• Title/Summary/Keyword: Phase Diagram

Search Result 522, Processing Time 0.027 seconds

Preparation of Zirconium Nitride by Nitridation of Zirconia and its Physical Characteristics (Zirconia로부터 Zr 질화물의 합성 및 물리화학적 특성)

  • Ahn, Beom-Shu;Sung, Ki-Chun
    • Journal of the Korean Applied Science and Technology
    • /
    • v.20 no.4
    • /
    • pp.358-365
    • /
    • 2003
  • Zirconium nitride powders were synthesized at a relatively lower temperature using methane as a reducing agent in the nitridation of zircoia. $ZrO_2$ powder was prepared by a sol-gel technique. The resulting sol-gel was centrifuged, and the gel was washed with deionized water. Anhydrous ammonia was used as the nitrogen source and methane was used as the reducing agent. Conversion diagrams show the equilibrium solid phase as a function of reagent concentrations for a specific temperature and gas pressure for the reagent system $NH_3-ZrO_2-CH_4$. The reagent concentration ranges within which pure ZrN is formed increase with increasing reaction temperature. Low pressure with an excess of hydrogen decreases the reaction temperature at which pure ZrN is formed. Low pressure together with the introduction of excess hydrogen into the reaction system increases Zr and N conversion efficiency and retards C deposition.

Synthesis of SnO2 Powders by Oxidation Heat Treatment of Nano-sized Sn Powders and Their Microstructural Characteristics (나노크기 Sn 분말의 산화열처리에 의한 SnO2분말의 합성 및 미세조직 특성)

  • Oh, Sung-Tag;Lee, Sung-Il;Joo, Yeon-Jun
    • Journal of Powder Materials
    • /
    • v.14 no.5
    • /
    • pp.287-291
    • /
    • 2007
  • Oxidation behavior and microstructural characteristics of nano-sized Sn powder were studied. DTA-TG analysis showed that the Sn powder exhibited an endothermic peak at $227^{\circ}C$ and exothermic peak at $560^{\circ}C$ with an increase in weight. Based on the phase diagram consideration of Sn-O system and XRD analysis, it was interpreted that the first peak was for the melting of Sn powder and the second peak resulted from the formation of $SnO_2$ phase. Microstructural observation revealed that the $SnO_2$ powder, heated to $1000^{\circ}C$ under air atmosphere, consisted of agglomerates with large particle size due to the melting of Sn powder during heat treatment. Finally, fine $SnO_2$ powders with an average size of 50nm can be fabricated by controlled heat treatment and ultrasonic milling process.

A Study on Integrated SE Process for the Development of the Railway Systems with Safety Assessment Included (철도 시스템 개발에서 시스템공학 프로세스와 안전성 평가를 동시에 고려한 통합 프로세스에 관한 연구)

  • Yoon, Jae-Han;Lee, Jae-Chon;Hong, Seon-Ho
    • Journal of the Korean Society for Railway
    • /
    • v.10 no.4
    • /
    • pp.438-443
    • /
    • 2007
  • This paper proposes an integrated SE process for the development of railway systems with safety assessment included. Although the safety assessment process must be performed with SE process properly with good coordination, the interfaces between the two processes have not been clear. Thus, in many of safety critical system developments in Korea, it is difficult to assess safety in proper development phase. The process model proposed in this paper is based on both the concept of system life cycle and the repetitive use of SE process. In each of development phases, appropriate safety assessment methods are described. Also the evaluation of the integrated system incorporating safety factors is described. The resultant process model is expressed by the Enhanced Functional Flow Block Diagram (EFFBD) using a CASE tool. The model also allows timeline analysis for identifying activity flow and data flow, resulting in the effective management of process. In conclusion, the integrated process enable both the SE process and safety assessment process to cooperate with each other from early development phase throughout the whole system life cycle.

