• 제목/요약/키워드: Pesticide analysis

검색결과 593건 처리시간 0.028초

농촌과 도시지역 노인약물중독환자의 응급처치와 약물중독안전관리에 대한 연구 (A Comparative Analysis of Elderly Intoxication Patient between Urban and Rural Area for the Safety Management and Emergency Care)

  • 임재동;조병준;성열훈;김선예
    • 대한안전경영과학회지
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    • 제12권1호
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    • pp.19-25
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    • 2010
  • To investigate acute drug intoxication trends in the elderly visited Emergency Medical Centers, Data was collected from the records of poisoning patients visited Five different Hospitals from January 1. 2007 to December 31. 2007. The analysis was conducted by using 135 cases of 624 cases. When considering only the elderly and making comparisons between the urban areas and the rural areas the following data was produced. In regard to patients with acute drug intoxication, the main substance of choice was pesticides. Cases of acute drug intoxication are definitely higher for those categorized as the rural elderly (75.0%) when compared with those categorized as the urban elderly (44.1%). The male to female ratio, those living together as a family, past suicide attempts, mental state and sobriety condition when they came, monthly distribution etc. between the two groups did not demonstrate a difference between them. In regard to reasons given for acute drug intoxication, suicide was the highest at 60.7% of the cases. When comparing accidental reasons for poisoning, the urban elderly, at 34.2% of their cases, were higher than in the rural elderly, at 23.7%. After first aid was administered, the admission rate was higher for the rural elderly (47.4%) than for the urban elderly (33.9%). This shows that the rural elderly have a more severe acute drug intoxication poisoning problem than the urban elderly do.

골프장 연못의 생태적 관리를 위한 환경특성 분석 (Analyses of the Environmental Characteristics of Ponds in Golf Courses for Ecological Management)

  • 안득수;김창환
    • 한국조경학회지
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    • 제33권6호
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    • pp.51-77
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    • 2006
  • Pond management is a critical part of overall golf course management, both during growth and maintenance modes of turf care. This study investigated 48 ponds in nine 18- or 27-hole golf courses to analyze the environmental characteristics of ponds. The research process had three phases: (1) inventory and analysis of grading plans and drainage plans, (2) field verification and interviews with greenskeepers, and (3) analyses of water quality and statistics. All data were collected from May to August in 2004. The results of this study can be summarized as follows: 1. It is desirable to site a golf course in a small watershed with high watershed eccentricity to control storm water runoff efficiently and to minimize soil erosion during construction. 2. The siting and size of a pond should be determined through a land-use analysis of the watershed for the purpose of ecological management. The bigger the forest-to-golf course ratio, the better the water quality will be. 3. The size and capacity of each individual ponds varied and there were many somewhat longish rather than round ponds. 4. There were many differences among golf courses in naturalness of the ponds, and the correlation between naturalness and area of aquatic plants was very high. 5. Analyses of pond water quality indicated that the degrees of Dissolved Oxygen, Chemical Oxygen Demanded and Suspended Solids were relatively low values but Total Phosphorus and Total Nitrogen were too high. Therefore a systematic approach is needed to solve e problem. Pesticide residues were not detected in all ponds. 6. Water depth and area of hydrophyte should be considered when designing an ecological pond. 7. All ponds used storm water as a main source of water supply and added underground water. Aquatic plants and physical methods such as water aeration and spray fountains were the main choices for maintaining a healthy aquatic environment.

Degradation of the Herbicide Butachlor by Laboratory-synthesized Nanoscale $Fe^0$ in Batch Experiments

  • Kim, Hyang-Yeon;Kim, In-Kyung;Han, Tae-Ho;Shim, Jae-Han;Kim, In-Seon
    • Journal of Applied Biological Chemistry
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    • 제49권3호
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    • pp.101-105
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    • 2006
  • Degradation of the herbicide butachlor was investigated using laboratory-synthesized zerovalent iron ($Fe^0$). The synthesized zerovalent iron was determined to be nanoscale powder by scanning electron microscopic analysis. To investigate degradation of butachlor using the synthesized nanoscale zerovalent iron, time-course batch experiments were conducted by treating the solution of butachlor formulation with the iron. More than 90% degradation of butachlor was observed by iron treatment within 24 h. The synthesized nanoscale zerovalent iron showed an increase in particle aggregation in the batch tests. Green rust formation and a pH drop in solutions were observed, suggesting that the oxidation of the iron occurred. When the iron was extracted with dichloromethane, a negligible concentration was found in the extract, suggesting that butachlor did not bind to the iron particles. GC/MS analysis detected the dechlorinated product as a major degradation product of butachlor in the solutions. The data indicate that laboratory-synthesized zerovalent iron functioned as a reductant to remove electron-withdrawing chlorine, giving the dechlorinated product.

