• Journal of Environmental Health Sciences
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• v.22 no.3
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• pp.72-80
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• 1996

This study was carried to investigate the biodegradability of phenol wastewater in the sluge blanket-packed bed reactor(SBPBR). The reactor consisted of two regions. The lower region was a sludge blanket of 0.5 m height and the upper region was a packed-bed. The phenol and COD concentration of the effluent, the gas production and the composition of gas were measured to determine the performance of the anaerobic wastewater treatment system as the phenol concentration of the influent was increased from 600 to 1800 mg/l. Stable biodegradation of phenol wastewater could be achieved with the anaerobic treatment system from 600 to 1200 mg/l of the influent phenol concentration. But the SBPBR system was getting more serious at 1800 mg/l of influent phenol concentration. At the steady state of the influent phenol concentration of 600-1200 mg/l, the treatment performance showed the phenol removal efficiency of 94.5~96.3%, the COD removal efficiency of 93.3~96% and the gas production of 4.94~9.64 l/day.

• Journal of Environmental Science International
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• v.9 no.1
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• pp.89-93
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• 2000

Twenty organic chemical substances(Table 2) were isolated from untreated wastewater, as well as treated wastewater, collected at 76 companys of 9 industry group located in the basin of Youngsan River. Those organic compounds were analyzed by Gas Chromatography/Mass Spectrometry(GC/MS) and confirmed through comparison with each standard reagents. Phenol, which was not detected in the raw wastewater, was identified in the effluent of treatment facility, indicating that phenol is generated from isopropylbenzene of plant wastewater.

• Journal of Korean Society of Water and Wastewater
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• v.21 no.5
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• pp.521-529
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• 2007

Nutrient removal from synthetic wastewater was investigated using a MLE (Modified-Ludzack Ettinger) type MBBR (Moving Bed Biofilm Reactor), with different phenol ($C_6H_5OH$) concentrations, in order to determine the inhibition effects of phenol on biological nutrient removal and the biodegradation of phenolic wastewater. The wastewater was prepared by mixing a solution of molasses with known amounts of phenol and nutrients. The experiments were conducted in a lab-scale MLE type MBBR, operated with four different phenol concentrations (0, 67, 100 and 168mg/L) in the synthetic feed. Throughout the experiments, the ratio of the phenolic COD concentration to the total COD was varied from 0 to 1. Throughout batch test, the SNR (Specific Nitrification Rate) and SDNR (Specific Denitrification Rate) were significantly influenced by changes of the phenol concentration. Phenol was inhibitory to the nitrification/denitrification process, and showed greater inhibition with higher initial phenol concentrations. The SNR observed with 0, 67, 100 and 168mg phenol/L were very different like 10.12, 6.95, 1.51 and $0.35mg\;NH_{3^-}N/gMLVSS$ hr, respectively. Similarly, the SDNR observed at 0, 67, 100 and 168mg phenol/L were different like 0.322, 0.143, 0.049and 0.006mgN/gMLVSS day, respectively.

• Journal of Korean Society of Water and Wastewater
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• v.10 no.4
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• pp.119-126
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• 1996

Influence factors and efficiency characteristics for treatment of wastewater containing phenol were studied with using Pseudomonas sp. B3. It took 130 hours to remove phenol, when only activated sludge of terminal disposal palnt of sewage was innoculated in batch culture, but it was required just 36 hours, when bacteria degrading phenol and activated sludge were simultaneously innoculated. If only phenol an carbon source was used, it necessary 36 hours for biodegradation of phenol, while glucose was added to medium, it took 73 hours. It was revealed as excellent effluent and SVI, when the F/M ratio, COD and phenol concentration were 53mg/l and 1.2mg/l, respectively, and optimum F/M ratio was revealed 0.31. The reactor were seriously shocked as reducing hydraulic retention time at constant phenol concentration more than increasing phenol concentration at constant hydraulic retention time, when volumetric loading rate was increased to $0.8kg\;phenol/m^3{\codt}d$ from $1.6kg\;phenol/m^3{\codt}d$. And also the effluent phenol concentration was 34mg/l after starting 12 hours of shocking and reactor was recovered as steady state after 65 hours of changing in the former test. Although the effluent phenol concentration was maximum value with 12mg/l after starting 20 hours of shocking and reactor was recovered as steady state after 54 hours of changing in the later test.

