• 제목/요약/키워드: Phase composition

검색결과 2,035건 처리시간 0.038초

Syntheses and properties of Ti2AlN MAX-phase films

  • Zhang, Tengfei;Myoung, Hee-bok;Shin, Dong-woo;Kim, Kwang Ho
    • Journal of Ceramic Processing Research
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    • 제13권spc1호
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    • pp.149-153
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    • 2012
  • Ti2AlN MAX-phase films were synthesized through the post-annealing process of as-deposited Ti-Al-N films. Near amorphous or quasi-crystalline ternary Ti-Al-N films were deposited on Si and Al2O3 substrates by sputtering a Ti2AlN MAX-phase target at room temperature, 300 ℃ and 450 ℃, respectively. A vacuum annealing of those films at 800 ℃ for 1 hour changed those films to crystalline Ti2AlN MAX-phase. The polycrystalline Ti2AlN MAX-phase films exhibited very excellent oxidation resistance due to its characteristics microstructure (nanolaminates), which has potential applications for high-temperature protective coatings. The microstructure and composition of Ti2AlN MAX-phase films were investigated using with a variety of characterization tools.

BRAZING CHARACTERISTICS BETWEEN CEMENTED CARBIDES AND STEEL USED BY AG-IN BRAZING FILLER

  • Nakamura, Mitsuru;Itoh, Eiji
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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    • pp.551-554
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    • 2002
  • As a general rule, the brazing process between cemented carbides and steel used by Silver (Ag) type brazing filler. The composition of Ag type filler were used Ag-Cu-Zn-Cd type filler mainly. But, the demand of Cadmium (Cd)-free in Ag type filler was raised recently. The reason why Cd-free in Ag brazing filler were occupied to vaporize as a CdO$_2$ when brazing process, because of Cd element was almost low boiling point of all Ag type filler elements. And, CdO$_2$ was a very harmful element for the human body. This experiment was developed Cd-freeing on Ag type filler that was used Indium (In) instead of Cd element. In this experiment, there were changed from 0 to 5% In addition in Ag brazing filler and investigated to most effective percentage of Indium. As a result, the change of In addition instead of Cd, there was a very useful element and obtained same property only 3% In added specimens compared to Cd 19% added specimens. These specimens were obtained same or more deflective strength. In this case, there were obtained 70 MPa over strength and wide brazing temperature range 650-800 C. A factor of deflective strength were influenced by composition and the shape of $\beta$ phase and between $\beta$ phase and cemented carbides interface. Indium element presented as $\alpha$ phase and non-effective factor directly, but it's occupied to solid solution hardening as a phase. $\beta$ phase were composed 84-94% Cu-Ni-Zn elements mainly. Especially, the presence of Ni element in interface was a very important factor. Influence of condensed Ni element in interface layer was increased the ductility and strength of brazing layer. Therefore, these 3% In added Ag type filler were caused to obtain a high brazing strength.

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버섯 병재배를 위한 배지조성물의 종합관리 모델 (Comprehensive model formedium composition for mushroom bottle cultivation)

  • 정종천;이찬중;문지원
    • 한국버섯학회지
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    • 제14권3호
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    • pp.111-118
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    • 2016
  • 버섯 병 재배용 배지는 재료의 혼합, 수분조절, 입병, 살균, 냉각의 작업과정을 거쳐 조성된다. 배지조성은 버섯종류별로 알맞은 재료의 선택, 수분함량, 병당 입병량, 가비중, 질소량, 병내 배지의 3상조건 등을 매일 입병 작업하는 과정에서 연중 일정하게 유지해야 할 필요가 있다. 이를 위하여 지금까지 배지조성에 관하여 단편적으로 개발한 기술들을 작업과정에 맞추어서 종합적으로 투입하는 모델을 설정하였다. 배지조성 방법들을 종합적으로 적용함으로써, 우리나라에서 4계절을 통한 버섯 재배에서 균 배양기간, 재배기간, 수량 및 품질에 기복이 많았던 점을 극복할 수 있을 것으로 기대한다.