A Precipitation of Ammonium Uranyl Carbonate from Uranylnitrate Solution (UO$_2$(NO$_3$)$_2$ 용액으로부터 Ammonium Uranyl Carbonate 제조)

  • 김응호;김형수;이규암;유재형;최청송
    • Journal of the Korean Ceramic Society
    • /
    • v.35 no.6
    • /
    • pp.559-568
    • /
    • 1998
  • Studies of preparation condition and characteristics of AUC(ammonium uranyl carbonate) were carried out to optimize AUC process with different reactor sizes and precipitation methos. As results four types of precipitates with different chemical compositions and morphologies were obtained from the reaction of {{{{ {(NH }_{4 }) { }_{2 } {CO }_{3 } }} with {{{{ {UO }_{2 }( {NO }_{3 }) { }_{2 } }} solution. A phase diagram has been made and crystal structure and chemical composition of each phase have been characterized by using SEM X-ray IR and thermal analysis. It was found that ammonium uranyl carbonate {{{{ {(NH }_{4 }) { }_{4 } {UO }_{2 } {(CO }_{3 }) { }_{3 } }} with monoclinic crystal morphology could be syn-thesized when the mole ratio of in {{{{ {(NH }_{4 }) { }_{2 } {CO }_{3 }/ {UO }_{2 } {(NO }_{3 }) { }_{2 } }} in the solution was higher than 5 Also a mechanism and a precipitating condition on rounding of the AUC particle were examined in the course of the AUC pre-cipitation. The rounding of the AUC particle was possible only by external circulation using pump not by internal circulation using agitator.

  • PDF

A Multifunctional Three-Phase Electronic Step-Down Transformer with Constant Output Voltage Characteristics (정전압 출력 특성을 갖는 다기능 3상 전자식 강압형 변압기)

  • 최남섭
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.5 no.2
    • /
    • pp.309-313
    • /
    • 2001
  • In this paper, a multifunctional three-phase electronic step-down transformer with output voltage stabilization characteristics is presented for custom power applications. The proposed electronic transformer has some advantages and features as follows: 1) It has 40 % weights lighter than that of commercial magnetic transformer, 2) It has output voltage stabilization characteristic with regulated output voltage over input variations, 3) It cab be operated as circuit breaker in the case of emergency, 4) It can be operated with so called soft starting function. Moreover, the electronic transformer may have stand-by power cutoff function and act as distortion compensator. This paper show the circuit diagram and present its features through various PSPICE simulations.

  • PDF

The study of Controlling chaos for Bonhoeffer-van der Pol oscillation model by small parameter perturbation (Bonhoeffer - van der Pol 오실레이터 모델에서의 미소 파라미터 섭동에 의한 카오스 제어)

  • Bae, Yeong-Chul;Ko, Jae-Ho;Yim, Wha-Yeong
    • Proceedings of the KIEE Conference
    • /
    • 1995.07b
    • /
    • pp.817-819
    • /
    • 1995
  • Applied by periodic Stimulating Currents in Bonhoeffer-Van der Pol(BVP) model, chaotic and periodic phenomena occured at specific conditions. The conditions of the chaotic motion in BVP comprised 0.7182< $A_{1}$ <0.792 and 1.09< $A_{1}$ <1.302 proved by the analysis of phase plane, bifurcation diagram, and lyapunov exponent. To control the chaotic motion, two methods were suggested by the first used the amplitude parameter $A_{1}$,$A_{1}={\varepsilon}((x-x_{s})-(y-y_{s}))$ and the second used the temperature parameter c, c=c$(1+ {\eta}cos{\Omega}t)$ which the values of $\eta$, ${\Omega}$ varied respectlvly, and $x_{s}$, $y_{s}$ are the periodic signal. As a result of simulating these methods, the chaotic phenomena was controlled with the periodic motion of periodisity. The feasibilities of the chaotic and the periodic phenomena were analysed by phase plane and lyapunov exponent.

  • PDF

A Basic Study on Estimation Model Development by Applying Probabilistic Forecasting Method for Determining Optimal Price of Residential Officetel (확률론적 추정 기법을 적용한 주거형 오피스텔의 최적 분양가 산정 모델 개발 기초연구)

  • Jang, Jun-Ho;Kim, Tae-Hui;Ha, Sung-Eun;Son, Ki-Young
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2017.11a
    • /
    • pp.191-192
    • /
    • 2017
  • In response to the economic depression, the demand for fixed rent income has increased according to the easing construction regulations. it caused indiscriminated investment to stakeholders. This leads to oversupply in the multi-family Housing market and increases unsold housing and vacancy rates except specific area such as Gangnam-gu.In order to solve this issue, although studies on the optimization price of apartment houses has been conducted, the study is insufficient regarding on residential officetel. Therefore, the objective is to suggest a basic study on optimal price estimation model development by using probabilistic forecasting method in planning phase. To achieve the objective, first, variables are defined such as expenses, financial costs, income, etc. Second, causal loop diagram is suggested. Third, basic optimization prices estimation model is developed. In the future, this study can be used as one of decision making tools in planning phase of officetel development projects.

