• Title/Summary/Keyword: Phase Behavior

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TCC behavior of a shell phase in core/shell structure formed in Y-doped BaTiO3: an individual observation (Yttrium이 첨가된 BaTiO3에서 형성된 core/shell 구조에서 shell의 TCC 거동: 독립적 관찰)

  • Jeon, Sang-Chae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.3
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    • pp.110-116
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    • 2020
  • Grains in the BaTiO3, which is used for a dielectric layer in MLCC(Multi-Layer Ceramic Capacitor) are necessary to form core/shell structure for a stable TCC(Temperature Coefficient of Capacitance) behavior. The shell property has been deduced from the whole TCC behavior of core/shell structure due to its tiny size, ~ few ㎛. This study demonstrates the individual TCC behavior of the shell phase measured by micro-contact measurement in a temperature range between 35 and 135℃. Pt electrode pairs deposited on an enlarged core/shell structure in a diffusion couple sample made the measurement possible. As a result, the DPT (Diffusion Phase Transition) behavior of the shell phase was revealed as a different TCC behavior from that of the core: a broad peak with Tm at 65℃. This would be also useful experimental data for a modelling that depicts dielectric-temperature behavior of core/shell structure.

Effect of Neutral Solvent on the Phase Behavior of Polystyrene-block-Poly(n-butyl methacrylate) Copolymers

  • Li, Chaoxu;Li, Guang-Hua;Moon, Hong-Chul;Lee, Dong-Hyun;Kim, Jin-Kon;Cho, Jun-Han
    • Macromolecular Research
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    • v.15 no.7
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    • pp.656-661
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    • 2007
  • The effects of a neutral solvent of dioctyl phthalate (DOP) on the phase behavior of symmetric polystyrene-block-poly(n-butyl methacrylate) copolymers (PS-b-PnBMA) were assessed herein. Closed-loop phase behavior with a lower disorder-to-order transition (LDOT) and an upper order-to-disorder transition (UODT) was observed for PS-b-PnBMA/DOP solution when the quantity of DOP was carefully controlled. When the molecular weight of PS-b-PnBMA became larger, the LDOT did not appreciably change at smaller quantities of DOP. With larger quantities of DOP, the reduction in the UODT is greater than the increase in the LDOT. This behavior is discussed in accordance with a molecular theory predicated on a compressible random-phase approximation.

Effect of Cosurfactant on Microemulsion Phase Behavior in NP7 Surfactant System (보조계면활성제가 NP7 계면활성제 시스템의 마이크로에멀젼 형성에 미치는 영향에 관한 연구)

  • Lim, HeungKyoon;Lee, Seul;Mo, DaHee;Lim, JongChoo
    • Applied Chemistry for Engineering
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    • v.22 no.4
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    • pp.416-422
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    • 2011
  • In this study, the effect of cosurfactant on the phase equilibrium and dynamic behavior was studied in systems containing NP7 nonionic surfactant solutions and nonpolar hydrocarbon oils. All cosurfactants used during this study such as n-pentanol, n-octanol and n-decanol acted as a hydrophobic additive and thus promoted the transition from an oil in water (O/W) microemulsion (${\mu}E$) in equilibrium with an excess oil phase to a three-phase region containing excess water, excess oil, and a middle-phase microemulsion and further to a water in oil (W/O) ${\mu}E$ in equilibrium with the excess water phase. The transition temperature was found to decrease with both increases in the chain length and amount of addition of a cosurfactant. Dynamic behavior studies under O/W ${\mu}E$ conditions showed that an oil drop size decreased with time due to the solubilization into micelles. On the other hand, both the spontaneous emulsification of water into the oil phase and the expansion of oil drop were observed under W/O ${\mu}E$ conditions because of the diffusion of surfactant and water into the oil phase. Under conditions of a three-phase region including a middle-phase ${\mu}E$, both the rapid solubilization and emulsification of the oil into aqueous solutions were found mainly due to the existence of ultra-low interfacial tension. Dynamic interfacial tension measurements have been found to be in a good agreement with dynamic behavior results.

