• Title/Summary/Keyword: Permanent charge

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Comparison of Methods of Permanent Charge Measurement in Montmorillonite and Illite (몬모릴로나이트와 일라이트에서 영구전하 측정방법간 비교)

  • Lee, Sang-Ryong;Ok, Yong-Sik;Choi, You-Suk;Lim, Sookil;Kim, Jeong-Gyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.3
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    • pp.136-142
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    • 2004
  • Though diverse methods have been developed to characterize surface charge of soils and pure minerals, there is not still a reliable and rapid method for differentiating permanent charge from variable charge. Thus, it is needed to find out a reasonable method for measuring permanent and pH-dependent charge of soils. In this study various methods such as Cs-adsorption method, Hybrid model, $NH_4{^+}$-adsorption method and theoretical calculation of lattice charge were applied to measure permanent charge of montmorillonite and illite. Calculated lattice charge was $71.82cmol\;kg^{-1}$ and $14.20cmol\;kg^{-1}$ for montmorillonite and illite, respectively. The permanent charge measured by Cs-adsorption method were $78.23cmol\;kg^{-1}$ and $11.13cmol\;kg^{-1}$ for montmorillonite and illite, respectively. The differences between the values measured by Cs-adsorption method and the calculated lattice charge were not different significantly as $6.41cmol\;kg^{-1}$ and $3.07cmol\;kg^{-1}$. But, Hybrid model showed an underestimated values when applied to clay minerals with predominant amounts of permanent charge. The experimental results showed Cs-adsorption method was more reasonable for permanent charge measurement than the Hybrid model for illlte or montmorillonitetype clays.

Artificial Photosynthesis Using Zeolites

  • Castagnola, Norma B.;Dutta, Prabir K.
    • Journal of Photoscience
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    • v.6 no.3
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    • pp.91-96
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    • 1999
  • Zeolites and microporouos materials continue to attract attention as novel hosts for photochemical reactions. Zeolities are attractive because of their ability to selectivity exchange and incorporate species within the void spaces and interconnecting channels, providing a spatial arrangement of molecules. Our research has primarily focused on intrazeolitic electron transfer from excited Ru(bpy)32+ in supercages of zeolite Y to a series of bipyridinium ions. In the Ru(bpy)32+ viologen-zeolite Y samples, the slowing of the back electron transfer from the bipyridinium radical cation to Ru(bpy)32+ allows for charge propagation via self exchange between diquat molecules. This provides an opportunity for permanent charge separation. When the migrating charge on the diquat radical within the zeolite reaches the surface, it can be transferred to a neutral viologen (PVS) in solution, resulting in permanent charge separation. The advantage of long-lived charge separation can be exploited for useful chemistry if suitable catablysts can be assembled on the zeolities. We have studied Ru(bpy)2 as water oxdiation catalysts. We have demonstrated that synthesis of RuO2 fibers on a zeolite via thermal decomposition of Ru3(CO)12 leads to the most active water decomposition catalyst reported to date. Because of the extensive interest of photochemical water reduction to H2, much is known about catalytic systems usin gone electron catalyst, and even more importantly, that no reaction of viologen occurred with H2 over this catalyst. The present challenge is to incorporate all these elements of the system into an architecture and we are examining zeolite membranes for this purpose.

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Andic Properties of Major Soils in Cheju Island II. Electric Charge Characteristics (제주도(濟州島) 대표토양(代表土壤)의 Andic 특성(特性)에 관한 연구 II.전하특성(電荷特性))

  • Song, Kwan-Cheol;Yoo, Sun-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.24 no.4
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    • pp.241-247
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    • 1991
  • Electric charge characteristics of volcanic ash soils in Cheju Island were investigated. For this study, soils of toposequence distributed along the sourthern slope of Mt. Halla, and the major soil groups such as dark brown soils, very dark brown soils, black soils, and brown forest soils were collected and analyzed for extratable acidity, KCl ext. Al, CEC, base saturation, permanent charge and variable charge, etc.. Weolpyeong and Yongheung soils developed on the lower elevations have high $NH_4OAc$ ext. bases, permanent charge and base saturation, and relatively low ext. acidity, CEC and variable charge. For other soils, whose colloidal fractions are dominated by allophane or Al-humus complexes, ext. acidity, CEC, variable charge, and variable charge ratio were very high, and $NH_4OAc$ ext. bases, permanent charge, and base saturation were very low. These trends were especially prominant in the surface. horizons of black soils and brown forest soils dominated by Al-humus complexes. Ext. acidity, CEC($NH_4OAc$), CEC(sum of cations), and variable charge strongly correlated with pyrophosphate ext. carbon. Very dark brown soils and cinder cone soils dominated by allophane showed low KCl ext. Al and relatively high pH, despite their very low base saturation.

