• Title/Summary/Keyword: Plastic Viscosity

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A Laboratory Study on Rheological Properties of Fluid Mud (머드유동층의 유동학적 특성에 관한 실험적 연구)

  • Nguyen, Dinh Phuc;Jung, Eui-Taek;Park, Kun-Chul;Hwang, Kyu-Nam
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.24 no.3
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    • pp.203-209
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    • 2012
  • In this study, rheological properties of kaolinite and three different porcelain fluid muds are quantitatively estimated with the latest rheometer, in which variations of their viscosities and yield stresses with their densities are estimated. This study also involves the measurements for the basic physico-chemical properties of fluid muds and the qualitative analysis of their correlation between physico-chemical and rheological properties. Experimental results of rheological tests show that fluid muds in general belong to Pseudo-plastic fluids and both viscosities and yield stresses of them increase exponentially with the increase of density while they are remarkably different in quantity depending on sediments.

Poly(1,2-propylene glycol adipate) as an Environmentally Friendly Plasticizer for Poly(vinyl chloride) (폴리염화비닐의 친환경 가소제로서 Poly(1,2-propylene glycol adipate))

  • Zhao, Yan;Liang, Hongyu;Wu, Dandan;Bian, Junjia;Hao, Yanping;Zhang, Guibao;Liu, Sanrong;Zhang, Huiliang;Dong, Lisong
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.247-255
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    • 2015
  • Poly(1,2-propylene glycol adipate) (PPA) was used as an environmentally friendly plasticizer in flexible poly(vinyl chloride) (PVC). Thermal, mechanical, and rheological properties of the PVC/PPA blends were characterized by differential scanning calorimetry, dynamic mechanical analysis, tensile test, scanning electron microscopy and small amplitude oscillatory shear rheometry. The results showed that PPA lowered the glass transition temperature of PVC. The introduction of PPA could decrease tensile strength and Young's modulus of the PVC/PPA blends; however, elongation-at-break was dramatically increased due to the plastic deformation. The plasticization effect of PPA was also manifested by the decrease of dynamic storage modulus and viscosity in the melt state of the blends. The results indicated that PPA had a good plasticizing effect on PVC.

Effect of Solvents on Physical Properties and Release Characteristics of Monolithic Hydroxypropylmethylcellulose Matrix Granules and Tablets

  • Cao Qing-Ri;Choi Yun-Woong;Cui Jing-Hao;Lee Beom-Jin
    • Archives of Pharmacal Research
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    • v.28 no.4
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    • pp.493-501
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    • 2005
  • Effect of solvents on physical characteristics and release characteristics of monolithic acetaminophen (APAP) hydroxypropylmethylcellulose (HPMC) matrix granules and tablets were examined. Various types and amounts of solvents were employed for granulation and coating. APAP and other excipients were mixed and were then wet-granulated in a high-speed mixer. The dried granules were then directly compressed and film-coated with low viscosity grade HPMC. As the amount of water increased, the size of granules also increased, showing more spherical and regular shape. However, manufacturing problems such as capping and lamination in tableting occurred when water was used alone as a granulating solvent. The physical properties of HPMC matrix granules were not affected by the batch size. The initial release rate as well as the amount of APAP dissolved had a tendency to decrease as the water level increased. Addition of nonaqueous solvent like ethanol to water resulted in good physical properties of granules. When compared to water/ethanol as a coating solvent, the release rate of film-coated HPMC matrix tablets was more sensitive to the conditions of coating and drying in methylene chloride/ethanol. Most of all, monolithic HPMC matrix tablet when granulated in ethanol/water showed dual release with about $50\%$ drug release immediately within few minutes followed by extended release. It was evident that the type and amount of solvents (mainly water and ethanol) were very important for wet granulation and film-coating of monolithic HPMC matrix tablet, because the plastic deforming and fragmenting properties of material were changed by the different strengths of the different solvents.

