• Journal of Advanced Marine Engineering and Technology
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• 제29권5호
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• pp.495-501
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• 2005

Al is a active metal that owes its resistance to a thin, protective, barrier oxide surface layer, which is stable in air and neutral aqueous solution. Thus Al alloys are widely used in architectural trim. cold & hot-water storage vessels and piping. However Al and most of its alloy may corrode with some forms such as pitting corrosion, intergranular corrosion and galvanic corrosion in the case of exposure to various industrial and marine atmosphere. Therefore a correct evaluation of corrosion resistance for their Al and Al alloys may be more important in a economical point of view. In this study. a relative evaluation of corrosion resistance for three kinds of Al alloys such as ALDC2, ALDC3, and ALDC8 series was carried out with electrochemical method. There is a tendency that corrosion potential is shifted to positive or negative direction by alloying components regardless of corrosion resistance. Moreover the data of corrosion properties obtained from cathodic Polarization curve, cyclic voltammogram and AC. DC impedance respectively showed a good correspondence each other against the corrosion resistance but variation of corrosion potential. passivity current density of anodic polarization curve and corrosion current density by Tafel extrapolation and Stern-Geary method didn't correspond with not only each other but also considerably the data of corrosion properties discussed above. Therefore it is suggested that an optimum electrochemical evaluation for corrosion resistance of Al alloy is to calculate the diffusion limiting current density of cathodic polarization curve, impedance of AC or DC and polarization resistance of cyclic voltammogram.

• International Journal of Concrete Structures and Materials
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• 제9권2호
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• pp.173-183
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• 2015

Most of the diffusion models of chloride ions in reinforced concrete (RC) elements proposed in literature are related to an isotropic homogeneous semi-infinite medium. This assumption reduces the mathematical complexity, but it is correct only for plane RC elements. This work proposes a comparison between the diffusion model of chloride ions in RC circular columns and in RC slab elements. The durability of RC cylindric elements estimated with the circular model instead of the plane model is shown to be shorter. Finally, a guideline is formulated to properly use the standard and more simple plane model instead of the circular one to estimate the time to corrosion initiation of cylindrical RC elements.

• 한국자동차공학회논문집
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• 제18권5호
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• pp.25-30
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• 2010

The authors have studied on the corrosion resistance of the hot stamped steel sheets for the application to automotive parts. Recently automotive companies have focused on the hot stamped parts to meet the light weighting needs and the safe reason. Because of the cost reduction of the hot stamped parts, automotive companies increase the usage of the coated steel sheets, especially Al-Si coated steel sheets. The coated layer of Al-Si coated steel sheets contains up to 50% of Fe, which was diffused from the steel sheet, after hot stamping. The hot stamped steel sheet was not phosphated due to the oxidation layer of the coating, however, the result of the water resistance test is similar to that of the conventional GA steel sheets. The pitting depth and the weight reduction of the coated layer of hot stamped steel sheets are less than those of GA steel.

• Journal of Advanced Marine Engineering and Technology
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• 제19권4호
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• pp.42-50
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• 1995

To study the effect of welding methods on the Stress Corrosion Cracking (SCC) behavior of welded AISI type 316L and 304 austenitic stainless steel, the Slow Strain Rate Technique(SSRT) has been adopted in the boiling 45 wt% $MgCl_2$ solution. The results are as follows. 1) Welded sections are more susceptible than base metal in SCC, and the rank of SCC, and the rasistance in welding method is TIG, MIG, $CO_2$ and ARC. 2) The Ultimate tensile strength(UTS) and the strain of both base metal and welded joint are reduced as decreasing extension rate. 3) The SCC resistance of 316L base metal and welded sections are superior than that of 304. 4) The tendency of pitting and the SCC suseptibility are agreed well, and the SCC site is welded deposit section in 316L whereas HAZ in 304.

• Corrosion Science and Technology
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• 제15권4호
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• pp.153-158
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• 2016

Light metal alloys of Mg, Ti, and Al undergo environmentally assisted cracking (EAC). Passive film breakdown and pitting are not only precursor events for stress corrosion, but can accelerate hydrogen evolution that is responsible for hydrogen embrittlement. This is clearly demonstrated in the case of Mg and Ti alloys. The so-called innocuous precipitates, which do not directly participate in either alloy strengthening or EAC can be effective precursors for initiating EAC. This aspect is highlighted using high strength aluminium alloys. Such behaviours lead to a paradigm shift in the design of alloys with resistance to EAC.

