• 제목/요약/키워드: Phase boundary

검색결과 1,095건 처리시간 0.027초

$Fe_{78}Si_9B_{13}$ 비정질 합금의 초크 코어 특성에 미치는 열처리 효과 (Effects of Heat Treatment on Choke Core Properties in $Fe_{78}Si_9B_{13}$ Amorphous Alloys)

  • 노태환;장완희
    • 한국자기학회지
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    • 제10권5호
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    • pp.191-195
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    • 2000
  • Fe$_{78}$Si$_{9}$B$_{13}$ 비정질 합금을 스위칭 전원의 평활용 쵸크 코어로 사용하기 위한 최적 열처리 조건을 조사하였다. 코어의 모양은 자기경로 상에 공극을 넣지 않는 무공극형으로 하였으며, 보다 효과적으로 쵸크 코어 특성을 얻기 위해 산화 분위기 중에서 열처리하였다. 이 합금에서 가장 양호한 쵸크 코어 특성은 44$0^{\circ}C$, 2시간의 열처리에 의하여 얻어졌으며, 그 때의 실효투자율은 180 정도로서 수 MHz의 높은 주파수 영역에 이르기까지 그 크기가 일정하게 유지되었다. 또 12A가지의 직류 바이어스 전류 또는 8,000 A/m의 직류 바이어스 자장을 가하여도 실효투자율의 저하가 나타나지 않는 우수한 직류중첩 특성을 나타내었다. 그리고 교류 자심 손실도 종래의 쵸크 코어에 비해 상당히 낮은 것으로 나타났다. 이와 같은 열처리 조건하에서 비정질상은 미세한 $\alpha$-Fe 결정상의 석출 입자를 포함하는 혼합상으로 변태하는데 , 상기의 쵸크코어 특성은 주로 이들 미세 결정 입자에 의해 효과적으로 자벽 이동이 억제되고 자구가 미세화 되는 것에 기인하는 것으로 생각되었다.

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Ca 첨가에 따른 Mg-4Al-2Sn-xCa 다이캐스팅 합금의 기계적특성 연구 (Effect of Ca additions on Mechanical Properties of Mg-4Al-2Sn-xCa Die-Casting Alloys)

  • 김영민;이영철;박용호
    • 한국주조공학회지
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    • 제31권5호
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    • pp.293-301
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    • 2011
  • Representative magnesium alloys applied to the die-casting are AZ91, AM60, etc., and the application of these alloys is restricted to components operating at moderate temperatures, due to grain boundary siding of ${\beta}$-phase($Mg_{17}Al_{12}$) at temperatures above $120^{\circ}C$. Heat-resistant magnesium alloys such as AE42, AE44 have been developed, but that have been too burdensome to produce because of the expensive rare earth materials. Research work for the development of low-priced heat-resistant magnesium alloy is actively in progress and positive results are being reported. This study aims to investigate the effect of Ca additions on mechanical properties of Mg-4Al-2Sn heat resistant magnesium alloys. Mg-4Al-2Sn alloys with Ca (0wt.%, 0.3wt.%, 0.7wt.%, 1wt.%) have been produced through the die-casting process for the development of low-priced heat-resistant magnesium alloy, and high temperature tensile tests are performed using the specimens. The results showed that mechanical properties of Mg-4Al-2Sn-xCa increased with the addition of Ca up to 0.7wt.% Ca and further addition of Ca deteriorated the mechanical properties of the alloys. A significant amount of porosity was observed at the sample with 1wt%. Ca and the longer freezing range of the alloy was believed to cause the formation of porosity.