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Evaluation of Global Force and Interaction Body Force Density in Permanent Magnet Employing Virtual Air-gap Concept (가상공극개념을 이용한 연구자석의 전체전자기력과 상호체적력밀도 계산)

  • Lee, Se-Hee
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.2
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    • pp.278-284
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    • 2009
  • The global force and interaction body force density were evaluated in permanent magnets by using the virtual air-gap scheme incorporating the finite-element method. Until now, the virtual air-gap concept has been successfully applied to calculate a contact force and a body force density in soft magnetic materials. These force calculating methods have been called as generalized methods such as the generalized magnetic charge force density method, the generalized magnetizing current force density method, and the generalized Kelvin force density method. For permanent magnets, however, there have been few research works on a contact force and a force density field. Unlike the conventional force calculating methods resulting in surface force densities, the generalized methods are novel methods of evaluating body force density. These generalized methods yield the actual total force, but their distributions have an irregularity, which seems to be random distributions of body force density. Inside permanent magnets, however, a smooth pattern was obtained in the interaction body force density, which represents the interacting force field among magnetic materials. To evaluate the interaction body force density, the intrinsic force density should be withdrawn from the total force density. Several analysis models with permanent magnets were tested to verify the proposed methods evaluating the interaction body force density and the contact force, in which the permanent magnet contacts with a soft magnetic material.

Aerosol filtration and electrostatic properties of electrospun nanofiber air filters (전기방사 나노섬유 에어필터의 정전기적 특성 및 에어로졸 여과특성)

  • Park, Hyun-Seol;Lim, Koung Soo
    • Particle and aerosol research
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    • v.5 no.2
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    • pp.71-81
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    • 2009
  • In this study, Nylon 6,6 electrospun (ES) nanofiber filter media were prepared at various spinning conditions. The ES filters tested had no intrinsic electrical charges. The ES filters were triboelectrically charged in the course of filter sample handling, and the charge was drastically decayed in a few hours. On the other hand, the corona charged melt blown filter media showed a permanent electrical charge. The electrical charge state of the ES filters was also examined by comparing collection efficiencies of ES filters for uncharged and charged aerosol particles.

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Analytical Calculation of the 3D Magnetic Field Created by Non-Periodic Permanent Magnet Arrays

  • Zhang, He;Kou, Baoquan;Li, Liyi
    • Journal of international Conference on Electrical Machines and Systems
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    • v.1 no.3
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    • pp.289-294
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    • 2012
  • In this paper, the three-dimensional magnetic field created by non-periodic magnet arrays is calculated analytically. The analytical expression of the magnetic field is derived by using a magnetic charge model. The influence of ferromagnetic boundaries is formulated with an image method. Finally, we compare the results determined by analytical calculations to those from a finite element simulation.

Comparison of the Ion Adsorption Method, Potentiometric Titraion and Backtitration Technique for Surface Charge measurement in Ultisol, Alfisol, and Inceptisol (Ultisol과 Alfisol 및 Inceptisol 토양에서 토양표면전하 측정에 사용된 이온흡착법, 전위차 적정법 및 역적정법간의 비교)