• Corrosion Science and Technology
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• 제12권4호
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• pp.163-170
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• 2013

In NaCl solutions acidified with $H_2SO_4$, Fe20Cr1.1N alloy showed enhanced pitting corrosion resistance than Fe20Cr alloy. An XPS analysis revealed that the passive film of Fe20Cr1.1N alloy contained higher cationfraction of Cr than that of Fe20Cr alloy, and nitrogen was incorporated into the film. In addition, it was found that the passive film of Fe20Cr1.1N alloy was thinner and had higher oxygen vacancy density than that of Fe20Cr alloy. Based on these observations, it was concluded that the chemical composition was the determining factor for the protectiveness of the passive film of Fe20Cr based alloy in dilute $H_2SO_4$ solution.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2005년도 제36회 하계학술대회 논문집 전기설비
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• pp.61-63
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• 2005

In present, most of underground metallic structures, especially gas pipeline, have adopted in order to protect against a corrosion. If a coating defect is be on the surface of gas pipeline, the pitting corrosion is occur normally. So, in the corrosion field, investigation of coating defect is very important activity. In this paper, DCVG(Direct Current Voltage Gradient) method which is can detect a coating defect of gas pipeline is introduced. And also, the assesment of coating defect position according to the position of temporary anode of ICCP(Impresed Current Cathodic Protection) system is presented.

• Corrosion Science and Technology
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• 제15권6호
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• pp.265-270
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• 2016

The ellipso-microscopic observation of a titanium surface undergoing anodization in $0.05mol\;dm^{-3}$ of $H_2SO_4$ was conducted. During irradiation by ultra-violet (UV) light with a wavelength of 325 nm, the titanium surface allowed for the flow of a photo-induced current and showed up as a bright, patch-like image on an ellipso-microscopic view. The brightness and patch-pattern in the image changed with flowing photo-induced current. The changes in the brightness and the image corresponded to the formation and/or degradation of titanium oxide due to the photo-electrochemical reaction of the oxide. An in situ monitoring using the ellipso-microscope revealed that the film change was dependent on the irradiation light power, by UV-light increases the anodic current and results in the initiation of pitting at lower potentials as compared with the non-irradiated condition.

• 한국진공학회지
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• 제12권S1호
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• pp.21-27
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• 2003

Micro-arc discharge oxidation (MDO) is a cost-effective plasma electrolytic process which can be used to improve the wear and corrosion resistance of Al-alloy parts by forming a alumina coating on the component surface. However, the MDO coated Al-alloy components often exhibit relatively high friction coefficients and low wear resistance fitted with many counterface materials, additionally, the pitting corrosion for the MDO coated AI-alloy components, especially for a thinner alumina coating, often occurs in atmosphere circumstance due to the porous alumina coats. Therefore, a duplex treatment, combining a MDO coated ahumina thin layer with a TiN coating, prepared by magnetron sputtering (MS), has been investigated. The Vicker's microhardness, pin-on-disc, electrochemical measurement, salt spray, XRD and SEM tests were used to characterize and analyze the treated samples. The work demonstrates that the MDO/MS coated samples have a combination of a very low friction coefficient and good wear resistance as well as corrosion since the micro-holes on alumina coating are partly or fully covered by TiN material.

• 한국표면공학회지
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• 제50권6호
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• pp.432-438
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• 2017

AZ91D casting alloy requires an advanced plasma anodizing processing because large amount of defects are liable to generate during anodization. In this study, plasma electrolytic oxidation (PEO) of AZ91D Mg alloy was conducted by the application of either constant voltage or current using a pulse mode and its effects on pore formation, surface roughness and corrosion resistance were investigated. The PEO films showed a three-layer structure. The PEO film thickness was found to increase linearly with voltage. The surface roughness, Ra, ranged between $0.2{\mu}m$ and $0.3{\mu}m$. The corrosion resistance increased from RN 3.5 to 9.5 by the PEO treatment when evaluated according to the 72 hour salt spray test. The PEO-treated surface exhibited higher pitting potential than the raw material.