• Journal of the Korean Institute of Gas
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• v.1 no.1
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• pp.41-48
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• 1997

The equation of state is widely utilized as a simple model for the prediction of gas properties. There are several equations of state and they often make diverse and hard to believe output of gas properties. In this study, We show a reliability of equation of state for nitrogen, oxygen and argon in pressure range from 1 bar to 30 bar and temperature range from liquefaction to room temperature. We use three equations of state such as Soave-Redlich-Kwong, Peng-Robinson and BWR-LS' equation of state which provided in the Aspen plus. The results were compared with literatures and virial equation. Finally, We report the differences of process calculation of distillation column and expansion turbine in cryogenic air separation plant with change of equation of state.

• Korean Chemical Engineering Research
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• v.48 no.6
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• pp.763-767
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• 2010

High-pressure phase behavior for the binary mixture of 1-propanol with supercritical $CO_2$ has been measured by means of a high-pressure phase equilibrium apparatus equipped with a variable-volume view cell. The equilibrium loci of the pressure - composition and pressure - temperature were obtained for the binary mixture of 1-propanol + $CO_2$ system at 305.15 K, 313.15 K, 323.15 K and 333.15 K, and from 2 MPa to 11 MPa. The critical temperature of the mixture increased with the temperature. The pressure-composition line for the binary mixture of $CO_2$-1-propanol system showed a typical type-II phase behavior. The experimental P-x envelopes were correlated by using the Peng-Robinson equation of state in a satisfactory manner to obtain the parameters with $k_{ij}=0.116$ and ${\eta}_{ij}=-0.065$.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.5
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• pp.1747-1753
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• 2010

In this study, a comparative study was performed to predict the vapor-liquid equilibria with maximum azeotropic pressure for ethanol-benzene binary system between an equation of state model and a liquid activity coefficient model. Peng-Robinson equation of state model with a Panatiotopoulos mixing rules (PRP) was used and NRTL liquid activity coefficient model proposed by Renon was selected. The PRP model, even though it has only two binary adjustable parameters, was not inferior to the NRTL model to predict vapor-liquid equilibria for low pressure region of ethanol-benzene system and showed a better prediction capability for high pressure region of ethanol-benzene system than the NRTL model with three binary interaction parameters.

• Korean Chemical Engineering Research
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• v.53 no.2
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• pp.193-198
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• 2015

The high-pressure phase behavior of a polycaprolactone (Mw=56,145 g/mol, polydispersity 1.2), dichloromethane, and carbon dioxide ternary system was measured using a variable-volume view cell. The experimental temperatures and pressures ranged from 313.15 K to 353.15 K and up to 300 bar as functions of the $CO_2$/dichloromethane mass ratio and temperature, at poly(D-lactic acid) weight fractions of 1.0, 2.0, and 3.0%. The correlation results were obtained from the hybrid equation of state (Peng-Robinson equation of state + SAFT equation of state) for the $CO_2$-polymer system using the van der Waals one-fluid mixing rule. The three binary interaction parameters were optimized by the simplex method algorithm.

• Korean Chemical Engineering Research
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• v.54 no.3
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• pp.350-359
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• 2016

For accurate estimation over the change of pressure and temperature of the vessel during blowdown period, a new dynamic blowdown model was developed in this work. In particular, heat transfer from the vessel wall to discharge gas at both laminar or turbulent flow in the vessel was embedded to the model to increase the accuracy of blowdown estimation. For thermodynamics, the whole blowdown period was discretized into finite pressure decrement steps, and the step size was adjusted so that the calculation can be more efficiently carried out, while maintaining the model's accuracy. Both Peng-Robinson and Soave-Redlich-Kwong equation of states were applied to the model, and the results were compared each other. Finally, the simulation results was compared with Haque and coworkers' experimental results, and it proved high accuracy of the model.

• Journal of the Korean Society of Propulsion Engineers
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• v.26 no.5
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• pp.24-34
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• 2022

In order to predict the cooling performance of a regenerative cooling channel using hydrocarbon fuel operating in the supercritical region, it is essential to predict the thermodynamic properties. In this study, a comparative analysis was performed on two-parameter equations of state (SRK(Soave-Redlich-Kwong), PR(Peng-Robinson) equations of state) and three-parameter equations of state (RK-PR equations of state) to appropriately predict density and specific heat according to the critical compressibility factor of polymer hydrocarbons. Representatively, n-dodecane fuel with low critical compressibility factor and JP-10 fuel with high critical compressibility factor were selected, and an appropriate equation of state was presented when predicting the thermodynamic properties of the two fuels. Finally, the prediction results of density and specific heat were compared and verified with NIST REFPROP data.

