• Title/Summary/Keyword: Permeance

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A Study on the Development and Performance Evaluation of Permeable GFRP Strengthening Panel for RC Structure (투수성 GFRP 보강 복합체 개발 및 투수성에 대한 연구)

  • Jo, Byung Wan;Kang, Seok Won;Park, Cheol;Kim, Jang Wook
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.3
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    • pp.65-73
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    • 2013
  • Recently the exterior attaching reinforcement method is being often used by using FRP (Fiber Reinforced Polymer) as a method of strengthening concrete structure. this FRP exterior attaching reinforcement method has several advantages like high intensity, stiffness, good durability and easy installment comparing to its weight. but its structure is airtight covered by reinforcement material whose water permeability is low and water can't be discharged, thus it may provoke a damage to the structure after a long while. the main purposes of this study are to develop GFRP reinforcement material which can discharge the surface water properly and to measure its special functions. for this, we have changed the normal reinforcement material to water permeable structure and measured its water permeance modulus by an indoor test which shows the process of water permeance with the parameter of contained GFRP quantity. also tried to verify the measured value of the water permeance modulus in theory by analyzing the numbers on water permeance process. the test result showed that the biggest quantity of water, 0.5129 g/h $m^2$ was discharged when the fiber contained quantity reached at 75% and the tensile strength was also biggest by 476.6MPa at 75%, so it appeared that COSREM GP panel with 75% fiber contained quantity is the best in ventilation and structure.

Effect of Non-ionic Additive on Morphology and Gas Permeation Properties of Polysulfone Hollow Fiber Membrane (비이온계 첨가제에 의한 폴리술폰계 중공사 막의 모폴로지 조절과 기체투과 특성)

  • Lee, Hye Jin;Koh, Mi Jin;Kim, Duek Ju;Nam, Sang Yong
    • Membrane Journal
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    • v.22 no.3
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    • pp.224-233
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    • 2012
  • To improve permeation performance of gas separation membrane, polysulfone hollow fiber membrane was prepared by wet-dry phase inversion method using Triton X-100 as non-ionic additive. And variation of gas permeation behavior by additive was investigated. Various spinning conditions such as air gap, concentration of polymer, dope tank temperature were controlled and these effects were studied. The morphology and gas permeation property of hollow fiber membranes were investigated using scanning electron microscope (SEM) and bubble flow meter respectively. We confirmed that the membranes added with Triton X-100 had a smooth external skin at various air gap length conditions. The macrovoids of these hollow fiber membranes were more developed with increase of air-gap from 4 to 90 cm and that induced higher permeance. The permeance of polysulfone membranes has the higher value at comparatively lower concentration polymer (30 wt% polysulfone) and lower concentration of additive (15 wt% Triton X-100). When temperature in dope tank was controlled, the membranes prepared at $100^{\circ}C$ showed low permeance because of volatilization of additive and solvent.

Elucidation of the Mechanism of Propylene/Propane Separation through Faujasite Zeolite Membrane (Faujasite 제올라이트 분리막을 통한 프로필렌/프로판 분리 메카니즘 규명에 대한 연구)

  • Min, Hae-Hyun;Park, You-In;Chang, Jong-San;Park, Yong-Ki;Cho, Churl-Hee
    • Membrane Journal
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    • v.28 no.5
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    • pp.351-360
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    • 2018
  • In this study, propylene/propane separation mechanism through NaY zeolite membrane was investigated. As permeation temperature increased, both propylene and propane permeances increased, saturated and decreased again, and a maximum selectivity was shown at around 50 to $60^{\circ}C$. Propane permeance in mixed gas experiment was much smaller than that in single gas experiment, and propylene/propane mixed gas selectivity was much larger than single gas permselectivity. As permeation time increased in transient permeation experiment, propylene permeance initially increased and saturated, while propane permeance decreased and saturated. All the experimental results announced that propylene/propane separation through NaY zeolite membrane was from preferentially adsorbed propylene molecules. The adsorbed propylene molecules efficiently prevented propane molecules from permeating through the membrane, and sufae diffused through the membrane. NaY zeolite capillary membrane prepared in the present study showed a high mixed gas selectivity of 12 and high propylene permeance of 497 GPU for a propylene/propane (89 : 11) mixture at $50^{\circ}C$ and 4 bar. Therefore, it was concluded that NaY zeolite membrane is one of promising membrane materials for propylene/propane separation due to the low cost and high separation performance.