직사각형판(直四角形板)의 진동해석(振動解析) (Vibration of Rectangular Plates)

  • 김극천;정태영
    • 대한조선학회지
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    • 제14권1호
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    • pp.1-10
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    • 1977
  • The major objects of this report are to supplement data of natural frequencies of thin elastic rectangular plates to the available data, and to give an experimental verification for natural frequencies obtained by Rayleigh-Ritz method, the generation set of which are eigenfunctions of Euler beams. For the first object the following five models, for which data only for the fundamental mode or data only for square plates are available, are adopted; (1) two opposed edges are clamped and the other two opposed edges simply supported (C-C, S-S), (2) one edge is simply supported and the other three edges clamped (C-C, C-S), (3) one edge is free and the other three edges clamped (C-C, C-F), (4) two adjacent edges are clamped and the other two adjacent edges free (C-F, C-F). For the (C-C, S-S) model the frequency equation obtained with the mode shapes assumed as of a single trigonometric series is solved. And for the other four models Rayleigh-Ritz method taking eigenfunctions of Euler beams as the generating set is applied. The numerical examples are obtained up to the fourth, the fifth or the sixth order depending on the range of the aspect ratio (0.1-10.0). The number of terms in the generating set for Rayleigh-Ritz method is fifteen for all models. For the experiment three models made of 3.2mm thickness mild steel plate for general structure use were prepared in following size; $300mm{\times}600mm,\;600mm{\times}600mm\;and\;900mm{\times}600mm$. Their boundary conditions are made to fit (C-C, C-F) condition. From the experiment mechanical impedance curves based on the frequency response method were obtained together with phase relation diagrams. The experimental data are resulted in good conformity to calculated values.

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캐비테이션 터널에서 PIV를 이용한 프로펠러 후류 보오텍스 유동계측 및 거동해석 (PIV Aanalysis of Vortical Flow behind a Rotating Propeller in a Cavitation Tunnel)

  • 백부근;김진;박영하;김기섭;김경열
    • 대한조선학회논문집
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    • 제42권6호
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    • pp.619-630
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    • 2005
  • A two-frame PIV (Particle Image Velocimetry) technique is used to investigate the wake characteristics behind a marine propeller with 4 blades at high Reynolds number. For each of 9 different blade phases from $ 0^{\circ} $ to $ 80^{\circ} $, one hundred and fifty instantaneous velocity fields are measured. They are ensemble averaged to study the spatial evolution of the propeller wake in the region ranging from the trailing edge to one propeller diameter (D) downstream location. The phase-averaged mean velocity shows that the trailing vorticity is related to radial velocity jump, and the viscous wake is affected by boundary layers developed on the blade surfaces and centrifugal force. Both Galilean decomposition method and vortex identification method using swirling strength calculation are very useful for the study of vortex behaviors En the propeller wake legion. The slipstream contraction occurs in the near-wake region up to about X/D : 0.53 downstream. Thereafter, unstable oscillation occurs because of the reduction of interaction between the tip vortex and the wake sheet behind the maximum contraction point.

직교 격자계 기반 유동해석기법을 이용한 파랑 중 해양구조물의 운동 해석 (Numerical Study on Wave-induced Motion of Offshore Structures Using Cartesian-grid based Flow Simulation Method)

  • 남보우;김용환;양경규;홍사영;성홍근
    • 한국해양공학회지
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    • 제26권6호
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    • pp.7-13
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    • 2012
  • This paper presents a numerical study of the wave loads acting on offshore structures using a Cartesian-grid-based flow simulation method. Finite volume discretization with a volume-of-fluid (VOF) method is adopted to solve two-phase Navier-Stokes equations. Among the many variations of the VOF method, the CICSAM scheme is applied. The body boundary conditions are satisfied using a porosity function, and wave generation is carried out by using transient (wave or damping) zone approaches. In order to validate the present numerical method, three different basic offshore structures, including a sphere, Pinkster barge, and Wigley model, are numerically investigated. First, diffraction and radiation problems are solved using the present numerical method. The wave exciting and drift forces from the diffraction problems are compared with potential-based solutions. The added mass and wave damping forces from the radiation problems are also compared with the potential results. Next, the wave-induced motion responses of the structures are calculated and compared with the existing experimental data. The comparison results are fairly good, showing the validity of the present numerical method.