동적 농업 비점오염 평가모델 (DANSAT)의 3차원 민감도 분석 (Three-dimensional Sensitivity Analysis of Dynamic Agricultural Nonpoint Source Assessment Tool (DANSAT))

  • 조재필;황세운;모스타기미사이드
    • 한국농공학회논문집
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    • 제51권1호
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    • pp.41-52
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    • 2009
  • 새로 개발된 모형에 대한 민감도 분석은 입력변수의 선정 및 보정을 위한 필요한 지침을 제공하기 위해 수행되어야 할 필수적인 과정이다. 동적 농업비점오염 평가모델 (dynamic agricultural nonpoint source assessment tool, DANSAT)은 농업 최적관리기법(BMP)의 지표 및 지하수에 대한 영향을 평가하기 위해 개발된 3차원 모델이다. 본 연구의 목적은 서로 다른 토층 및 유역내 위치에서 입력변수의 변화에 따른 지표 및 지하관련 출력들의 반응을 토대로 DANSAT의 일반적인 민감도 분석을 수행하는 것이다. 선정된 입력변수들의 변화에 따른 세가지의 지표관련 출력 (유출량, 유사량, 유출수중 농약 부하량) 및 두가지의 지하관련 출력 (지하수로의 유입 유량 및 지하수로의 농약 유입량)의 반응이 고려되었다. 민감한 입력변수들은 하나의 격자만을 이용한 예비 민감도 분석을 통하여 선정되었는데, 대체로 토양 관련 인자들이 지표 및 지하에서 양적/질적으로 민감하게 작용하는 것으로 나타났다. 예비민감도 분석을 통해 선정된 토양입력변수들의 서로 다른 토층에서의 변화에 따른 모형 출력들의 반응을 고려한 수직적 민감도 분석결과, 지표관련 출력들의 경우 지표 부근의 상층 토양의 인자가, 지하관련 출력들의 경우 하부 토층의 인자가 각각 민감하게 작용하는 것으로 평가되었다. 유역내에서 입력변수들의 공간적 위치의 변화에 따른 반응을 고려하는 수평적 민감도 분석결과, 유역 경계의 주변보다 하천 주변에서의 입력변수 변화가 모형의 지표 및 지하관련 출력들에 민감한 것으로 나타났다. 본 연구 결과는 BMP의 지표 및 지하의 수문/수질에 미치는 영향을 평가하기 위해 개발된 DANSAT 모형의 입력변수 선정 및 보정에 유용한 자료로 활용될 것으로 기대된다.

Insecticidal and Repellent Activities of Crude Saponin from the Starfish Asterias Amurensis

  • Park, Hee-Yeon;Kim, Ji-Young;Kim, Hyun-Ju;Lee, Geon-Hwi;Park, Jin-Il;Lim, Chi-Won;Kim, Yeon-Kye;Yoon, Ho-Dong
    • Fisheries and Aquatic Sciences
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    • 제12권1호
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    • pp.1-5
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    • 2009
  • Crude saponin, extracted from the starfish Asterias amurensis, was assessed for its capacity as a biological pesticide. As part of this analysis, its insecticidal and repellent activities, in addition to its acute and chronic toxicities were tested. In comparison with the control group, insecticidal activity of saponin against tobacco cutworm, Spodoptera litura, in kale, Brassica loeracea was low at 36.4%. Repellent activities of the extracted saponin against green peach aphid, Myzus persicae, and S. litura, on soybean leaf, Glycine max and kale were 65.6% and 35.0% at $1^{st}$ day, and 54.5% and 30.0% at $3^{rd}$ day, respectively. Acute and chronic toxicity analysis was carried out using acute immobilizatioin test and reproduction impairment test, respectively. The saponin had 48 h-$EC_{50}$ of $65.21{\mu}g/mL$. Twenty-one day accumulative reproduction after treatment was lower in Daphnia magna at $7{\mu}g/mL$ saponin (78 youngs), compared with the control group (129 youngs). These results indicate that the extracted saponin exhibited some toxicity and has potential as a repellent against insects.