Feasibility Study of Employing a Catalytic Membrane Reactor for a Pressurized CO2 and Purified H2 Production in a Water Gas Shift Reaction

  • Lim, Hankwon
    • Clean Technology
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    • v.20 no.4
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    • pp.425-432
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    • 2014
  • The effect of two important parameters of a catalytic membrane reactor (CMR), hydrogen selectivity and hydrogen permeance, coupled with an Ar sweep flow and an operating pressure on the performance of a water gas shift reaction in a CMR has been extensively studied using a one-dimensional reactor model and reaction kinetics. As an alternative pre-combustion $CO_2$ capture method, the feasibility of capturing a pressurized and concentrated $CO_2$ in a retentate (a shell side of a CMR) and separating a purified $H_2$ in a permeate (a tube side of a CMR) simultaneously in a CMR was examined and a guideline for a hydrogen permeance, a hydrogen selectivity, an Ar sweep flow rate, and an operating pressure to achieve a simultaneous capture of a concentrate $CO_2$ in a retentate and production of a purified $H_2$ in a permeate is presented. For example, with an operating pressure of 8 atm and Ar sweep gas for rate of $6.7{\times}10^{-4}mols^{-1}$, a concentrated $CO_2$ in a retentate (~90%) and a purified $H_2$ in a permeate (~100%) was simultaneously obtained in a CMR fitted with a membrane with hydrogen permeance of $1{\times}10^{-8}molm^{-2}s^{-1}Pa^{-1}$ and a hydrogen selectivity of 10000.

The Permeation Behaviors of $H_2S/CH_4$ using Polyimide Hollow Fiber Membranes (폴리이미드 중공사막을 이용한 $H_2S/CH_4$ 투과거동에 관한 연구)

  • Lee, Hyung-Keun;An, Young-Mo;Kim, Dae-Hoon;Jo, Hang-Dae;Seo, Yong-Seog;Park, Yeong-Seong
    • Membrane Journal
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    • v.19 no.4
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    • pp.261-267
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    • 2009
  • Polyimide which is the glassy polymer has high chemical resistance, thermal stability and high mechanical property. In this study, the polyimide hollow fiber membranes were prepared by the dry-jet wet phase inversion in order to investigate the permeation porperties of the $H_2S$ and $CH_4$. The morphology of prepared hollow fiber membranes and their permeation behaviors of $H_2S$ and $CH_4$ before and after silicon coating were evaluated. The permeance of $H_2S$ and $H_2S/CH_4$ selectivity increased due to plasticization with increasing the feed pressure. The permeance of KSM03b and selectivity of KSM03d were highest among the three type membranes used this experiments. The permeance decreased but the $H_2S/CH_4$ selectivity increased with increasing the air gap. The permeance reduced after silicon coating. However, the selectivity increased and the selectivity of KSM03d was 275 at 7 atm.

Preparation and Characterization of Organic Solvent Reverse Osmosis (OSRO) Membranes Using Polyketone (PK) Supports (폴리케톤(PK) 지지체를 이용한 유기용매 역삼투(OSRO) 분리막의 제조 및 특성 평가)

  • Seoungwoo Kim;Seunghee Hong;Hee Min Park;Yong Taek Lee
    • Membrane Journal
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    • v.34 no.4
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    • pp.205-215
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    • 2024
  • The purpose of this paper was to preparation of organic solvent reverse osmosis (OSRO) membrane using a polyketone (PK) support. The PK support was prepared by non-solvent induced phase separation (NIPS) method, and a polyamide layer was interfacially polymerized on the PK support to fabricate OSRO membrane in the form of thin-film composite (TFC). After that, the surface and cross-sectional morphology of the OSRO membrane were analyzed, and the surface chemical structure of the membrane was analyzed. The water permeance and salt rejection of the OSRO membrane were about 1.28 LMH/bar and 99.0% respectively. The polyamide layer of the OSRO membrane was very stable during 1 day of organic solvent immersion, and the single organic solvent permeance trend was consistent with the organic solvent nanofiltration (OSN) membrane permeance model. The MWCO of the OSRO membrane is 240 g/mol in MeOH. The permeance and separation factor of the OSRO membrane for MeOH-toluene mixture were 200% and 60% higher than those of the commercial OSN membranes respectively.