  • Lee, Sang-Eun;Neue, Heins Ulitz;Park, Jun-Kyu;Lim, Sookil H.
    • Korean Journal of Soil Science and Fertilizer
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    • v.26 no.3
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    • pp.160-171
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    • 1993
  • Surface charge characteristics of Ultisol(Luisiana soil from Philippines), Alfisol(Maahas soil from Philippines), and Inceptisol(Yongii soil from Korea) were studied by way of potentiometric titration, backtitration technique, and ion adsorption method(or CEC - AEC method). The PZNC(point of zero net charge) values determined by ion adsorption method were much lower than the natural pHs in all soils, indicating that all soil samples bore net negative surface charge. The PZSE (point of zero salt effect) values determined by potentiometric titration and backtitration technique were identical in Luisiana and Yongii soils but not in Maaghas soil. All soils showed higher PZSE values than PZNC values probably due to the influence of permanent negative charge. The permanent charge calculated by the theory of Uehara and Gillman (1980) occupied quite low portion of the CEC measured at pH 7 in all soils. Backtitration technique corrected errors of potentiometric titration at extreme pH. However, it still overestimate the surface charge compared with ion adsorption method. Therefore, the ion adsorption method was recommanded for the surface charge measurement of the usual soils which have high negative charge components.

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The Effect of Manufacturing Conditions of Coated Yarn Using Anti-Static Thermoplastic Polyurethane M/B on Anti-Static Resistance (대전방지 열가소성폴리우레탄 M/B를 이용한 코팅사 제조 조건이 대전방지성에 미치는 영향)

  • Yedam Jeong;Jieun Kwon;Sunmin Kwon;Seehyeon Chae;Hyunjea Cho;Wooseok Kim;Mikyung Kim;Jongwon Kim
    • Textile Coloration and Finishing
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    • v.35 no.1
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    • pp.20-28
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    • 2023
  • In this study, TPU resin for coating was prepared by varying the mixing ratio of antistatic TPU and recycled TPU to manufacture permanent antistatic materials. The coated yarn was prepared by coating on the nylon yarn, and then the thermal, rheological, mechanical properties and antistatic properties were analyzed. In addition, antistatic properties and durability were confirmed after manufacturing UD fabrics using coated yarns. The mixing ratio of antistatic TPU and recycled TPU was most appropriate at 4:6, and the antistatic property had a surface resistance of 2.20 × 109 Ω and a static charge of 398 V. In the coating process, the coating speed was most appropriate at 0.21 m/s, and the surface resistance of the UD fabric manufactured with the coated yarn manufactured under this condition was 6.80 × 109 Ω and the static charge was 484 V. The UD fabric had a surface resistance of 7.21 × 109 Ω and a static charge of 517 V after washing 10 times, and it was confirmed that the permanent antistatic property was excellent.

A Study on the Multiple Disaster Administration's Problem and Improvement (대형 재해관리의 문제점과 개선방안)

  • Kim, Hak-Soo;Koh, Jae-Moon
    • The Korean Journal of Emergency Medical Services
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    • v.7 no.1
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    • pp.179-198
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    • 2003
  • If see disaster administration system of our country, start in terms of is coping by countermeasure after four immediately after disaster occurrence many problems blessing with a sons by tribe and so on of link nature between formation, disaster administration complete charge utensil's absence, disaster charge manpower and budget be indicated and join. If examine improvement way accordingly, is as following ; Necessity of synthetic disaster administration system, Fire fighting formation's independence guarantee, Integration of fire fighting connection similarity business, Disaster administration's permanent establishment complete charge utensil's necessity, Disaster administration midautumn complete charge utensil at a metropolitan autonomous fire fighting system reorganization, Role division of labor between center and local government, Disaster administration professional human strength positivity, Disaster administration information system construction practical use, Equipment and improvement of budget state, Education public information for safety culture consciousness fixing, Internationalization of fire fighting business, globalization propulsion, Structure, member of rescue confrontation system and efficiency. Fire fighting environment is changing greatly, and fire fighting must become center to correspond to do confrontation that do one thing troble when produce disaster.

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Design of Magnetic Levitating Flywheel Energy Storage System (자기부상형 플라이휠 에너지 저장 장치의 자기베어링 시스템 설계)

  • Yoo, S.;Mo, S.;Choi, S.;Lee, J.;Han, Y.;Noh, M.D.
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.963-967
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    • 2007
  • Flywheel energy storage systems (FESS) have advantages over other types of energy storage methods due to their infinite charge/discharge cycles and environmental friendliness. The system has two radial bearings and one hybrid-thrust bearing. Thrust hybrid-type bearing use permanent magnet to relieve gravity load. The radial bearings were designed to provide sufficient force slew rate considering the unbalance disturbance at the operating speeds. In this paper, we will derive dynamic model of hybrid-type bearing using permanent magnet for thrust bearing and present simulation and stability of the model.

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