• Title/Summary/Keyword: Phenolic

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Fabrication of in-situ Formed Namo-Composite Using Polymer Precursor : I. Adsorption Behavior of Polymer Followed $SiO_2$ Surface formation onto Silicon Nitride Surface (폴리머 Precursor를 이용한 in-situ 나노 복합체의 제조 : I. 질화규소 표면에서의 $SiO_2$ 피막형성에 따른 폴리머의 흡착거동)

  • 정연길;백운규
    • Journal of the Korean Ceramic Society
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    • v.37 no.3
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    • pp.280-287
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    • 2000
  • Adsorption behavior and amount of phenolic resin followed silica (SiO2) formation onto silicon nitride(Si3N4) surface were investigated using electrokinetic sonic amplitude (ESA) technique and with UV spectrometer, to fabricate Si3N4/SiC nano-composite based on reaction between SiO2 formed and phenolic resin absorbed onto Si3N4 particle. The amount of SiO2 formed and carbon from phenolic resin absorbed onto Si3N4 surface were calculated quantitatively to adjust the reaction between SiO2 and phenolic resin, resulting in no residual SiO2 and carbon. As a result, pre-heated tempeature for optimized reaction was below 25$0^{\circ}C$, in which there was no residual SiO2 and carbon.

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Phenolic Compounds in Plant Foods: Chemistry and Health Benefits

  • Naczk, Marian;Shahidi, Fereidoon
    • Preventive Nutrition and Food Science
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    • v.8 no.2
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    • pp.200-218
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    • 2003
  • Phenolic compounds in food and plant materials belong to the simple phenols, phenolic acids, coumarins, flavonoids, stilbenes, tannins, lignans and lignins, all of which are considered as secondary plant metabolites. These compounds may be synthesized by plants during normal development or in response to stress conditions. Phenolics are not distributed uniformly in plants. Insoluble phenolics are components of cell walls while soluble ones are present in vacuoles. A cursory account of phenolics of cereals, beans, pulses, fruits, vegetables and oilseeds is provided in this overview. The information on the bioavailability and absorption of plant phenolics remains fragmentary and diverse. Pharmacological potentials of food phenolics ave extensively evaluated. However, there are many challenges that must be overcome in order to fully understand both the function of phenolics in plant as well as their health effects.

Development of Phenolic SMC for The Rail (철도차량 및 지하철 불연 내장재 페놀 SMC 개발)

  • Kim Young-keun;Shin Dong-hyok;Kim Young-min;Park Joung-wuk;Min Jae-Jun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.55-58
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    • 2004
  • Phenolin resin, prepared form phenol and formaldehyde, is one of the oldest thermosetting resins available. Phenolic resins are cured via condensation polymerization with evolution of water, which in molding process is a big problem. The use of phenolic resins in glass fiber composites is growing, primarily due to their low flame spread, low smoke generation and low smoke toxicity properties. SMC of phenolics has been rearched since the 1986. The technology challenge was to match resin viscosity, handling and cure with those for the polyester SMC to avoid any special processing for fabricators and end users. Phenolic SMC was chosen because of the ease of molding to the required shape with light- weight, thin wall structure and with excellent fire protection.

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Through-thickness CTE and Void Content of Carbon Fabric Phenolic Composites with Respect to Compaction (압착에 따른 탄소직물 페놀 복합재의 두께방향 열팽창계수와 기공분율)

  • Kim, Jong-Woon;Kim, Hyong-Geun;Lee, Dai-Gil
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.192-197
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    • 2004
  • The anisotropy in coefficient of thermal expansion (CTE) between the in-plane and out-of-plane of 3-dimensional thick composite structures induces residual stresses and the large void content due to insufficient compaction of fabric composites, which results in low interlaminar strengths. In order to reduce the through thickness CTE and the void content, in this work, carbon fabric phenolic laminates were compacted by pressure generated by autoclave and a compressive jig, from which the through-thickness CTEs and the void contents were measured. From the measurement, it was found that the through-thickness CTE and the void content had different characteristics from ordinary composites due to gas produced during the cure reaction of phenolic resin.

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Comparative Effects of Gamma Irradiation and Ethylene Oxide Fumigation on Antioxidant Activity of White Ginseng Powder (백삼분말의 항산화 활성에 대한 감마선과 에틸렌옥사이드 처리의 영향)

  • 한용남;김선영
    • Journal of Ginseng Research
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    • v.19 no.3
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    • pp.231-236
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    • 1995
  • The antioxidant activity and the pharmacologically active constituents such as nucleosides and phenolic substancs of Panax ginseng C.A. Meyer (white ginseng powder) treated with gamma irradiation (Rl group) and ethylene oxide fumigation (EO group) were compared with those of non-treated ginseng (control group). High performance liquid chromatograms of nucleosides in three groups were similar with each other. The bathochromic effect of phenolic substances at W absorption region tends to be higher for EO group than Rl group. This tendency was also observed in heat treatment of each group. However, the antioxidant activity may have some effects on the labile property of phenolic substances. In summary the gamma-irradiated ginseng was more stable than the ethylene oxide-treated ginseng, but both ginseng samples gave the similar antioxidant activity.