• Proceedings of the KAIS Fall Conference
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• 2011.05a
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• pp.489-492
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• 2011

Supercritical fluid technology has been an alternative for purification and separation of biological compounds in cosmetic, food, and pharmaceutical products. Solubility information of biological compounds in supercritical fluids is essential for choosing a supercritical fluid processes. The equilibrium solubility of hinokitiol was measured in supercritical carbon dioxide with a static method in the pressure range from 8 to 40 MPa and at temperatures equal to 313.2, 323.2 and 333.2 K. The experimental data were correlated well by Peng.Robinson equation of state and quasi-chemical nonrandom lattice fluid model.

• Analytical Science and Technology
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• v.27 no.2
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• pp.79-91
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• 2014

Solubility data of carbon dioxide ($CO_2$) in 1-butyl-3-methylpiperidinium bis(trifluoromethylsulfonyl)imide ($[bmpip][Tf_2N]$) ionic liquid are presented at pressures up to about 30 MPa and at temperatures between 303 K and 343 K. As far as we know, the data on the $CO_2$ solubility in the $[bmpip][Tf_2N]$ ionic liquid have never been reported in the literature by other investigators. The solubilities of $CO_2$ were determined by measuring the bubble point or cloud point pressures of the $CO_2+[bmpip][Tf_2N]$ mixtures with various compositions using a high-pressure equilibrium apparatus equipped with a variable-volume view cell. To observe the effect of the cation composing the ionic liquid on the $CO_2$ solubility, the $CO_2$ solubilities in $[bmpip][Tf_2N]$ used in this study were compared with those in 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide ($[bmim]Tf_2N]$). As the equilibrium pressure increased, the $CO_2$ solubility in $[bmpip][Tf_2N]$ increased sharply. On the other hand, the $CO_2$ solubility decreased with increasing temperature. The mole fraction-based $CO_2$ solubilities were almost the same for both $[bmpip][Tf_2N]$ and $[bmim][Tf_2N]$, regardless of temperature and pressure. The phase equilibrium data for the $CO_2+[bmpip][Tf_2N]$ systems have been correlated using the Peng-Robinson equation of state.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.2
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• pp.1013-1019
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• 2011

In this paper, simulation works for a multi-stage cascade refrigeration cycle using propane, ethylene and methane as refrigerants have been performed for the liquefaction of natural gas using Peng-Robinson equation of state built-in PRO/II with PROVISION release 8.3. The natural gas feed compositions were supplied from Korea Gas Corporation and the flow rate was assumed to be 5.0 million tons per annual. Supply temperature for propane refrigerant was fixed as $-40^{\circ}C$, that for ethylene refrigerant as $-95^{\circ}C$, and that for methane refrigerant as $-155^{\circ}C$. For the multi-stage refrigeration cycle, three-stage refrigeration was assumed for propane refrigeration cycle, two-stage refrigeration for ethylene refrigeration cycle and three-stage refrigeration for methane refrigeration cycle. Natural gas was finally cooled and liquefied to $-162^{\circ}C$ by Joule-Thomson expansion. Conclusively, 91.71% by mole of the natural gas liquefaction ratio was obtained through a cascade refrigeration cycle and Joule-Thomson expansion and 0.433 kW of compression power was consumed for the liquefaction of 1.0 kg/hr of natural gas.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.10 no.11
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• pp.3253-3259
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• 2009

In this study, a computer simulation has been performed for the refrigeration cycle using mixed refrigerants in order to decrease the process stream temperature to $-20^{\circ}C$. Refrigerant supply temperature was assumed to be $-30^{\circ}C$ considering the temperature difference as $10^{\circ}C$ with process stream. Peng-Robinson equation of state model was selected for the computer simulation. A new alpha function proposed by Twu et al was used for an accurate prediction of pure component vapor pressure experimental data. One fluid mixing rules were used for the estimation of mixture vapor-liquid equilibria calculations. A commercial process simulator, PRO/II with PROVISION was utilized for the simulation of the overall refrigeration process. In order to minimize the compressor power consumption, we have optimized the two-stage compression system by varying the first stage compressor outlet pressure. Finally, we could obtain the minimum total power 755.7kW at the first stage compressor outlet pressure, 6 bar.