Nonlinear Behavior in Love Model with Discontinuous External Force

  • Bae, Youngchul
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • v.16 no.1
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    • pp.64-71
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    • 2016
  • This paper proposes nonlinear behavior in a love model for Romeo and Juliet with an external force of discontinuous time. We investigated the periodic motion and chaotic behavior in the love model by using time series and phase portraits with respect to some variable and fixed parameters. The computer simulation results confirmed that the proposed love model with an external force of discontinuous time shows periodic motion and chaotic behavior with respect to parameter variation.

Precipitation Behavior of Laves Phase and Mechanical Properties of 10%Cr Ferritic Heat-resistant Steel Applied to the Power Plants (발전플렌트용 10Cr페라이트 내열강의 라베스상 석출거동 및 기계적 성질)

  • Kang, C.Y.;Nam, K.W.;Kim, H.J.;Kim, C.G.;Bae, D.S.;Lee, J.M.
    • Journal of Power System Engineering
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    • v.5 no.1
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    • pp.97-103
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    • 2001
  • The present study was investigated changes of precipitation behaviour of laves phase in ferrite single phase and ferrite-martensite dual phase and the mechanical properties of 10%Cr ferritic alloys. In the ferrite phase, laves phase was mainly precipitated, whereas in the martensite phase, carbide was preferentially formed during the initial stage of aging and with increasing aging time. Laves phase and carbide were simultaneously precipitated by precipitation of laves phase at around carbide. Strength and toughness were lowered by the disk-type precipitator in the initial stage of aging and toughness was recovered with increasing of aging time and then, decreasing by precipitation of laves phase.

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Abnormal Grain Growth Mechanism of Calcium Hexaluminate Phase

  • Song, Jun-Ho;Jo, Young-Jin;Bang, Hee-Gon;Park, Sang-Yeup
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.525-526
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    • 2006
  • Calcium-hexaluminate phase $(CA_6)$ is known to be effective for the crack shielding due to the spinel block crystal structure. In this study, we focused to the control of $CA_6$ morphology for good damage tolerance behavior in alumina and zirconia/calcium-hexaluminate $(CA_6)$ composites. Calcium-hexaluminate $(CA_6)$ composites were prepared from zirconia, alumina and calcium carbornate powders. Calcium-hexaluminate $(CA_6)$ phase was obtained by the solid reaction through the formation of intermediate phase $(CA_2)$. $CA_6$ phase showed the column type abnormal grain grown behavior composed of small blocks. Due to the typical microstructure of $CA_6$, alumina and zirconia/calcium-hexaluminate composites provide a well controlled crack propagation behavior.

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Effect of cooling rate on the post-fire behavior of CFST column

  • Afaghi-Darabi, Alireza;Abdollahzadeh, Gholamreza
    • Computers and Concrete
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    • v.23 no.4
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    • pp.281-294
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    • 2019
  • The post-fire behavior of structural elements and the cooling process has always been one of the main concerns of the structural engineers. The structures can be cooled at different rates, where they affect the structure's behavior. In the present study, a numerical model has been developed using the Abaqus program to investigate the effect of cooling rate on the post-fire behavior of the CFST column. To verify the model, results of an experimental study performed on CFST columns within a full heating and cooling cycle have been used. In this model, coMParison of the residual strength has been employed in order to examine the behavior of CFST column under different cooling rates. Furthermore, a parametric study was carried out on the strength of steel and concrete, the height of the specimens, the axial load ratio and the cross-sectional shape of the specimen through the proposed model. It was observed that the cooling rate affects the behavior of the column after the fire, and thus the higher the specimen's temperature is, the more effect it has on the behavior. It was also noticed that water cooling had slightly more residual strength than natural cooling. Furthermore, it was recognized from the parametric study, that by increasing the strength of steel and concrete and the load ratio, as well as modifying the cross-sectional shape from circular to square, residual strength of column at the cooling phase was less than that of the heating phase. In addition, with reducing column height, no change was witnessed in the column behavior after the cooling phase.