농촌과 도시지역 노인약물중독환자의 응급처치와 약물중독안전관리에 대한연구 (A Comparative Analysis of Elderly Intoxication Patient between Urban and Rural Area for the Safety Management and Emergency Care)

  • 임재동;조병준;성열훈;김선예
    • 대한안전경영과학회:학술대회논문집
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    • 대한안전경영과학회 2009년도 추계학술대회
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    • pp.51-60
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    • 2009
  • To investigate acute drug intoxication trends in the elderly visited Emergency Medical Centers, Data was collected from the records of poisoning patients visited Five different Hospitals from January 1. 2007 to December 31. 2007. The analysis was conducted by using 135 cases of 624 cases. When considering only the elderly and making comparisons between the urban areas and the rural areas the following data was produced. In regard to patients with acute drug intoxication, the main substance of choice was pesticides. Cases of acute drug intoxication are definitely higher for those categorized as the rural elderly (75.0%) when compared with those categorized as the urban elderly (44.1%). The male to female ratio, those living together as a family, past suicide attempts, mental state and sobriety condition when they came, monthly distribution etc. between the two groups did not demonstrate a difference between them. In regard to reasons given for acute drug intoxication, suicide was the highest at 60.7% of the cases. When comparing accidental reasons for poisoning, the urban elderly, at 34.2% of their cases, were higher than in the rural elderly, at 23.7%. After first aid was administered, the admission rate was higher for the rural elderly (47.4%) than for the urban elderly (33.9%). This shows that the rural elderly have a more severe acute drug intoxication poisoning problem than the urban elderly do.

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잔류농약 다성분 동시분석법에 관한 연구(I): GC-ECD 및 NPD를 병렬 사용한 분석 (Simultaneous Determination of Various Pesticides (I): Analysis by GC with ECD and NPD Dual Detectors)

  • 노경아;김진호;김현위;이윤경;박기문
    • 한국식품과학회지
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    • 제29권3호
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    • pp.427-431
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    • 1997
  • 유기인제, 유기염소제, 카바메이트제 및 피레쓰로이드제 농약을 한 번의 전처리와 주입으로 동시에 분석할수 있는 실험법을 연구하였다. 자동 soxhlet 추출 장치로 쌀시료로 부터 농약을 추출해내고, 이 추출물의 용매를 증발시킨후 hexane에 재용해하고 Sep-Pak florisil catridge를 이용한 고체상 추출법으로 정제하였다. Soxhlet 추출의 용매는 acetone을 사용하였고, 정제시의 용출용매로는 ethyl acetate : n-hexane (1:1) 혼합 용매를 사용하였다. 이와 같은 전처리 과정을 거친 시료액을 GC에 주입하고, 하나의 칼럼에 병렬로 연결된 ECD와 NPD를 통해 검출하였다. ECD를 통해서는 유기염소제와 피레쓰로이드제 농약들이 검출되고, NPD를 통해서는 유기인제와 카바메이트제 농약이 선택적으로 동시에 검출되어진다. 이 분석법으로 쌀시료에 대해 5회의 회수율 실험을 하였을 때 dichlorvos와 captan을 제외한 46종 농약이 60% 이상의 회수율을 나타내었고, 5회 반복된 실험치 간의 표준편차는 $1.12{\sim}14.44$의 범위로 나타나 비교적 양호한 재현성을 보였다.

