• Title/Summary/Keyword: Permeate

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Characteristics of the Sinusoidal Flux Continuous Operation Mode for the Submerged Flat-sheet Membrane Module in Cutting Oil Solution (절삭유 수용액내 침지식 평막 모듈에 대한 사인파형 투과유속 연속운전 방식의 특성)

  • Won, In Hye;Chung, Kun Yong
    • Korean Chemical Engineering Research
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    • v.53 no.5
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    • pp.646-652
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    • 2015
  • In this study transmembrane pressure (TMP) was measured with respect to permeate flux through the submerged flat sheet membrane for the emulsion and semi-synthetic cutting oil solutions. The effective area and nominal pore size of the used microfiltration membrane were $0.02m^2$ and $0.15{\mu}m$, respectively. The experiments were carried out simultaneously for run/stop (R/S) and sinusoidal flux continuous operation (SFCO) modes using two submerged membrane module in the reservoir. TMP for the case of SFCO was maintained under 60% of R/S, and the effect on TMP drop decreased as the permeate flux increased for emulsion cutting oil solution. Membrane fouling for the semisynthetic solution showing low turbidity was induced lower comparing to the emulsion solution. Also, the effect on TMP drop for SFCO decreased during long-term operation.

Gas Permeation Properties of Hydrocarbon/$N_2$ Mixture through PEI-PDMS Hollow Fiber Composite Membranes (Hydrocarbon/$N_2$ 혼합물의 분리를 위한 PEI-PDMS 중공사 복합막의 기체 투과 특성)

  • Lee, Chung Seop;Cho, Eun Hye;Ha, Seong Yong;Rhim, Ji Won
    • Membrane Journal
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    • v.22 no.4
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    • pp.251-257
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    • 2012
  • For the separation and recovery of n-pentane from nitrogen environment, the poly (dimethyl siloxane) (PDMS) composite membranes supported by polyetherimide (PEI) hollow fiber membranes were prepared. To characterize the gas separation properties of the resulting membranes, the permeance of n-pentane and nitrogen, concentrations of permeate and retentate, and recovery ratio were measured for n-pentane and nitrogen mixtures. The permeance of n-pentane and nitrogen, 2485.3 and 9.9 GPU, were observed respectively. As the stage cut decreases and the feed concentration increases, the n-pentane concentration in permeate tends to increase. In the meanwhile, the recovery efficiency tends to increase as the stage cut increases and the feed concentration decreases.

Performance Evaluation of MF Membrane Filtration Pilot System Associated with Pre Coagulation-Sedimentation with Iron-Based Coagulant and Chlorination Treatment (철염계 응집제를 사용한 전응집침전, 전염소처리와 PVDF 재질의 정밀여과 막을 조합한 막 여과 정수처리시스템 평가에 관한 연구)

  • Lee, Sanghyup;Jang, Nakyong;Yoshimasa, Watanabe;Choi, Yongsu
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.5
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    • pp.588-597
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    • 2004
  • In this research, we investigated the variation of transmembrane pressure and permeate water quality with pre coagulation and sedimentation with iron based coagulant and chlorination of feed water for PVDF (polyvinylidene fluoride) based MF membrane filtration. NaCIO was fed to the membrane module with dosage of 0.5mg/L and maintained during filtration. To observe the effect of raw water, three types of raw and processed waters, including river surface water, coagulated water and coagulated-settled water, were applied. In case of river surface water, the transmembrane pressure increased drastically in 500 hours of operation. On the contrary, no significant increase in transmembrane pressure was observed for 1,200 hours of operation for coagulated water and coagulated-settled waters. The turbidity of permeate was lower than a detection limit of equipment for all raw waters. The removal efficiency of humic substances of coagulated water and coagulated-settled water was approximate ten times of that of surface river water. And, the removal efficiency of TOC and DOC was approximate two times of that of surface river water. From the results of plant operation, stable operation was maintained at $0.9m^3/m^2{\cdot}day$ filtration flux through the combination of pre-coagulation and pre-chlorination. However, the water quality of permeate was the best when pre-coagulation-sedimentation process was combined with pre-chlorination.