Investigation on reverse flow characteristics in U-tubes under two-phase natural circulation

  • Chu, Xi;Li, Mingrui;Chen, Wenzhen;Hao, Jianli
    • Nuclear Engineering and Technology
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    • v.52 no.5
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    • pp.889-896
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    • 2020
  • The vertically inverted U-tube steam generator (UTSG) is widely used in the pressurized water reactor (PWR). The reverse flow behavior generally exists in some U-tubes of a steam generator (SG) under both single- and two-phase natural circulations (NCs). The behavior increases the flow resistance in the primary loop and reduces the heat transfer in the SG. As a consequence, the NC ability as well as the inherent safety of nuclear reactors is faced with severe challenges. The theoretical models for calculating single- and two-phase flow pressure drops in U-tubes are developed and validated in this paper. The two-phase reverse flow characteristics in two types of SGs are investigated base on the theoretical models, and the effects of the U-tube height, bending radius, inlet steam quality and primary side pressure on the behavior are analyzed. The conclusions may provide some promising references for SG optimization to reduce the disadvantageous behavior. It is also of significance to improve the NC ability and ensure the PWR safety during some accidents.

Yielding Behavior and Strain Aging Properties of Bake Hardening Steel with Dual-Phase Microstructure (2상 조직을 갖는 소부경화강의 항복 거동과 변형 시효 특성)

  • Lee, Seung-Wan;Lee, Sang-In;Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.30 no.6
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    • pp.315-320
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    • 2020
  • This study deals with the yielding behavior and strain aging properties of three bake hardening steels with dual-phase microstructure, fabricated by varying the annealing temperature. Bake hardening and aging tests are performed to examine the correlation of martensite volume fraction with yielding behavior and strain aging properties of the bake hardening steels with dual-phase microstructure. The volume fraction of martensite increases with increasing annealing temperature. Room-temperature tensile test results show that the yielding behavior changes from discontinuous-type to continuous-type with increasing volume fraction of martensite due to higher mobile dislocation density. According to the bake hardening and aging tests, the specimen with the highest fraction of martensite exhibited high bake hardening with low aging index because solute carbon atoms in ferrite and martensite effectively diffuse to dislocations during the bake hardening test, while in the aging test they diffuse at only ferrite due to lower aging temperature.

Spinodal Phase Separation and Isothermal Crystallization Behavior in Blends of VDF/TrFE(75/25) Copolymer and Poly(1,4-butylene adipate) (I) -Spinodal Phase Separation Behavior-

  • Kim, Kap Jin;Kyu, Thein
    • Fibers and Polymers
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    • v.4 no.4
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    • pp.188-194
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    • 2003
  • Phase behavior and spinodal phase separation kinetics in binary blends of a random copolymer of vinylidene fluoride and trifluoroethylene (75/25) [P(VDF/TrFE)] and poly(l,4-butylene adipate) (PBA) have been investigated by means of optical microscopic observation and time-resolved light scattering. The blends exhibited a typical lower critical solution temperature (LCST)∼${34}^{\circ}C$ above the melting temperature of the P(VDF/TrFE) crystals over the entire blend composition range. P(VDF/TrFE) and PBA were totally miscible in the temperature gap between the melting point of P(VDF/TrFE) and the LCST. Temperature jump experiments of the 3/7 P(VDF/TrFE)/PBA blend were carried out on a light-scattering apparatus from a single-phase melt state (${180}^{\circ}C$) to a two-phase region (205∼${215}^{\circ}C$). Since the late stage of spinodal decomposition (SD) is prevalent in the 3/7 blend, SD was analyzed using a power law scheme. Self-similarity was preserved well in the late stage of SD in the 3/7 blend.