• Title/Summary/Keyword: Photo-physical

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A STUDY ON THE EFFECT OF PERMA CURE SYSTEM ON THE PHYSICAL PROPERTIES OF ACRYLIC RESIN SURFACES (광중합(光重合) 활택 경화제가 아크릴 레진 표면에 미치는 물리적 성질에 관한 연구)

  • Bae, Jeong-Sik;Lee, Ho-Yong;Chung, Moon-Kyu
    • The Journal of Korean Academy of Prosthodontics
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    • v.23 no.1
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    • pp.155-164
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    • 1985
  • Acrylic resin has some disadvantages in its physical properties such as a low surface hardness, being easily abraded as well as low degree of impact resistance. To overcome these disavantages, Perma Cure System was introduced in 1981, in which photo polymerizing monomers coated on acrylic resin surface were polymerized. In this study, to observe the effect of Perma Cure System on physical properties of treated surface of different types of acrylic resin, abrasion resistance, surface hardness and surface roughness of 4 different types of resin (Premium, Ortho-jet acrylic, Quick resin, Thermo jel) were tested before and after coating treatment. The conclusions arised from this study are as follows; 1. In all types of resin, the abrasion resistance of coated specimen was higher than that of uncoated specimen, and there was difference in amount of abrasion among the types of coated resin. 2. In all types of resin, the surface hardness of coated specimen was higher than that of uncoated specimen, and there was no difference in surface hardness among the types of coated resin. 3. In all types of resin, surface roughness of coated specimen was lower than that of uncoated specimen, and was different according to the degree of surface roughness before coating treatment in same sort of resin specimen.

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Formulation and ink-jet 3D printability of photo curable nano silica ink (광경화 나노 실리카 잉크의 합성 및 잉크젯 프린팅 적층 특성평가)

  • Lee, Jae-Young;Lee, Ji-Hyeon;Park, Jae-Hyeon;Nahm, Sahn;Hwang, Kwang-Taek;Kim, Jin-Ho;Han, Kyu-Sung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.345-351
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    • 2019
  • Recently, ink-jet printing technology has been applied for various industries such as semiconductor, display, ceramic tile decoration. Ink-jet printing has advantages of high resolution patterning, fast printing speed, high ink efficiency and many attempts have been made to apply functional materials with excellent physical and chemical properties for the ink-jet printing process. Due to these advantages, research scope of ink-jet printing is expanding from conventional two-dimensional printing to three-dimensional printing. In order to expand the application of ink-jet printing, it is necessary to optimize the rheological properties of the ink and the interaction with the substrate. In this study, photo curable ceramic complex ink containing nano silica particles were synthesized and its printability was characterized. Contact angle of the photo curable silica ink were modified by control of the ink composition and the surface property of the substrate. Effects of contact angle on printing resolution and three-dimensional printability were investigated in detail.

ZnO Nanoparticle Based Dye-Sensitized Solar Cells Devices Fabricated Utilizing Hydropolymer at Low Temperature (저온에서 Hydropolymer를 이용한 ZnO 나노입자 염료 감응형 태양전지)

  • Kwon, Byoung-Wook;Son, Dong-Ick;Park, Dong-Hee;Yang, Jeong-Do;Choi, Won-Kook
    • Korean Journal of Materials Research
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    • v.20 no.9
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    • pp.483-487
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    • 2010
  • To fabricate $TiO_2$ nanoparticle-based dye sensitized solar cells (DSSCs) at a low-temperature, DSSCs were fabricated using hydropolymer and ZnO nanoparticles composites for the electron transport layer around a low-temperature ($200^{\circ}C$). ZnO nanoparticle with 20 nm and 60 nm diameter were used and Pt was deposited as a counter electrode on ITO/glass using an RF magnetron sputtering. We investigate the effect of ZnO nanoparticle concentration in hydropolymer and ZnO nanoparticle solution on the photoconversion performance of the low temperature fabricated ($200^{\circ}C$) DSSCs. Using cis-bis(isothiocyanato)bis(2,20 bipyridy1-4,40 dicarboxylato) ruthenium (II) bis-tetrabutylammonium (N719) dye as a sensitizer, the corresponding device performance and photo-physical characteristics are investigated through conventional physical characterization techniques. The effect of thickness of the ZnO photoelectrode and the morphology of the ZnO nanoparticles with the variations of hydropolymer to ZnO ratio on the photoconversion performance are also investigated. The morphology of the ZnO layer after sintering was examined using a field emission scanning electron microscope (FE-SEM). 60 nm ZnO nanoparticle DSSCs showed an incident photon-to-current conversion efficiency (IPCE) value of about 7% higher than that of 20 nm ZnO nanoparticle DSSCs. The maximum parameters of the short circuit current density ($J_{sc}$), the open circuit potential ($V_{oc}$), fill factor (ff), and efficiency ($\eta$) in the 60 nm ZnO nanoparticle-based DSSC devices were 4.93 mA/$cm^2$, 0.56V, 0.40, and 1.12%, respectively.

