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http://dx.doi.org/10.7317/pk.2015.39.2.247

Poly(1,2-propylene glycol adipate) as an Environmentally Friendly Plasticizer for Poly(vinyl chloride)  

Zhao, Yan (Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry)
Liang, Hongyu (Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry)
Wu, Dandan (Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry)
Bian, Junjia (Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry)
Hao, Yanping (Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry)
Zhang, Guibao (Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry)
Liu, Sanrong (Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry)
Zhang, Huiliang (Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry)
Dong, Lisong (Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry)
Publication Information
Polymer(Korea) / v.39, no.2, 2015 , pp. 247-255 More about this Journal
Abstract
Poly(1,2-propylene glycol adipate) (PPA) was used as an environmentally friendly plasticizer in flexible poly(vinyl chloride) (PVC). Thermal, mechanical, and rheological properties of the PVC/PPA blends were characterized by differential scanning calorimetry, dynamic mechanical analysis, tensile test, scanning electron microscopy and small amplitude oscillatory shear rheometry. The results showed that PPA lowered the glass transition temperature of PVC. The introduction of PPA could decrease tensile strength and Young's modulus of the PVC/PPA blends; however, elongation-at-break was dramatically increased due to the plastic deformation. The plasticization effect of PPA was also manifested by the decrease of dynamic storage modulus and viscosity in the melt state of the blends. The results indicated that PPA had a good plasticizing effect on PVC.
Keywords
poly(vinyl chloride); poly(1,2-propylene glycol adipate); plasticizer; blends; mechanical properties;
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  • Reference
1 M. Khan and F. Kanwal, J. Chem. Soc. Pakistan., 19, 8 (1997).
2 M. Rahman and C. S. Brazel, Prog. Polym. Sci., 29, 1223 (2004).   DOI   ScienceOn
3 Y. S. Soong, R. E. Cohen, and M. C. Boyce, Ploymer, 48, 1410 (2007).   DOI   ScienceOn
4 A. Lindstrom and M Hakkarainen, J. Appl. Polym. Sci., 100, 2180 (2006).   DOI   ScienceOn
5 G. Latini, C. D. Felice, and A. Verrotti, Reprod. Toxicol., 19, 27 (2004).   DOI   ScienceOn
6 J. A. Tickner, T. Schettler, T. Guidotti, M. McCally, and M. Rossi, Am. J. Ind. Med., 39, 100 (2001).   DOI
7 European Commission Health & Consumer protection directorate-general, Directorate C-Scientific Opinions, C2. Opinion on Medical Devices Containing DEHP plasticized PVC; Neonates and Other Groups Possibly at Risk from DEHP Toxicity (2002).
8 S. S. Hill, B. S. Shaw, and A. H. B. Wu, Clin. Chim. Acta, 304, 1 (2001).   DOI   ScienceOn
9 G. Latini, C. D. Felice, G. Presta, A. D. Vecchio, I. Paris, F. Ruggieri, and P. Mazzeo, Environ. Health. Persp., 111, 1783 (2003).   DOI
10 N. H. Kleinsasser, U. A. Harreus, E. R. Kastenbauer, B. C. Wallner, A. W. Sassen, R. Staudenmaier, and A. W. Rettenmeier, Toxicol. Lett., 148, 83 (2004).   DOI   ScienceOn
11 L. G. Krauskopf, J. Vinyl Add. Technol., 9, 159 (2003).   DOI   ScienceOn
12 A. Lindstrom and M. Hakkarainen, J. Appl. Polym. Sci., 100, 2180 (2006).   DOI   ScienceOn
13 H. L. Zhang, J. Y. Fang, H. H. Ge, L. J. Han, X. M. Wang, Y. P. Hao, C. Y. Han, and L. S. Dong, Polym. Eng. Sci., 53, 112 (2013).   DOI   ScienceOn
14 X. H. Li, Y. Xiao, B. Wang, Y. Tang; Y. Q. Lu, and C. J. Wang, J. Appl. Polym. Sci., 124, 1737 (2012).   DOI   ScienceOn
15 X. J. Loh, S. H. Goh, and J. Li, Biomacromolecules, 8, 585 (2007).   DOI   ScienceOn
16 B. Yang, Y. Bai, and Y. Cao, J. Appl. Polym. Sci., 115, 2178 (2010).   DOI   ScienceOn
17 A. Marcilla and S. Garcia, J. Anal. Appl. Pyroly., 71, 458 (2004).
18 A. J. Nijenhuis, E. Colstee, D. W. Grijpma, and A. J. Pennings, Polymer, 37, 5849 (1996).   DOI   ScienceOn
19 A. Agrawal, A. D. Saran, S. S. Rath, and A. Khanna, Polymer, 45, 8603 (2004).   DOI   ScienceOn
20 B. L. Shah and V. V. Shertukde, J. Appl. Polym. Sci., 90, 3278 (2003).   DOI   ScienceOn
21 N. Kakuta, J. Mater. Cycles Waste Manag., 11, 23 (2009).   DOI
22 Y. B. Liu, W. Q. Liu, and M. H. Hou, Polym. Degrad. Stabil., 92, 1565 (2007).   DOI   ScienceOn