• 한국전기전자재료학회논문지
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• 제25권7호
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• pp.552-557
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• 2012

In this study, we have coated the inner surface of YSZ channel using LSM powder ink through depressurization process for making the cathode of a stacked planar-type SOFC module. To coat the surface of YSZ channel uniformly, we tried to find the optimum manufacturing condition for LSM ink. We used four different dispersants (BYK series) and two different solvents (ethanol and DMF) to make the LSM ink. It was revealed that the ink made with the ethanol solvent and the BYK-111 dispersant has the lowest viscosity, relatively low contact angle and most excellent dispersibility. After depressurizing a chamber filled with LSM ink and sintered YSZ channel, we have found that the YSZ channel was uniformly coated with LSM cathode. The LSM ink with 25 vol% BYK-111 showed the most uniform coating.

• 신재생에너지
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• 제2권2호
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• pp.44-49
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• 2006

본 연구는 독일 율리히 연구소에서 도입된 면적 200mm*200mm의 연료극 지지체 평판형 SOFC 셀 및 금속 분리판 5장을 적층하여 500W급 SOFC 스택을 제작하고, 이러한 스택의 운전특성을 분석한 연구이다. 도입된 500W급 SOFC 스택은 가스터빈-연료전지 하이브리드 시스템어에 사용되는 5kW급 SOFC 스택의 예비실험을 위한 것으로서, 본 연구의 목적은 상압 운전특성을 바탕으로 외국에서 시도된 적이 없는 평판형 SOFC 스택의 가압 운전기술을 확보하는 것이다. 이러한 목적을 위해 본 연구에서는 상압형 500W급 SOFC 발전시스템에 대한 구성과 설계, 전반적인 운전 특성평가 (5셀 스택 운전, 연료 전환 $(H_2{\rightarrow}pre-reformed\;gas)$, 500 시간 연속운전 등)가 이뤄졌다.

• 대한기계학회논문집B
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• 제27권5호
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• pp.635-643
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• 2003

Parametric study for the analysis of performance characteristics of a planar -type solid oxide fuel cell(SOFC) using computational flow analysis is conducted. A planar -type SOFC, which is composed by two gas channels (fuel and ai.) and one set of anode-electrolyte-cathode assembly, is modeled as a two -dimensional isothermal case. Results of computational analysis of flow field including distributions of mass fractions in gas channels are used to the performance analysis of the fuel cell. Flow analysis makes it possible to consider current density distributions along the length of the cell in the process of performance analysis of the SOFC. As results of parametric study, it is found that the mole fraction of fuel at the inlet of fuel channel, operating pressure and temperature are closely related to the performance characteristics of SOFC.

• 한국전기전자재료학회논문지
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• 제25권3호
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• pp.241-246
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• 2012

A layered planer SOFC module was designed from planar-type SOFC. It was prepared by multi-layered ceramic technology. To form the cathode and the anode in the layered structure, reliable channels should be made on the both side of electrolyte perpendicularly. However, monolithic SOFC using multi-layered ceramic technology hasn't been studied another group, and the warpage of electrolyte in the channel, also, hasn't been studied, when electrode is printed on the electrolyte. In this study, the channels are prepared with electrode printing, and their warpage are evaluated. In the case of YSZ without electrode, the warpages are nothing in the limit of measurement using optical microscope. The warpage of 'YSZ-NiO printed' increases than that of 'NiO printed', and also, the case of 'double electrode printed' is similar to 'YSZ-NiO printed'. It is thought that, in the printed electrolyte, the warpage is related to the difference of the sintering behavior of each material.

• 한국수소및신에너지학회논문집
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• 제28권6호
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• pp.657-662
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• 2017

This paper presents the reversible electrolysis characteristics of a solid oxide fuel cell (SOFC) using a $10{\times}10cm^2$ anode supported planar cell with an active area of $81cm^2$. In this work, current-voltage characteristic test and reversible electrolysis cycle test were carried out sequentially for 2,114 hours at a furnace temperature of $700^{\circ}C$. The current-voltage characteristics for reversible electrolysis mode was measured at a current of ${\pm}26.7A$ under various $H_2O$ utilization conditions. The reversible electrolysis cycle was performed 50 times at a current of ${\pm}32.4A$. As a result, The performance degradation of SOEC mode was larger than that of SOFC mode.

• 한국전기전자재료학회논문지
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• 제27권12호
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• pp.866-870
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• 2014

In solid oxide fuel cell system, yttria-stabilized zirconia is generally adopted as the electrolyte, which has high strength and superior oxygen ion conductivity, and the air electrode and the fuel electrode are attached to this. Recently, new structure of 'layered planar SOFC module' was suggested to solve the reliability problem due to the high temperature stability of a sealing agent and a binding material. In this study to materialize the air electrode in a layered planar SOFC module, the LSM ink was coated to form homogeneous electrode in the channel after the ink preparation. As the porosity control agent, PMMA or active carbon powder was adopted with use of a commercial dispersant in ethanol. The optimal amounts of both the porosity control agents and the dispersant were determined. Four (4) vol% of the dispersant for the LSM-PMMA case and 15 vol% for LSM-carbon powder showed the lowest viscosities respectively to indicate the best dispersed states of the slurries. With PMMA and carbon powder, sintered LSM ink shows the relatively homogeneous distributions of pores and with increases of the agents, the porosities increased in both cases. From this, it can be thought that the amount of the PMMA or carbon powder could be used to control the porosity of the LSM ink.