Preparation and Characterization of Visible Light-Sensitive N-doped TiO2 Using a Sol-gel Method (Sol-gel법을 이용한 백색도가 높은 가시광 응답형 N-doped TiO2 제조 및 특성 평가 연구)

  • Lee, NaRi;Yu, Ri;Kim, Tae Kwan;Pee, Jae-Hwan;Kim, YooJin
    • Journal of Powder Materials
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    • v.24 no.6
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    • pp.477-482
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    • 2017
  • Nitrogen-doped titanium dioxide (N-doped $TiO_2$) is attracting continuously increasing attention as a material for environmental photocatalysis. The N-atoms can occupy both interstitial and substitutional positions in the solid, with some evidence of a preference for interstitial sites. In this study, N-doped $TiO_2$ is prepared by the sol-gel method using $NH_4OH$ and $NH_4Cl$ as N ion doping agents, and the physical and photocatalytic properties with changes in the synthesis temperature and amount of agent are analyzed. The photocatalytic activities of the N-doped $TiO_2$ samples are evaluated based on the decomposition of methylene blue (MB) under visible-light irradiation. The addition of 5 wt% $NH_4Cl$ produces the best physical properties. As per the UV-vis analysis results, the N-doped $TiO_2$ exhibits a higher visible-light activity than the undoped $TiO_2$. The wavelength of the N-doped $TiO_2$ shifts to the visible-light region up to 412 nm. In addition, this sample shows MB removal of approximately 81%, with the whiteness increasing to +97 when the synthesis temperature is $600^{\circ}C$. The coloration and phase structure of the N-doped $TiO_2$ are characterized in detail using UV-vis, CIE Lab color parameter measurements, and powder X-ray diffraction (XRD).

Photoelectrochemical and Hydrogen Production Characteristics of CdS-TiO2 Nanocomposite Photocatalysts Synthesized in Organic Solvent (유기용매상에서 제조된 수소제조용 CdS-TiO2 나노복합 광촉매의 특성 연구)

  • Jang, Jum-Suk;So, Won-Wook;Kim, Kwang-Je;Moon, Sang-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.13 no.3
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    • pp.224-232
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    • 2002
  • CdS-$TiO_2$ nano-composite sol was prepared by the sol-gel method in organic solvents at room temperature and further hydrothermal treatment at various temperatures to control the physical properties of the primary particles. Again, CdS-$TiO_2$ composite particulate films were made by casting CdS-$TiO_2$ sols onto $F:SnO_2$ conducting glass and then heat-treatment at $400^{\circ}C$. Physical properties of these 61ms were further controlled by the surface treatment with $TiCl_4$, aqueous solution. The photo currents and hydrogen production rates measured under the experimental conditions varied according to the $CdS/[CdS+TiO_2]$ mole ratio and the mixed-sol preparation method. For $CdS-TiO_2$ composite sols prepared in IPA, CdS particles were homogeneously surrounded by $TiO_2$ particles. Also, the surface treatment with $TiCl_4$ aqueous solution caused a considerable improvement in the photocatalytic activity, probably as a result of close contacts between the primary particles by the etching effect of $TiCl_4$. It was found that the photoelectrochemical performance of these particulate films could be effectively enhanced by this approach.

NUMERICAL AERODYNAMIC ANALYSIS OF A TRANSONIC COMMERCIAL AIRPLANE ACCORDING TO THE ANGLE OF ATTACK AND MACH NUMBER (천음속 여객기의 받음각과 마하수에 따른 공력 해석)

  • Kim, Y.K.;Kim, S.C.;Choi, J.W.;Kim, J.S.
    • Journal of computational fluids engineering
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    • v.13 no.4
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    • pp.66-71
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    • 2008
  • This research computes the viscous flow field and aerodynamics around the model of a commercial passenger airplane, Boeing 747-400, which cruises in transonic speed. The configuration was realized through the reverse engineering based on the photo scanning measurement. In results, the pressure coefficients at the several wing section on the wing surface of the airplane was described and discussed to obtain the physical meaning. The lift coefficient increased almost linearly up to $17^{\circ}$. Here the maximum lift occurred at $18^{\circ}$ according to the angle of attack. And the minimum drag is expected at $-2^{\circ}$. The maximum lift coefficient occurred at the Mach number 0.89, and the drag coefficient rapidly increased after the Mach number of 0.92. Also shear-stress transport model predicts slightly lower aerodynamic coefficients than other models and Chen's model shows the highest aerodynamic values. The aerodynamic performance of the airplane elements was presented.