  • PDF

A Study of Metallurgical Phenomena in Austenitic Stainless Steel Fusion Welds (I) -Weldability of Commercial Austenitic Stainless Steels- (오스테나이트계 스테인리스강 용접부의 금속학적 현상에 관한 연구(I) - 시판 오스테나이트계 스테인리스강의 용접성 -)

  • 이종섭;김숙환
    • Journal of Welding and Joining
    • /
    • v.16 no.3
    • /
    • pp.111-120
    • /
    • 1998
  • To predict and evaluate metallurgical and mechanical behavior of th welds, it is essential to understand solidification behavior and microstructural evolution experienced in the welds, neither of which follows the equilibrium phase diagram because of rapid heating and cooling conditions. Metallurgical phenomena in austenitic stainless steel fusion welds, types 304, 309S, 316L, 321 and 304N, were investigated in this study. Autogenous GTA welding was performed on weld coupons, and primary solidification mode and phase distribution were investigated from the welds. Varestraint test was employed to evaluate solidification cracking susceptibilities of the alloys. GTA weld fusion zones in type 304, 321 and 304N stainless steels experienced primary ferrite solidification while those in type 309S primary austenite solidification. Type 316L exhibited a mixed type of primary ferrite and primary austenite solidification. The primary solidification mode strongly depended on $Cr_{eq}/Ni_{eq}$ ratio. In terms of solidification cracking susceptibility, type 309S that solidified as primary austenite exhibited high cracking susceptibility while the alloys experienced primary ferrite solidification showed low cracking susceptibility. The relative ranking in solidification cracking susceptibility was type 304=type 304N < type 321 < type 316L < type 309S.

  • PDF

Simulation Function of Railway Station Project by Virtual Construction Technology (가상건설기법에 의한 철도역사 시설물 시공시뮬레이션 기능 구축)

  • Kang, Leen-Seok;Moon, Jin-Seok;Kwon, Jung-Hee
    • Journal of the Korean Society for Railway
    • /
    • v.11 no.5
    • /
    • pp.433-440
    • /
    • 2008
  • Virtual construction methodology enables to construct project facility from design phase to construction phase in 3D virtual environment. It is a technique that can solve problems of construction in virtual construction process. This study suggests some methodologies of virtual construction and developed a system for a railway station in Honam express railway project based on suggested methodologies. This study developed layout review and layer simulation functions. Those functions can improve the effectiveness of 3D simulation and the virtual construction system can be used as a verification tool for construction process of various construction projects.

A BEHAVIOR-PRESERVING TRANSLATION FROM FBD DESIGN TO C IMPLEMENTATION FOR REACTOR PROTECTION SYSTEM SOFTWARE

  • Yoo, Junbeom;Kim, Eui-Sub;Lee, Jang-Soo
    • Nuclear Engineering and Technology
    • /
    • v.45 no.4
    • /
    • pp.489-504
    • /
    • 2013
  • Software safety for nuclear reactor protection systems (RPSs) is the most important requirement for the obtainment of permission for operation and export from government authorities, which is why it should be managed with well-experienced software development processes. The RPS software is typically modeled with function block diagrams (FBDs) in the design phase, and then mechanically translated into C programs in the implementation phase, which is finally compiled into executable machine codes and loaded on RPS hardware - PLC (Programmable Logic Controller). Whereas C Compilers are fully-verified COTS (Commercial Off-The-Shelf) software, translators from FBDs to C programs are provided by PLC vendors. Long-term experience, experiments and simulations have validated their correctness and function safety. This paper proposes a behavior-preserving translation from FBD design to C implementation for RPS software. It includes two sets of translation algorithms and rules as well as a prototype translator. We used an example of RPS software in a Korean nuclear power plant to demonstrate the correctness and effectiveness of the proposed translation.