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전작물 재배를 위해 토양에 혼화처리된 Ethoprophos의 후작물 흡수이행 (Uptake and Translocation of Ethoprophos Mixed with Soil for Cultivation of Preceding Crop into Succeeding Crop)

  • 곽세연;이상협;김효영;신병곤;김장억
    • 한국환경농학회지
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    • 제40권2호
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    • pp.92-98
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    • 2021
  • BACKGROUND: Unintentional residual pesticide in soil derived from preceding crops and the transfer to succeeding crops was considered a critical barrier for positive list system (PLS). Thus, an uncertain risk is predicted for ethoprophos applied at cultivation of preceding crop (Korean cabbage) to succeeding crop (spinach). METHODS AND RESULTS: Ethoprophos was treated on soil following the recommended dose and 5 times dose according to the safe use guidelines for Korean cabbage after seeding. On the 4 days after harvesting of preceding crop, spinach was sowed. The initial residual amounts of ethoprophos on soil (7.081-19.493 mg/kg) were decreased to 3.832-7.218 mg/kg until the harvest of Korean cabbage, and then finally decreased to 0.011-0.079 mg/kg after spinach cultivation. The uptake rates of ethoprophos from soil by Korean cabbage were 0.01-0.03% and distributed to root (0.150-0.903 mg/kg) and shoot (0.021-0.151 mg/kg), respectively. The residual amounts of uptake and translocation from preceding crop cultivated soil to spinach edible part were found to be below LOQ. CONCLUSION: The plant back internal (PBI) for ethoprophos is not recommended during sequential cultivation of leafy vegetables, since the residual amounts of ethoprophos in spinach were less than MRL (0.02 mg/kg).

LC-MS/MS에 의한 벌꿀 중 잔류 네오마이신의 분석 (Analysis of residual neomycin in honey by LC-MS/MS)

  • 심영은;정지윤;명승운
    • 분석과학
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    • 제22권4호
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    • pp.319-325
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    • 2009
  • 벌꿀 중에 잔류하는 아미노그라이코사이드 항생제인 네오마이신을 효과적으로 분석하는 방법을 개발하고 방법에 대한 유효성 검증을 수행하였다. 0.1M 염산을 사용하여 벌꿀의 pH를 2로 조절한 후 고체상 추출(SPE) 고체상인 양이온교환 카트리지에 적재한 후 염기성 메탄올로 용리하였다. 용리된 추출물은 이온쌍 시약을 사용한 이온쌍 크로마토그래피법으로 분리한 후 LC/(+)ESI-MS/MS의 MRM 방법으로 분석하였다. 정량분석을 위해서 spike 한 $5.0{\sim}250{\mu}g/kg$ 농도 범위에서 검정곡선은 좋은 직선성 ($r^2$ > 0.9951)을 나타내었다. 분석방법의 상대표준편차는 11.5~18.7%이었고 정확도는 bias로 10.9~20.9%이었다. 확립된 분석방법은 벌꿀 중에서 네오마이신의 분석방법으로 유용하게 사용될 수 있을 것이다.

방제드론 전용노즐의 유효살포폭 내 액적분포 및 수치해석 시뮬레이션 (Simulation of The Effective Distribution of Droplets and Numerical Analysis of The Control Drone-Only Nozzle)

  • 임진택;유성구
    • 문화기술의 융합
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    • 제10권2호
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    • pp.531-536
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    • 2024
  • 최근 농업분야의 스마트 농기계로 분류되고 있는 방제드론은 농촌지역의 고령화 시대를 맞이하여 작업 시간 단축과 방제효과를 높이기 위해 하드웨어 및 소프트웨어를 결합하여 스마트 방제 및 자동방제 시스템 구축을 위해 노력하고 있다. 본 논문에서는 관리관제 및 자동방제 시스템 구축을 위한 기초연구로 방제드론 전용노즐의 특성을 분석하였다. 다양한 드론 모델의 종류, 방제사, 바람, 비행속도, 비행고도, 날씨 조건, UAV 농약 종류 등 다양한 변수를 고려하기 위해서는 노즐의 특성파악과 범용성을 고려하여 약제살포 기준 제시가 가능한 관련 연구가 필요하다. 따라서 다양한 변수 고려가 가능하도록 자체 설계노즐을 기반으로 유동해석(CFD) 시뮬레이션을 실시하고 감수지 실험을 통하여 액적분포의 이론값과 실험값을 비교 분석하였다. 추후 드론운용에 따른 다양한 변수를 고려하여 정확한 비산을 산출하고 관리관제 및 자동방제 시스템에 활용하고자 한다.