Process Development of Wastewater Containing Silicon Fine Particles by Ultrafiltration for Water Reuse -III. Permeation Characteristics of Pilot Scale Hollow Fiber Membrane Modules- (한외여과에 의한 Si 미립자 함유폐수 재이용 공정개발(III) -Pilot-Scale 중공사막 모듈에 의한 투과 특성)

  • 전재홍;함용규;이석기;박영태;남석태;최호상
    • Membrane Journal
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    • v.9 no.3
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    • pp.185-192
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    • 1999
  • The ultrafiltration characteristics of wafer processing wastewater produced from semicon¬ductor industry was investigated for wastewater reuse. Using the pilot-scale ultrafiltration system con¬taining poly sulfone hollow fiber membranes (MWCO : 10,000, 20,000, 30,(00), the membrane performance, such as flux, rejection rate and concentration factor for flux was examined. The SDhs, turbidity, electrical conductivity and concentration of Si particles were measured, and the possibility of permeate reuse was validated from the experimental results. It was shown that the flux was recovered by the sweeping with air and water effectively. The permeate flux of 30,000 MWCO membrane was about 5 times higher than that of 10,000 and 20,000 MWCO membranes. The concentration of Si particle in the saw wastewater was analyzed 3.8-5.6 mg/$\ell$ and that of Si particle in the permeate was analyzed less than 0.2${\mu}g$/$\ell$. This means the rejection of silicon particle was over 96%.

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Simulation of Pervaporation Process Through Hollow Fiber Module for Treatment of Reactive Waste Stream from a Phenolic Resin Manufacturing Process (페놀수지 생산공정에서 배출되는 반응성 폐수처리를 위한 중공사막 모듈 투과증발 공정모사)

  • C. K Yeom;F. U. Baig
    • Membrane Journal
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    • v.13 no.4
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    • pp.257-267
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    • 2003
  • For the treatment of reactive phenolic resin waste, a simulation model of pervaporative dehydration process has been developed through hollow fiber membrane module. Some of basic parameters were determined directly from dehydration of the waste liquid through a flat sheet membrane to get realistic values. The simulation model was verified by comparing the simulated values with experimental data obtained from hollow fiber membrane module. Hollow fiber membranes with active layer coated on inside fiber were used, and feed flew through inside hollow fiber. Feed flow rate affected membrane performances and reaction by providing a corresponding temperature distribution of feed along with fiber length. Feed temperature is also a crucial factor to determine dehydration and reaction behavior by two competing ways; increasing temperature increases permeation rate as well as water formation rate. Once the permeate pressure is well below the saturated vapor pressure of feed, permeate pressure had a slightly negative effect on permeation performance by slightly reducing driving force. As the pressure approached the vapor pressure of feed, dehydration performances declined considerably due to the activity ratio of feed and permeate.

Effect of Arrow Root Flour on the Flow Property of Rice Flour-water System (쌀가루 수용액 계의 유동 특성에 미치는 칡 분말의 첨가 효과)

  • Lee, Shin-Young;Oh, Kun-Jun;Jung, Kwang-Seung;Park, Heung-Cho
    • Korean Journal of Food Science and Technology
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    • v.31 no.5
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    • pp.1254-1261
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    • 1999
  • The influence of addition of arrow(Pueraria hirsuta Matsum) root flour and its fractions by ultrafiltration on the flow properties of the rice flour-water systems were investigated. The flow properties of rice flour pastes during cold storage$(5^{\circ}C)$ were measured and the components from arrow root flour responsible for changes of flow properties were screened. Addition of arrow root flour significantly changed the flow properties of rice flour pastes. Permeate fractions by ultrafiltration, representing low molecular weight component fraction, significantly affected the flow property of rice flour paste stored at $5^{\circ}C$. Addition of permeate fraction to rice flour pastes rapidly decreased the consistency index, yield stress and pseudoplasticity, and showed a stability of flow property during storage suggesting the retardation of rice starch retrogradation. Permeate fractions of ultrafiltration were identified as puerarin, daidzein and daidzin known to representive isoflavonoid from arrow root.