• 대한기계학회논문집B
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• 제41권2호
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• pp.109-115
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• 2017

전산유체해석(CFD) 기법을 이용하여 음극 지지체형 고체산화물 연료전지(SOFC)에 대한 수치해석을 수행하였다. 평판형 구조의 SOFC 에서 가스채널과 리브폭 변화에 따른 성능과 온도균일성에 관한 연구가 이루어졌다. 전산해석 툴로서는 공개소스 전산유체해석 툴박스인 OpenFOAM 을 이용하였다. 수치해석결과, 산소고갈이 일어나지 않는 범위 내에서 가스채널과 리브폭의 증가는 성능과 온도 균일성에 크게 영향을 미치지 않음을 알 수 있었다. 하지만 넓은 리브폭의 사용과 고전류밀도에서의 작동은 산소고갈로 인한 성능저하의 가능성이 있음을 확인하였다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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• pp.57-60
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• 2008

KEPRI has studied planar type SOFC stacks using anode-supported single cells and kW class co-generation systems for residential power generation. A 1kW class SOFC system consisted of a hot box part, a cold BOP part and a water reservoir. A hot box part contains a SOFC stack made up of 48 single cells and ferritic stainless steel interconnectors, a fuel reformer, a catalytic combustor and heat exchangers. Thermal management and insulation system were especially designed for self-sustainable operation. A cold BOP part was composed of blowers, pumps, a water trap and system control units. When a 1kW class SOFC system was operated at $750^{\circ}C$ with hydrogen after pre-treatment process, the stack power was 1.2kW at 30 A and 1.6kW at 50A. Turning off an electric furnace, the SOFC system was operated using hydrogen and city gas without any external heat source. Under self-sustainable operation conditions, the stack power was about 1.3kW with hydrogen and 1.2kW with city gas respectively. The system also recuperated heat of about 1.1kW by making hot water.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.83.2-83.2
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• 2010

평판형 고체산화물 연료전지(planar SOFC : Solid oxide Fuelcell)는 높은 전류 효율 및 출력밀도를 가지는 중,대형 발전용 전기소자이다. SOFC 스택을 600~800도에서 작동할 경우, 금속 분리판에서 휘발된 크롬에 의한 열화현상과 금속의 산화에 의한 표면 저항의 증가가 큰 문제점으로 알려져 있으며, 이를 개선하기 위한 많은 연구가 진행되고 있다. 본 연구에서는 금속 분리판의 열화를 억제하기 위한 여러 보호코팅의 특성을 밝히고, 특성차이의 원인을 분석하고자 하였다. 모재는 상용 STS444합금 (Nisshin steel 생산) 2.0mmt 박판을 사용하였으며, 표면 상태를 균일하게 하기 위하여 표면은 동일한 #1200 번 사포로 연마후 코팅하였다. 적용한 코팅은 전기도금 Ni 코팅, (MnCo)3O4 wet powder spray 코팅, (MnCo)3O4 ADM코팅 3종이었으며, 코팅층의 두께는 최적 공정조건에 따라 달리 하였다. 산화후 형성되는 표면 산화물의 전기적 특성을 평가하기 위하여 시험편의 비면적 저항 (ASR : area specific resistance)을 장시간 측정하였다. 측정편의 크기는 가로 4cm ${\times}$ 세로 4cm였으며, 100시간 공기중 산화후 측정하였다. 표면 접촉을 높이기 위하여 Pt paste를 40~50um도포하였으며, 1~0.1A인가된 전류에 대한 저항을 4전극법 (4-probe)으로 측정하였다. 표면 코팅층이 크롬 휘발을 억제하는 정도를 평가하기 위하여 크롬 휘발량을 측정하였다. 시편은 가로 1.5cm ${\times}$ 세로 1cm 였으며, 공급된 공기와 수분의 혼합가스와 응축기 표면에 흡착된 크롬의 양을 ICP-MASS법으로 측정하였다.

• 대한기계학회논문집B
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• 제27권7호
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• pp.963-972
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• 2003

Performance characteristics of the planar-type solid oxide fuel cell (SOFC) are investigated by the analysis of flow fields coupled with heat and mass transfer phenomena in anode and cathode channels. For these purposes, performance analysis of the SOFC is conducted based on electrochemical reaction phenomena in electrodes and electrolyte coupled with flow fields in anode and cathode channels. In the present study, the isothermal model adopted in the previous paper prepared by the same authors is extended to the non-isothermal model by solving energy equation additionally with momentum and mass transfer equations using CFD technique. It is found that the difference between isothermal and non-isothermal models come from non-uniform temperature distribution along anode and cathode electrodes by solving energy equation in non-isothermal model. Non-uniform temperature distribution in non-isothermal model contributes to the increase of average temperature of the fuel cell and influences its performance characteristics.