An Experimental Study on the Concrete Pumping Technology of High Performance Concrete for the High-Rise Building Construction (초고층 구조물 시공을 위한 고성능 콘크리트의 펌프압송 기술에 관한 실험적 연구)

  • Kim, Gyu-Dong;Han, Cheon-Goo
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.4
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    • pp.375-381
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    • 2015
  • In this study, high performance concrete of C60 and C80 were applied to a super tall building and those had satisfactory properties of fresh and hardened concrete to the requirements even changes according to time. Especially the evaluation and analysis of the relation of the rheological properties and puMPability of high performance concrete, C60-14 which was applied to the height of from 500m to 575m in the building, was carried out bymeasuring pumping pressure and pumping speed, testing concrete properties at before and after pumping. As results, themax. pumping pressure showed increase of 5% at every 25m higher pumping and the average pumping speed showed the above $25m^3$ per hour whichmeans proper productivity. Additionally it was verified that the loss of slump flow after pumping was increased according to plastic viscosity values and the increment of temperature through concrete pumping.

A Study on the Initial Shear Strength Characteristics of Sudden Gelation Grout (순결형 그라우트의 초기 전단강도 특성에 대한 연구)

  • Heo, Hyung-Seok;Park, Inn-Joon
    • Journal of the Korean Geotechnical Society
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    • v.36 no.9
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    • pp.33-44
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    • 2020
  • In order to analyze the shear strength characteristics of the grout with sudden gelation in the pre-hardening state, the viscosity of the mixture and the indoor vane shear test were performed. The grout was prepared according to the water-cement (w/c) ratio and the shear strength test was conducted. The plastic-state shear strength of grout was affected by the w/c ratio, so the lower the w/c ratio, the higher the initial shear strength was, and the longer the curing time was, the higher the shear strength was. The maximum shear strength occurred at the faster rotation angle as the higher shear strength was developed, and the lower shear strength occurred at the larger rotation angle. In addition, it was confirmed that the pre-hardening grout rapidly decreased in strength after the maximum shear strength was gained, and converged at a certain level after the rotation angle of the vane blade was about 70° to 90°.

Diffusion-hydraulic properties of grouting geological rough fractures with power-law slurry

  • Mu, Wenqiang;Li, Lianchong;Liu, Xige;Zhang, Liaoyuan;Zhang, Zilin;Huang, Bo;Chen, Yong
    • Geomechanics and Engineering
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    • v.21 no.4
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    • pp.357-369
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    • 2020
  • Different from the conventional planar fracture and simplified Newton model, for power-law slurries with a lower water-cement ratio commonly used in grouting engineering, flow model in geological rough fractures is built based on ten standard profiles from Barton (1977) in this study. The numerical algorithm is validated by experimental results. The flow mechanism, grout superiority, and water plugging of pseudo plastic slurry are revealed. The representations of hydraulic grouting properties for JRCs are obtained. The results show that effective plugging is based on the mechanical mechanisms of the fluctuant structural surface and higher viscosity at the middle of the fissure. The formulas of grouting parameters are always variable with the roughness and shear movement, which play a key role in grouting. The roughness can only be neglected after reaching a threshold. Grouting pressure increases with increasing roughness and has variable responses for different apertures within standard profiles. The whole process can be divided into three stationary zones and three transition zones, and there is a mutation region (10 < JRCs < 14) in smaller geological fractures. The fitting equations of different JRCs are obtained of power-law models satisfying the condition of -2 < coefficient < 0. The effects of small apertures and moderate to larger roughness (JRCs > 10.8) on the permeability of surfaces cannot be underestimated. The determination of grouting parameters depends on the slurry groutability in terms of its weakest link with discontinuous streamlines. For grouting water plugging, the water-cement ratio, grouting pressure and grouting additives should be determined by combining the flow conditions and the apparent widths of the main fracture and rough surface. This study provides a calculation method of grouting parameters for variable cement-based slurries. And the findings can help for better understanding of fluid flow and diffusion in geological fractures.

The Effect of the Self-Healing Microcapsules on the Quality and Healing Properties of Cement Composites (자기치유 마이크로캡슐이 시멘트 복합재료의 품질 및 치유특성에 미치는 영향)

  • Kim, Cheol-Gyu;Oh, Sung-Rok;Kim, Ji-Hun;Choi, Yun-Wang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.389-396
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    • 2021
  • In this paper, it was evaluated that the effect of self-healing microcapsules on the quality and healing properties of cement composites. In the mixing of microcapsules, the plastic viscosity and yield stress of the cement composites decreased due to the particle properties of the microcapsules, and decreased in proportion to the mixing ratio. The table flow showed a tendency to decrease as the core material acted as a stimulant due to the loss of microcapsules, and the compressive strength could be supplemented through unit quantity correction. As a result of evaluating the effect of microcapsule mixing on the healing properties of cement composites, it was found that the unit water flow rate decreased by the healing reaction immediately after crack initiation. When more than 3% of microcapsules were mixed, it was found that there was a healing rate of more than 95% at 7 days of healing age.