IBAD-MgO 템플릿을 이용한 SmBCO 박막선재의 제조 (Fabrication of SmBCO Coated Conductors using IBAD-MgO Template)

  • 하홍수;김호섭;양주생;정예현;김호겸;유권국;고락길;송규정;하동우;오상수;염도준;박찬;유상임;문승현;주진호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.30-31
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    • 2006
  • We have fabricated SmBCO coated conductor on IBAD-MgO substrates using unique co-evaporation method. The batch type co-deposition system was specially designed and named as EDDC(evaporation using drum m dual chamber) that is possible to deposit superconducting layer with different composition ratio at low temperature of $700^{\circ}C$. In this study, we have investigated the influence of SmBCO phase composition and texture of IBAD-MgO template on the critical current density. We have changed the deposition rates of Sm, Ba and Cu during co-evaporation to examine the optimal composition ratio shown better critical current density. The composition ratio and surface morphology of SmBCO coated conductors were analyzed by the EDX and SEM, respectively. A higher critical current density was measured at superconducting phase composition ratio of Ba deficiency, Sm or Cu rich compared to the Sm1Ba2Cu3Ox stoichiometry.

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반응형 계획에 기초한 자동화된 시맨틱 웹서비스의 조합 (Automated Composition of Semantic Web Services Based on Reactive Planning)

  • 진훈;김인철
    • 정보처리학회논문지B
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    • 제14B권3호
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    • pp.199-214
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    • 2007
  • 최근 들어 인공지능 계획기법을 이용하여 자동화된 시맨틱 웹서비스들 간의 조합을 구현하려는 연구들이 활발하게 이루어지고 있다. 하지만 일반적으로 전통적인 인공지능 계획기법들은 복잡한 제어구조를 포함하는 웹서비스 프로세스를 하나의 단위 행동이나 계획으로 표현하기 어렵고, 온톨로지에 포함된 의미 정보들을 계획생성에 충분히 반영할 수 없으며, 웹서비스들 사이의 입출력 데이터 흐름을 직접 모델링할 수 없고, 계획단계와 실행단계가 분리되어 있어 웹서비스 실행단계의 불확실성과 가변성을 계획단계에서 충분히 고려할 수 없다는 등의 한계점을 가지고 있다. 본 연구에서는 이러한 문제점들을 해결하기 위한 접근 방법으로서 반응형 계획을 이용한 시맨틱 웹서비스 조합을 제안하고, 프로토타입 시스템인 SWEEP을 구현하였다. e-Commerce 분야의 예제 웹서비스들을 대상으로 실험을 통해, 우리는 반응형 계획이 자동화된 시맨틱 웹서비스의 조합과 실행을 구현하기 위한 효과적인 기술임을 확인할 수 있었다.

Morphology and Rheology on the Blends of PLA/CMPS

  • Shin, Boo-Young;Jo, Gyu-Soon;Kang, Kyoung-Su;Lee, Tae-Jin;Kim, Bong-Shik;Lee, Sang-Il;Song, Jeong-Sup
    • Macromolecular Research
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    • 제15권4호
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    • pp.291-301
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    • 2007
  • The rheological behaviors and morphologies of polylactide (PLA) and chemically modified plasticized starch (CMPS) blends were investigated. For this study, oscillatory shear flow measurements of the PLA, CMPS and their blends were performed. A scanning electron microscope (SEM) study was also conducted on the extracted extrudates of the blends. The morphology of the blend changed in relation to the composition: sphere-shaped CMPS disperse/continuous PLA, rod-like deformed CMPS phase/continuous PLA, a co-continuous structure with bridged CMPS long rods and PLA dispersed/continuous CMPS. The composition of the phase inversion could be estimated and closely coincided from the observed morphology experimental results. The rheological behavior of the blends, from oscillatory measurements, was found to vary in relation to the composition, and reflected the morphologies of the blends. PLA showed Newtonian flow behavior, while CMPS showed strong shear thinning behavior. The relationships between the morphology and rheological properties were observed in detail.

