Characteristics of Phenolic Wastewater Treatment using Moving Bed Biofilm Reactor in the MLE Process

MLE type MBBR을 이용한 페놀화합물 함유폐수의 처리특성

  • Received : 2007.03.23
  • Accepted : 2007.10.12
  • Published : 2007.10.15

Abstract

Nutrient removal from synthetic wastewater was investigated using a MLE (Modified-Ludzack Ettinger) type MBBR (Moving Bed Biofilm Reactor), with different phenol ($C_6H_5OH$) concentrations, in order to determine the inhibition effects of phenol on biological nutrient removal and the biodegradation of phenolic wastewater. The wastewater was prepared by mixing a solution of molasses with known amounts of phenol and nutrients. The experiments were conducted in a lab-scale MLE type MBBR, operated with four different phenol concentrations (0, 67, 100 and 168mg/L) in the synthetic feed. Throughout the experiments, the ratio of the phenolic COD concentration to the total COD was varied from 0 to 1. Throughout batch test, the SNR (Specific Nitrification Rate) and SDNR (Specific Denitrification Rate) were significantly influenced by changes of the phenol concentration. Phenol was inhibitory to the nitrification/denitrification process, and showed greater inhibition with higher initial phenol concentrations. The SNR observed with 0, 67, 100 and 168mg phenol/L were very different like 10.12, 6.95, 1.51 and $0.35mg\;NH_{3^-}N/gMLVSS$ hr, respectively. Similarly, the SDNR observed at 0, 67, 100 and 168mg phenol/L were different like 0.322, 0.143, 0.049and 0.006mgN/gMLVSS day, respectively.

Keywords

References

  1. 김용환, 조재현, 김무훈, 이용우 (1997) 생물막 담체를 이용한 질산화 반응 특성 연구. 대한환경공학회지, 19(3), pp. 415-424
  2. 류홍덕, 이상일 (2006) 온도가 MLE 및 M-Dephanox 공정의 유기물, 질소 및 인 제거 효율에 미치는 영향. Journal of Korea Society water Quality, 22(1), pp. 7-16
  3. 박운지, 이해승, 이찬기, 김성근 (2004) 기존 활성슬러지 공정은 MBBR공정 적용가능성 평가, 한국물환경학회지, 20(5), pp. 457-465
  4. 박희동, 임봉수, 김현용 (2003) 부유성 플라스틱 담체를 이용한 MLE공정의 하수고도처리 성능평가, 대한토목학회논문집, 23(5B), pp. 463-470
  5. Amor, L., Eiroa, M., Kennes, C. and Veiga, M.C. (2005) Phenol biodegradation and its effect on the nitrification process, Water Research, 39, pp. 2915-2920 https://doi.org/10.1016/j.watres.2005.05.019
  6. Bjorn Rusten, Bfornar Eikebrokk, Yngve Ulgenes and Eivind Lygren (2005) Design and operations of the Kaldnes moving bed biofilm reactors, Aquacultural Engineering
  7. E. Ubay Cokgor, S. Sozen, D. Orhon, M Henze (1999) Respirometric analysis of activated sludge behaviour-1. assessment of the readily biodegradable substrate, Wat. Res. 32(2), pp. 461-475 https://doi.org/10.1016/S0043-1354(97)00209-1
  8. Hossein, S.H. and Borghei, S.M. (2005) The treatment of phenolic wastewater using a moving bed bio-reaetor, Process Biochemistry, 40, pp. 1027-1031 https://doi.org/10.1016/j.procbio.2004.05.002
  9. M. Rodgers, M.G. Healy, J. Prendergast (2006) Nitrification in a vertically moving biofilm system, Journal of Environmental Management, 79, pp. 242-246 https://doi.org/10.1016/j.jenvman.2005.07.003
  10. Michael Rodgers, Xin-Min zhan, (2004) Biological nitrogen removal using a vertically moving biofilm system, Bioresorce Technology 93, pp. 313-319 https://doi.org/10.1016/j.biortech.2003.09.017
  11. UBAY COKGOR, E., SOZEN S., ORHON, D., and HENZE, M. (1998) Respirometric analysis of activated sludge behaviour-1. assessment of the readily biodegradable substrate, Water Research, 32(2), pp. 461-475 https://doi.org/10.1016/S0043-1354(97)00209-1