corrosion propagation, would be responsible for the deterioration of corrosion resistance after the solution treatment. This result implies that the microstructural features such as amount, size and distribution of secondary phases that determine corrosion mechanism, are more influential on the corrosion rate in comparison with the stability of surface corrosion product.

Electrochemical Characteristics of Solid Polymer Electrode Fabricated with Low IrO2 Loading for Water Electrolysis

  • Ban, Hee-Jung;Kim, Min Young;Kim, Dahye;Lim, Jinsub;Kim, Tae Won;Jeong, Chaehwan;Kim, Yoong-Ahm;Kim, Ho-Sung
    • Journal of Electrochemical Science and Technology
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    • v.10 no.1
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    • pp.22-28
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    • 2019
  • To maximize the oxygen evolution reaction (OER) in the electrolysis of water, nano-grade $IrO_2$ powder with a low specific surface was prepared as a catalyst for a solid polymer electrolyte (SPE) system, and a membrane electrode assembly (MEA) was prepared with a catalyst loading as low as $2mg\;cm^{-2}$ or less. The $IrO_2$ catalyst was composed of heterogeneous particles with particle sizes ranging from 20 to 70 nm, having a specific surface area of $3.8m^2g^{-1}$. The anode catalyst layer of about $5{\mu}m$ thickness was coated on the membrane (Nafion 117) for the MEA by the decal method. Scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS) confirmed strong adhesion at the interface between the membrane and the catalyst electrode. Although the loading of the $IrO_2$ catalyst was as low as $1.1-1.7mg\;cm^{-2}$, the SPE cell delivered a voltage of 1.88-1.93 V at a current density of $1A\;cm^{-2}$ and operating temperature of $80^{\circ}C$. That is, it was observed that the over-potential of the cell for the oxygen evolution reaction (OER) decreased with increasing $IrO_2$ catalyst loading. The electrochemical stability of the MEA was investigated in the electrolysis of water at a current density of $1A\;cm^{-2}$ for a short time. A voltage of ~2.0 V was maintained without any remarkable deterioration of the MEA characteristics.