녹색발광 β-SiAlON:Eu 세라믹 플레이트 형광체의 치밀화 소결 (The High Density Sintering of Green-emitting β-SiAlON:Eu Ceramic Plate Phosphor)

  • 박영조;이성훈;장욱경;윤창번;윤철수
    • 한국세라믹학회지
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    • 제47권6호
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    • pp.503-508
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    • 2010
  • $Eu^{2+}$-doped $\beta$-SiAlONs ($Si_{6-z}Al_zO_zN_{8-z}:Eu_y$) are recognized as promising phosphor materials to build an white LED for lighting application due to its excellent absorption/emission efficiency in the long wave length region. In this research, the fabrication of $\beta$-SiAlON:Eu plate phosphor by sintering was investigated with fixed Eu content(y) and varied composition of the host lattice(z). The addition of the activator $Eu_2O_3$ lead to enhanced densification by forming the transient liquid phase. The refinement of a composition by the calculated lattice parameter indicated that the measured composition of the fabricated specimens is nearly same to that of designed one. The single phase $\beta$-SiAlON:Eu plate with relative density of 96.4% was achieved by addition of 2 wt% CaO, which implies the possibility of full densification by adjusting the processing variables.

Cu2ZnSnSe4 Thin Films Preparation by Pulsed Laser Deposition Using Powder Compacted Target

  • Kim, Kyoo-Ho;Wibowo, Rachmat Adhi;Alfaruqi, M.Hilmy;Ahn, Jong-Heon
    • 한국표면공학회지
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    • 제44권5호
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    • pp.185-189
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    • 2011
  • $Cu_2ZnSnSe_4$ thin films for solar absorber application were prepared by pulsed laser deposition of a synthesized $Cu_2ZnSnSe_4$ compound target. The film's composition revealed that the deposited films possess an identical composition with the target material. Further film compositional control toward a stoichiometric composition was performed by optimizing substrate temperature, deposition time and target rotational speed. At the optimum condition, X-ray diffraction patterns of films showed that the films demonstrated polycrystalline stannite single phase with a high degree of (112) preferred orientation. The absorption coefficient of $Cu_2ZnSnSe_4$ thin films were above 104 cm.1 with a band gap of 1.45 eV. At an optimum condition, films were identified as a p type semiconductor characteristic with a resistivity as low as $10^{-1}{\Omega}cm$ and a carrier concentration in the order of $10^{17}cm^{-3}$.

3상 4선식 부하설비의 전압 불평형율 측정 및 분석 (The measurement & Analysis of Voltage Unbalance Factor at Three Phase Four Wire Load System)

  • 김종겸;박영진;이동주;이화수;이은웅
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
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    • pp.15-17
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    • 2004
  • Most of LV customer has been composed the 3-phase four wire system distribution system which is supplying simultaneously at the 1-phase & 3-phase load. In this system, the composition of the power apparatus system is simple rather than conventional separation mode of the 1-phase & 3-phase, But due to uneven load unbalance or unclean power quality, various kinds such as derating or power losses become an issue. In this paper, we measured and analyzed voltage and current waveform in the field, compared with internationally allowable voltage unbalance limits.

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ZnS 미립자 분산 붕규산엽계 유리에서의 분상 및 미립자 석출 특성 (Phase Separation and Precipitation Characteristics in ZnS doped Borosilicate Glasses)

  • 이승환;류봉기
    • 한국세라믹학회지
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    • 제35권12호
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    • pp.1337-1342
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    • 1998
  • To investigate an effect of phase separation on precipitation characteristics of ZnS microcrystals in ma-trix glass ZnS doped borosilicate glasses for nonlinear optical applications were prepared by melting and pre-cipitation process. ZnS dopant contributed to phase separation promotion which increased the phase separa-tion of the matrix glass within immiscibility region. It was also found that ZnS as phase separation promoter showed a similar contribution for some selected glass compositions in miscibility region. The precipitation of ZnS microcrystals occurred in thephase separable glass compoitions. The radius of ZnS microcrystals in-creased with increasing the heat treatment temperature and Na2O contents of matrix glass composition. The ZnS particle sizes estimated by effective mass approximation ranged from about 30 to 80${\AA}$ It was suf-ficiently small to show quantum confinement effect.

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