• Journal of Environmental Health Sciences
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• v.23 no.1
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• pp.74-80
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• 1997

This study was performed to estimate the ozonation characteristics of phenol wastewater with increasing pH in the continuous packed column reactor (PCR) and the bubble column reactor (BCR). Among various influencing factors that affect phenol on decomposition through the ozonation, pH was chosen as reaction parameter. Upon increasing pH from 3 to 9, the phenol removal efficiency in PCR was improved approximately by 17% while in BCR approximately by 19.2%. The improvements in the phenol removal efficiency by increasing pH caused the enhancements in ozone utilization efficiency reaching almost 100% in PCR at pH 9. In conclusions, ozone has latent power for phenol wastewater treatment, and the performance of PCR was superior to that of BCR in the aspects of phenol removal and ozone utilization efficiency.

• Journal of Environmental Health Sciences
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• v.21 no.4
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• pp.1-9
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• 1995

This study was carried to investigate the biodegradability of phenol in the wastewater with the two sludge blanket-packed bed reactor in series. Each reactor had a dimension of 0.09 m i.d. and 1.5 m height and consisted of two regions. The lower region was a sludge blanket of 0.5 m height and the upper region was a packed-bed of 1 m height. The packed bed region was charged with ceramic raschig rings of 10 mm i.d., 15 mm o.d. and 20 mm length. The reactors were operated at 35$\circ$C and the hydraulic retention time(HRT) was maintained 24 hours. The synthetic wastewater composed of glucose and phenol as major components was fed into the reactor in a continuous mode with incereasing phenol concentration. In addition, the nutrient trace metals($Na^+, Mg^{2+}, Ca^{2+}, PO_4^{3-}, NH_4^+, Co^{2+}, Fe^{2+}$ etc.) were added for growing anaerobes. The phenol concentration of the effluent, the overall gas production, the composition of product gas, the efficiency of COD reduction and the duration of acclimation period were measured to determine the performance of the anaerobic wastewater treatment system as the phenol concentration of the influent was increased from 600 to 2400 mg//l. Successfully stable biodegradation of phenol could be achieved with the anaerobic treatment system from 600 to 1, 800 mg/l of the influent phenol concentration. The upper level of influent phenol loading was high enough to meet most of the practical requirement. The duration of acclimation increased with the phenol loading. At steady state of the influent phenol concentration of 1800 mg/l, the treatment performance indicated the phenol reduction efficiency of 99%, the COD reduction efficiency of 99% and the gas production rate of 37 l/day. At the influent phenol concentration of 2400 mg/l, however, the operation of the treatment system was noted unstable. While the concentration of methane in biogas decreased with increasing the influent phenol loading, the carbon dioxide was increased. However, the concentration of hydrogen was varied negligibly. The concentration of methane was high enough to be used as a fuel. As a result, it is suggested that anaerobic phenol wastewater treament was economical in the sense of energy recovery and wastewater treatment.

• Journal of Korean Society of Water and Wastewater
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• v.11 no.3
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• pp.124-130
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• 1997

Wastewater containing phenol was treated using Pseudomonas sp. B3 in continuous reactor, reaction characteristics and kinetics according to variation of volumetric loading rate in continuous reactor were studied. The removal efficiencies of phenol were more than 99% at the whole range of experiment, and those of COD were 97% at the volumetric loading rate, $0.96kg/m^3{\cdot}d$ and 88% at $3.0kg/m^3{\cdot}d$, respectively. Kinetics constants of $q_m$, $K_s$, Y and $K_d$ were obtained 0.901 l/d, 0.620mg/l, 0.659 and 0.219 l/d, respectively. As compared with to constants of standard activated sludge process, these constants were remarkably different because of toxicity and inhibition of phenol to microbes. And also, kinetics constants of oxygen utilization, a, and b, were shown 0.384 kg $O_2/kg$ phenol and 0.029 l/d.