$CO_2$ Separation Using Surface Modified Silica Membrane (표면개질 실리카막을 이용한 $CO_2$선택투과분리)

  • 김성수;최현교;박홍채;김태옥;서봉국
    • Journal of Environmental Science International
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    • v.9 no.4
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    • pp.311-318
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    • 2000
  • To improve $CO_2$pemselectivity, a modified silica membrane was prepared by chemical vapor deposition with tetraethoxysilane(TEOS)-ethanol-water, and TEOS-ethanol-water-HCI solution at 300-$600^{\circ}C$. The silica was effectively deposited in the mesopores of a ${\gamma}$-alumina film coated on a porous $\alpha$-alumina tube by evacuating the reactants through the porous wall. In this membrane, $CO_2$interacts, to some extent, with the pore wall, and $CO_2$/$N_2$selectivity then exceeds the value of the Knudsen diffusion mechanism, while the membrane derived from TEOS alone has no $CO_2$selectivity. The silica membrane prepared from TEOS-ethanol-water-HCI solution showed that $CO_2$permeance was $2.5$\times$10^{-7}mol/s^{-1}.m^{-2}.Pa^{-1} at 30{\circ}C$ and $CO_2$/$N_2$selectivity was approximately 3. The $CO_2$permeance and selectivity was improved by enlarging the surface diffusion with modification of chemical affinity of the silica pores.

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Cogging Torque and Acoustic Noise Reduction in High Torque BLDC Motors by Teeth Pairings (고정자 잇날 페어링을 이용한 고출력 토크 BLDC 전동기의 코깅 토크 및 소음 저감)

  • Lee, Sang-Min;Hwang, Sang-Mun
    • The Transactions of the Korean Institute of Electrical Engineers B
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    • v.48 no.3
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    • pp.97-103
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    • 1999
  • This paper investigates reduction of acoustic noise and cogging torque in a BLDC motor with larger stator slot open width. Using energy method, cogging torque is analytically determined with airgap MMF function and airgap permeance function and confirmed by FEM analysis. It shows that the cogging torque is firstly governed by NL GNL BNL with the fundamental period of NL, where NL is the least common multiple of the number of slots and the number of poles, GNL, airgap permeance function and BNL, airgap MMF function. It also shows that there exist several tooth width which minimizes the cogging torque, for the motors that smaller slot open width or stator teeth notching is not available. And it proposes a teeth pairing with two different tooth width which can effectively eliminate the cogging torque and thus the acoustic noise. Experimental results show that the proposed teeth pairing reduces the cogging torque by 85% and the acoustic noise by 3.1dB.

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Preparation of Silica Membrane by CVD of Phenyl-Substituted Methoxysilane and $CO_2$ Separation (페닐기로 치환된 Methoxysilane의 CVD에 의한 실리카 분리막의 제조 및 $CO_2$ 분리)

  • Kim, Seong-Su;Seo, Bong-Guk;Lee, Yun-Bok;Park, Hong-Chae;Kim, Tae-Ok
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.622-624
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    • 2001
  • The CVD film of methoxysilane derived from diphenyldimethoxysilane(DPDMS) was formed on the outer surface of a porous ${\alpha}-alumina$ support tube coated(via dipping-drying-calcining) with a boehmite sol(0.3 mol-Al/L). The resulting silica membrane($500^{\circ}C,\;P_{fe}\;=\;130\;Pa$) showed a permeance of $5.18{\times}10^{-8}\;mol\;{\cdot}\;m^{-2}{\cdot}s^{-1}{\cdot}Pa^{-1}\;for\;CO_2$ and a permselectivity of 13.35 for $CO_2/N_2\;at\;30^{\circ}C$.

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