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The Protective Effects of Phenolic Constituents from Gastrodia elata on the Cytotoxicity Induced by KCI and Glutamate

  • Huang, Zhan-Bo;Wu, Zhe;Chen, Fa-Kui;Zou, Li-Bo
    • Archives of Pharmacal Research
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    • v.29 no.11
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    • pp.963-968
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    • 2006
  • Seven phenolic compounds (1-7) were isolated from the tubers of Gastrodia elata. Their structures were elucidated on the basis of MS and NMR spectral data. p-Ethoxymethyl phenyl-O-${\beta}$-D-glucoside (1) was proved to be a new compound, with N-(p-hydroxybenzyl)-adenosine (7) isolated from this plant for the first time. In this study, the protective effects of the six constituents (1-6) on PC12 cells against the cytotoxicity induced by KCI and glutamate were also investigated. The viability of the PC12 cells was significantly enhanced by pretreatment with the six phenolic constituents.

Phenolic Compounds Isolated from Opuntia ficus-indica Fruits

  • Kim, Jung Wha;Kim, Tae Bum;Yang, Heejung;Sung, Sang Hyun
    • Natural Product Sciences
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    • v.22 no.2
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    • pp.117-121
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    • 2016
  • On the phytochemical investigation of a 70% ethanol extract of the fruits of Opuntia ficus-indica, (Cacataceae), we could result in the isolation of thirteen phenolic compounds including seven flavonoids (1 - 9) and four simple phenolic glycosides (10 - 13) by column chromatographic methods. Among the isolated compounds, picein (11), androsin (12), and $1-O-feruloyl-{\beta}-{\small{D}}-glucopyranoside$ (13) were isolated for the first time from O. ficus-indica; additionally, this is the first report $benzyl-O-{\beta}-{\small{D}}-glucopyranoside$ (10) from the genus Opuntia. The structures of the compounds were determined by spectral data analysis which included 1D, 2D NMR spectrum and ESIMS.

Curing Process of Phenolic Resin (페놀 수지의 경화 공정)

  • Lee, Yoon Bae;Sung, Si Chang;Shin, Eun Jung
    • Applied Chemistry for Engineering
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    • v.16 no.2
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    • pp.292-295
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    • 2005
  • The curing time of the phenolic resin for the processing of brake pad is very important factor for reducing the processing cost. The curing time could be investigated by examining the reaction time of the phenolic resin and hexamethylenediamine. The reaction time has been studied by FT-IR, Differential Scanning Calolimetric Analysis (DSC), and Thermogravimetric Analysis (TGA).

A New Phenolic Amide from Lycium chinense Miller

  • Han, Song-Hee;Lee, Hyang-Hee;Lee, Ik-Soo;Moon, Young-Hee;Woo, Eun-Rhan
    • Archives of Pharmacal Research
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    • v.25 no.4
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    • pp.433-437
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    • 2002
  • A new phenolic amide, dihydro-N-caffeoyltyramine (1) was isolated from the root bark of Lycium chinense Miller, along with known compounds, trans-N-caffeoyltyramine (2), cis-N-caffeoyltyramine (3), and lyoniresinol $3{\alpha}-Ο-{\beta}-D-glucopyranoside$ (4). Their structures were determined by spectroscopic analysis. A NBT superoxide scavenging assay revealed that three phenolic amides showed potent antioxidative activity.

Ex situ Coloration of Laccase-Entrapped Bacterial Cellulose with Natural Phenolic Dyes

  • Kim, Hyunjin;Song, Ji Eun;Kim, Hye Rim
    • Journal of the Korean Society of Clothing and Textiles
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    • v.45 no.5
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    • pp.866-880
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    • 2021
  • This study aimed to ex situ colorize laccase-entrapped bacterial cellulose (BC) with natural phenolic dyes, namely,madder, turmeric, and cochineal, and to determine the effect of laccase entrapment on the dyeability of BC using color strength (K/S) analysis. Results showed that laccase entrapment improved the dyeability of BC and that pre-entrapment was the most effective method, compared with meta-entrapment and post-entrapment methods. In addition, surface characterizations confirmed the successful entrapment of laccase inside the BC nanostructure and retention of the cellulosic and crystalline structures of BC. The washing durability test confirmed that the K/S value of BC had improved after laccase entrapment. Furthermore, laccase-entrapped BC colorized with cochineal dye had the highest washing durability due to the high molecular weight of cochineal dyerelative to the other dyes. This study suggests a novel method for enhancing the dyeability and washing durability of BC colorized ex situ with natural phenolic dyes by laccase entrapment.