• Journal of Life Science
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• v.23 no.10
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• pp.1273-1279
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• 2013

Aromatic hydrocarbons, such as phenol, have been detected frequently in wastewater, soil, and groundwater because of the extensive use of oil products. Bacterial strains (56 isolates) that degraded phenol were isolated from soil and industrial wastewater contaminated with hydrocarbons. GN13, which showed the best cell growth and phenol degradation, was selected for further analysis. The GN13 isolate was identified as Neisseria sp. based on the results of morphological, physiological, and biochemical taxonomic analyses and designated as Neisseria sp. GN13. The optimum temperature and pH for phenol removal of Neisseria sp. GN13 was $32^{\circ}C$ and 7.0, respectively. The highest cell growth occurred after cultivation for 30 hours in a jar fermentor using optimized medium containing 1,000 mg/l of phenol as the sole carbon source. Phenol was not detected after 27 hours of cultivation. Based on the analysis of catechol dioxygenase, it seemed that catechol was degraded through the meta- and ortho-cleavage pathway. Analysis of the biodegradation of phenol by Neisseria sp. GN13 in artificial wastewater containing phenol showed that the removal rate of phenol was 97% during incubation of 30 hours. The removal rate of total organic carbon (TOC) by Neisseria sp. GN13 and activated sludge was 83% and 78%, respectively. The COD removal rate by Neisseria sp. GN13 from petrochemical wastewater was about 1.3 times higher than that of a control containing only activated sludge.

• Journal of Environmental Health Sciences
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• v.24 no.1
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• pp.1-8
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• 1998

This study was carried to investigate the treatment characteristics of the phenol and catechol with an anaerobic fluidized bed reactor(AFBR) having a dimension of 9 cm i.d. and 1.25 m height. The reactor was operated at $35\pm 1\circ$C. The COD concentration of the effluent, the gas production rate and the composition of gas were measured to determine the performance of the AFBR as the hydraulic retention time(HRT) was decreased from 2 days to i day at 600 mg/l of the phenol and catechol concentration. Stable treatment of the phenol wastewater could be achieved with the AFBR at 18 days but the catechol wastewater couldn't be. At HRT 2 days, the phenol wastewater showed the COD reduction efficiency of 93% and the gas production of 2.7 l/day and the catechol wastewater was obtained the COD reduction efficiency of 82% and the gas production of 0.72 l/day. Also at HRT 1 day the phenol and catechol wastewater showed the COD reduction efficiency of 95% and 73% and the gas production of 4.0 l/day and 1.25 l/day, respectively.

• Journal of Environmental Health Sciences
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• v.21 no.2
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• pp.12-19
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• 1995

The objectives of this research prograln were to study the ozonation characteristics of phenol contaminated wastewater in the continuous packed column reactor (PCR) and the bubble column reactor (BCR) using ozone that has a strong oxidizing potential, and to provide the fundamentals of ozonizing the phenol contaminated wastewater. Among various influencing factors on phenol decomposition through the oxidation by ozone, phenol/ozone mde ratio was chosen as reaction parameters. Concerning the phenol/ozone mde ratio, as the influent phenol concentration increased from 30 mg/l to 150 mg/l, the phenol removal efficiency decreased from 99% for 30 mg/l to 83.7% for 150 mg/l, in PCR. PCR also showed higher treatment efficiency than BCR by 1% for 30 mg/l and 2.2% for 150 mg/l, respectively. The ozone utilization efficiency of PCR for the phenol concentration 30 mg/l was higher than that of BCR while the efficiency of both reactors was 99.9% for the phenol concentration of 150 mg/l.