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Comparison of membrane distillation with reverse osmosis process for the treatment of anaerobic digestate of livestock wastewater (가축분뇨 혐기 소화액 처리를 위한 막 증발과 역삼투 공정 성능 비교)

  • Kim, Seunghwan;Cho, Jinwoo
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.4
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    • pp.259-266
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    • 2020
  • In this study, a pilot-scale (3 ㎥/day) membrane distillation (MD) process was operated to treat digestate produced from anaerobic digestion of livestock wastewater. In order to evaluate the performance and energy cost of MD process, it was compared with the pilot scale (10 ㎥/day) reverse osmosis (RO) process, expected competitive process, under same feed condition. As results, MD process shows stable permeate flux (average 10.1 L/㎡/hr) until 150 hours, whereas permeate flux of RO process was decreased from 5.3 to 1.5 L/㎡/hr within 24 hours. In the case of removal of COD, TN, and TP, MD process shows a high removal rate (98.7, 93.7, and 99% respectively) stably until 150 hours. However, in the case of RO process, removal rate was decreased from 91.6 to 69.5% in COD and from 93.7 to 76.0% in TP during 100 hours of operation. Removal rate of TN in RO process was fluctuated in the range of 34.5-62.9% (average 44.6%) during the operation. As a result of energy cost analysis, MD process using waste heat for heating the feed shows 18% lower cost compare with RO process. Thus, overall efficiency of the MD process is higher then that of the RO process in terms of permeate flux, removal rate of salts, and operating cost (in the case of using waste heat) in treating the anaerobic digestate of livestock wastewater.

Application of fluorescent particles as a tracer to detect the membrane surface damage in a pilot scale membrane bioreactor (형광입자를 이용한 분리막 표면 검측 방법의 파일럿 규모 플랜트 적용)

  • Kim, Choah;Kim, Hee Jun;Cho, Jinwoo
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.1
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    • pp.33-40
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    • 2016
  • In this study, a fluorescent silica nano particle is used as the surrogate for challenging test of membrane surface integrity. The particles are functionalized by a fluorescent dying agent so that as an ultraviolet light is imposed a bright fluorescent image from the particles can be taken. If a membrane surface is damaged and has a compromised part larger than the size of surrogate the fluorescent particles would pass through and contained in the permeate. An operator can directly notice whether the membrane surface is damaged or not by detecting a fluorescent image taken from the permeate. Additionally, the size of compromised part is estimated through analysing the fluorescent image in which we surmise the mass of particles included in the permeate by calculating an average RGB value of the image. The pilot scale experiments showed that this method could be applied successfully to determine if a membrane surface had a damaged parts regardless of the test condition. In the testing on the actual damaged area of $4.712mm^2$, the lowest error of estimating the damaged area was -1.32% with the surrogate concentration of 80 mg/L, flux of $40L/m^2/hr$ for 25 minutes of detection. A further study is still going on to increase the lowest detection limit and thus decrease the error of estimation.

A Numerical Analysis for Estimations of Osmotic Pressure of Colloidal Suspension and Gradient Diffusion Coefficient of Particles from Permeate Flux Experiments (투과플럭스 실험으로부터 콜로이드 서스펜션의 삼투압과 입자의 구배확산계수 산출을 위한 수치적 해석)

  • 전명석
    • Membrane Journal
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    • v.12 no.2
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    • pp.90-96
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    • 2002
  • A novel methodology on the calculations of osmotic pressure and gradient diffusion coefficient has been provided ill the present study, by applying a succinct numerical analysis on the experimental results. Although both the osmotic pressure and the gradient diffusion coefficient represent a fundamental characteristic in related membrane filtrations such as microfiltration and ultrafiltration, neither theoretical analysis nor experiments can readily determine them. The osmotic pressure of colloidal suspension has been successfully determined from a relationship between the data of the time-dependent permeate flux, their numerical accumulations, and their numerical derivatives. It is obvious that the osmotic pressure is gradually increased, as the particle concentration increases. The thermodynamic coefficient was calculated from the numerical differentiation of the correlation equation of osmotic pressure, and the hydrodynamic coefficient was evaluated from the previously developed relation for an ordered system. Finally, the estimated gradient diffusion coefficient, which entirely depends on the particle concentration, was compared to the previous results obtained from the statistical mechanical simulations.