기체분무형 공정으로 제조된 Zr계 금속수소화물의 수소화반응 및 Ni-MH 2차전지 전극 특성에 관한 연구 (Hydrogneation and Electrochemical Characteristics of Gas-atomized Zr-based $AB_2$ Hydride for Ni-MH Secondary Battery)

  • 김진호;황광택;김병관;한정섭
    • 한국수소및신에너지학회논문집
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    • 제20권6호
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    • pp.505-511
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    • 2009
  • The hydriding and electrochemical characteristics of Zr-based $AB_2$ alloy produced by gas atomization have been extensively examined. For the particle morphology of the as-cast and gas-atomized powders, it can be seen that the mechanically crushed powders are irregular, while the atomized powder particles are spherical. The increase of jet pressure of gas atomization process results in the decrease of hydrogen storage capacity and the slope of plateau pressure significantly increases. TEM and EDS studies showed the increase of jet pressure in the atomization process accelerated the phase separation within grain of the gas-atomized alloy, which brought about a poor hydrogenation property. However, the gas-atomized $AB_2$ alloy powders produced by jet pressure of 50 bar kept up the reversible $H_2$ storage capacity and discharge capacity similar to the mechanically crushed particles. In addition, the electrode of gas-atomized Zr-based $AB_2$ alloy of 50 bar showed improved cyclic stability over that of the cast and crushed particulate, which is attributed to the restriction of crack propagation by grain boundary and dislocation with ch/discharging cycling.

$Pb(Sb_{1/2}Nb_{1/2})O_3-PbTiO_3-PbZrO_3$ 세라믹스에서의 유전 및 압전 특성 (Dielectric and Piezoelectric Properties of $Pb(Sb_{1/2}Nb_{1/2})O_3-PbTiO_3-PbZrO_3$ Ceramics)

  • 차유정;김창일;정영훈;이영진;백종후
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.310-310
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    • 2008
  • 본 연구에서는 (1-x) Pb(Zr0.515Ti0.485)$O_3$ - x Pb$(Sb_{1/2}Nb_{1/2})O_3$ + 0.5wt% $MnO_2$ 조성에 Pb$(Sb_{1/2}Nb_{1/2})O_3$ (PSN) (x=0.02, 0.04, 0.06, 0.08) 변화에 따른 미세구조 및 압전, 유전특성에 관해 고찰하였다. PSN 치환량이 증가함에 따라 정방정 (tetragonal)구조에서 삼방정(rhombohedral)구조로 상전이가 일어났으며, 결정립의 크기가 작아지는 것을 확인하였다. 전기기계결합계수 (kp) 는 PSN이 4 mol % 치환됨에 따라 증가하였으며, 더 이상 치환 시 감소하였다. PSN 치환에 따른 전기적 특성은, 결정구조, 결정립의 크기 및 2 차상 등의 미세구조와 긴밀한 관계가 있는 것으로 보여진다. 상경계(Morphotropic Phase Boundary) 영역인 0.96 Pb(Zr0.515Ti0.485)$O_3$ - 0.04 Pb$(Sb_{1/2}Nb_{1/2})O_3$ + 0.5wt% $MnO_2$ 조성에서 $\varepsilon{^T}_{33}/\varepsilon_o$ = 1109, $k_p$= 70.8 (%), $d_{33}$= 325 (pC/N)의 우수한 특성을 나타내었다.

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BaTiO3 PTC 써미스터의 미세구조 및 전기적 특성에 대한 SiO2 영향 (The Effect of SiO2 on the Microstructure and Electrical Properties of BaTiO3 PTC Thermistor)