PATIAL DISTRIBUTION OF STAR FORMATION ACTIVITY ON NGC 253 BY FIR AND RADIO EMISSION LINES

  • Takahashi, H.;Matsuo, H.;Nakanishi, K.
    • Publications of The Korean Astronomical Society
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    • v.27 no.4
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    • pp.261-262
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    • 2012
  • The aim of this research is to reveal the spatial distribution of the star formation activity of nearby galaxies by comparing CO molecular emission lines with the large area observation in far-infrared (FIR) lines. We report the imaging observations of NGC 253 by FIR forbidden lines via FIS-FTS and CO molecular lines from low to high excitation levels with ASTE, which are good tracers of star forming regions or photo-dissociation regions, especially spiral galaxies, in order to derive the information of the physical conditions of the ambient interstellar radiation fields. The combination of spatially resolved FIR and sub-mm data leads to the star formation efficiency within galaxy. The ratio between the FIR luminosity and molecular gas mass, $L_{FIR}/M_{H_2}$, is expected to be proportional to the number of stars formed in the galaxy per unit molecular gas mass and time. Moreover the FIR line ux shows current star formation activity directly. Furthermore these can be systematic and statistical data for star formation history and evolution of spiral galaxies.

Antioxidant and Skin Anti-Aging Effects of Marigold Methanol Extract

  • Kang, Chul Ho;Rhie, Sung Ja;Kim, Young Chul
    • Toxicological Research
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    • v.34 no.1
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    • pp.31-39
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    • 2018
  • The objective of this study was to evaluate the antioxidant and anti-aging effects of marigold methanol extract (MGME) in human dermal fibroblasts. Total polyphenolic and flavonoid contents in MGME were 74.8 mg TAE (tannic acid equivalent)/g and 85.6 mg RE (rutin equivalent)/g, respectively. MGME ($500{\mu}g/mL$) increased 1,1-diphenyl-2-picryl hydrazyl (DPPH) and 2,2'-azino-3-ethylbenzothiazoline-6-sulfonic acid (ABTS) radical-scavenging, and superoxide dismutase (SOD)-like antioxidant activities by 36.5, 54.7, and 14.8%, respectively, compared with the control. At $1,000{\mu}g/mL$, these activities increased by 63.7, 70.6, and 20.6%, respectively. MGME ($100{\mu}g/mL$) significantly increased the synthesis of type 1 procollagen by 83.7% compared with control treatment. It also significantly decreased Matrix Metalloproteinase-2 (MMP-2) activity and MMP-1 mRNA expression by 36.5% and 69.5%, respectively; however, it significantly increased laminin-5 mRNA expression by 181.2%. These findings suggest that MGME could protect human skin against photo-aging by attenuating oxidative damage, suppressing MMP expression and/or activity as well as by stimulating collagen synthesis.

Synthesis and Properties of New Polymeric Photostabilizers Containing HALS Groups (HALS 그룹을 가진 새로운 고분자형 자외선 안정제의 합성 및 특성)

  • 김한식;채규호
    • Polymer(Korea)
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    • v.25 no.5
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    • pp.625-634
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    • 2001
  • New polymeric photostabilizers containing hindered amine light stabilizer (HALS) were prepared by the reaction of liquid polyisoprene rubber grafted maleic anhydride (MAH) and 2,2,5,6-tetramethyl-4-piperidinol (TMPO). Their chemical composition and physical properties were characterized by titration, GPC and TGA analysis. The effects of polymeric HALS on the photooxidation of the styrene-butadiene rubber were studied from the UV, IR spectral changes, and photo-crosslinking was examined by the measurement of the insoluble fraction. The photooxidation of SBR upon irradiation was inhibited by addition of the new polymeric HALS. The extraction resistance of new polymeric photostabilizer was much better than that of the low molecular weight compound which is prepared by the reaction of MAH and TMPO. The new polymeric HALS ate fairly compatible with the SBR.

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A Study on the Simulation of the Resolution for Ink-Jet Printing (잉크젯 프린팅에서 해상력에 관한 컴퓨터 시뮬레이션 연구)

  • Lee, Ji-Eun;Youn, Jong-Tae;Koo, Chul-Whoi
    • Journal of the Korean Graphic Arts Communication Society
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    • v.28 no.1
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    • pp.51-63
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    • 2010
  • Ink-jet is part of the non impact printing that shooting the ink drop from the nozzle to paper. It is very silence and express good color. There are two types of printing that continuous and drop on demand. But drop on demand process is becoming the mainstream. these days, LCD, PDP is passed more than semiconductor industry. And we expect organic EL, FED as a next display. But product equipment, main component and technology have a gap between an advanced country and us nevertheless physical development. Expecially, previous process part is depended on imports. Ink-jet printing technology that there isn't complicated photo lithography process is attracted, so ink-jet printing resolution is more embossed. But there were not many of ink-jet resolution thesis but ink-jet head or nozzle. Because, to out of the ink from the nozzle is unseeable and hard to experiment. Therefore this thesis was experimented and simulated how can ink-jet printer improved resolution by flow-3d simulation package program.