Quality and Long-tern Aged Healing Properties of Self-healing Surface Protection Materials Using Solid Capsules (고상캡슐을 활용한 자기치유 표면보호재의 품질 및 장기재령 치유특성)

  • Oh, Sung-Rok;Nam, Eun-Joon;Kang, Shin-Taeg;Choi, Yun-Wang
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.397-404
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    • 2021
  • In this study, it was reviewed that the effect of solid capsules on the quality of surface repair materials and the healing properties of long-term aging, as part of a study to utilize self-healing surface repair materials using solid capsules as repair materials. As a result of evaluation of the rheological properties of self-healing surface repair materials according to the mixing of solid capsules, plastic viscosity, yield stress, and table flow tended to decrease. In the case of compressive strength, 1MPa per 1% of the solid capsule decreased proportionally. As a result of evaluating the long-term healing properties, when 10% of solid capsules were mixed, a healing rate of 90% was shown at 28 days of healing, because the solid capsule was preserved even after 91 days of age had elapsed. after 91 days of healing, even in the case of 5% of solid capsules, a healing rate of 90% was shown.

A Basic Study on the Marine Anti-Fouling Coating Using Cellulose Nanofiber (셀룰로오스 나노섬유를 활용한 해양 방오 코팅제에 관한 기초 연구)

  • Jang, Nag-Seop;Kim, Tae-Kyun;Oh, Hong-Seob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.469-477
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    • 2021
  • In this study, the mechanical property of anti-fouling coating using CNF was evaluated to prevent the durability and stability of structure exposed the marine environment. Anti-fouling coating using CNF was prepared by CNF, AKD and waste glass powder, and contact angle test, drying time, viscosity analysis and microstructure were performed. When coating on one number of times, It was showed to relatively high hydrophobic performance in steel. And It was confirmed that the contact angle increased as the content of AKD increased in cement mortar. When coating on three number of times, the surface was confirmed super-hydrophobic at maximum of 151.6°. When mixing waste glass powder, the surface was showed to relatively high hydrophobic. It is pseudo plastic fluid when CNF and distilled water were prepared in a ratio of 1:1, And Anti fouling coating is judged to be suitable for use as coating on marine structure.

Performance of self-compacting concrete with manufactured crushed sand

  • Benyamina, Smain;Menadi, Belkacem;Bernard, Siham Kamali;Kenai, Said
    • Advances in concrete construction
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    • v.7 no.2
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    • pp.87-96
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    • 2019
  • Self-compacting concretes (SCC) are highly fluid concrete which can flow without any vibration. Their composition requires a large quantity of fines to limit the risk of bleeding and segregation. The use of crushed sand rich in limestone fines could be an adequate solution for both economic and environmental reasons. This paper investigates the influence of quarry limestone fines from manufactured crushed sand on rheological, mechanical and durability properties of SCC. For this purpose, five mixtures of SCC with different limestone fines content as substitution of crushed sand (0, 5, 10, 15 and 20%) were prepared at constant water-to-cement ratio of 0.40 and $490kg/m^3$ of cement content. Fresh SCC mixtures were tested by slump flow test, V-funnel flow time test, L-box height ratio, segregation resistance and rheological test using a rheometer. Compressive and flexural strengths of SCC mixtures were evaluated at 28 days. Regarding durability properties, total porosity, capillary water absorption and chloride-ion migration were studied at 180 days. For the two test modes in fresh state, the results indicated compatibility between slump flow/yield stress (${\tau}_0$) and V-funnel flow time/plastic viscosity (${\mu}$). Increasing the substitution level of limestone fines in SCC mixtures, contributes to the decrease of the slump flow and the yield stress. All SCC mixtures investigated achieved adequate filling, adequate passing ability and exhibit no segregation. Moreover, the inclusion of limestone fines as crushed sand substitution reduces the capillary water absorption, chloride-ion migration and consequently enhances the durability performance.