  • 전명표
    • 한국전기전자재료학회논문지
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    • 제26권1호
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    • pp.22-26
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    • 2013
  • PTCR ceramics of $(Ba_{0.998}Sm_{0.002})TiO_3+0.001MnCO_3+xSiO_2$ (x=1, 2, 3, 4, 5, 6 mol%) were fabricated by solid state method. Disk samples of diameter 5 mm and thickness about 1mm were sintered at $1,290^{\circ}C$ for 2 h in reduced atmosphere of $5%H_2-95%N_2$ followed by re-oxidation at $600^{\circ}C$ for 30 min. in $20%O_2-80%N_2$.and their microstructures and electrical properties were investigated with SEM and Multimeter. The color of sintered samples was strongly dependent on $SiO_2$ content showing that the color of samples with $SiO_2$ of 1~2 mol% was gray but that of samples with $SiO_2$ of 4~6 mol% was changed from gray to blue, which seems to be related with the reduction of samples due to the oxygen vacancies created during the sintering in reduced atmosphere. $SiO_2$ content had a great influence on the microstructure and the electrical properties. With increasing $SiO_2$ content, the grain size of samples increased and the resistivity as well as the resistivity jump ($R_{285}/R_{min}$) decreased, which is considered to be attributed to the resistivity change at grain interior and grain boundary due to the fast mass transfer through $SiO_2$ liquide phase during the sintering. Samples with 2 mol% $SiO_2$ has the resistivity of $202{\Omega}cm$ and the resistivity jump of 3.28. It is expected that $SiO_2$ doped $BaTiO_3$ based PTC ceramics can be used for multilayered PTC thermistor due to the resistance to the sintering in reduced atmosphere.

Fabrication and Characterization of (1-x)BiFeO3-xBaTiO3 Ceramics Prepared by a Solid State Reaction Method

  • Chandarak, S.;Unruan, M.;Sareein, T.;Ngamjarurojana, A.;Maensiri, S.;Laoratanakul, P.;Ananta, S.;Yimnirun, R.
    • Journal of Magnetics
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    • 제14권3호
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    • pp.120-123
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    • 2009
  • In this study, BiFe$O_3$-BaTi$O_3$ ceramics have been fabricated by a solid-state reaction method. The effects of BaTi$O_3$ content in the (1-x)BiFe$O_3$-xBaTi$O_3$ (x = 0.1, 0.2, 0.25, 0.3, 0.4, 0.5) system on crystal structure and magnetic, dielectric, and ferroelectric properties were investigated. Perovskite BiFe$O_3$ was stabilized through the formation of a solid solution with BaTi$O_3$. Rhombohedrally distorted structure (1-x)BiFe$O_3$-xBaTi$O_3$ ceramics showed strong ferromagnetism at x = 0.5. Dielectric and ferroelectric properties of the BiFe$O_3$-BaTi$O_3$ system also changed significantly upon addition of BaTi$O_3$. It was found that the maximum dielectric and ferroelectric properties were exhibited in the (1-x)BiFe$O_3$-xBaTi$O_3$ system at x = 0.25. This suggested the morphotropic phase boundary (MPB) with the coexistence of both rhombohedral and cubic phases of the (1-x)BiFe$O_3$-xBaTi$O_3$ system at x = 0.25.

Dielectric and Magnetic Properties of Co-doped Ni0.65Zn0.35Fe2O4 Thin Films Prepared by Using a Sol-gel Method

  • Lee, Hyun-Sook;Lee, Jae-Gwang;Baek, K.S.;Oak, H.N.
    • Journal of Magnetics
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    • 제8권4호
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    • pp.138-141
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    • 2003
  • $Ni_{0.65}Zn_{0.35}Fe_2O_4$thin films were prepared by using a sol-gel method. Their crystallographic, dielectric and magnetic properties were investigated as a function of Cu contents by means of an X-ray diffractometer (XRD), X-ray reflectivity, LCZ meter (NF2232), a vibrating sample magnetometer (VSM), and an atomic force microscope (AFM). From typical C-V measurements for $Ni_{0.65}Zn_{0.35}Fe_2O_4$ thin films on p-type silicon substrate, the surface charge density was calculated as 1.4 ${\mu}$C/$m^2$. The dielectric constant evaluated from the capacitance at the accumulation state was 28. The high $H_{c}$ and low $M_{sat}$ at x=0.0 and 0.1 were due to the growth of the ${\alpha}$-$Fe_2O_3$ phase having antiferromagnetic properties. The rapidly decreased $H_{c}$ and increased $M_{sat}$ at x=0.2 and 0.3 can be explained that the ${\alpha}$-$Fe_2O_3$ phases have completely disappeared at x=0.3 and so, non-magnetic defects are minimized. The $M_{sat}$ was slightly decreased and the $H_{c}$ was increased above at x=0.3 because the increase of grain boundary due to smaller grain size acts as defects during magnetization process.