• Title/Summary/Keyword: Paste electrode

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A Study on Rheology Characteristics of Ag Paste for Screen Printing Method for Silicon Solar Cells Electrodes Capable of Forming High Aspect Ratio (고온 소결형 실리콘 태양 전지의 High Aspect Ratio 전극 형성이 가능한 Ag 페이스트의 레오로지 특성 연구)

  • Oh, Tae-Hun;Kim, Sung-Bin;Nam, Su-Yong
    • Journal of the Korean Graphic Arts Communication Society
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    • v.28 no.1
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    • pp.15-24
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    • 2010
  • Photovoltaic solar cells are all in the incident because they are not converted into electrical energy, high-efficiency solar cells in order to reduce the loss of elements must be. Significant factor in the loss of solar cells, optical loss and electrical loss can be divided into. Optical losses occur when the sun will be joined on the surface of the reflection, the shadow loss due to electrodes, and the losses are in the solar wavelengths. Commercialization is currently the most common solar cells on the front of the light incident on the electrode is formed. Therefore, the shadow caused by the electrode to cover the dead area of the sun, due to factors that hinder the absorption of sunlight which is shadowing them and conversion efficiency of solar cells is the inhibition factor. These barriers to eliminate the electrode linewidth reduces the shadowing to reduce, but simply of the electrode line width is reduced electrode area by reducing the series resistance elevates this because to improve the electrode Aspect ratio(height/width) to increase Ag development of paste is required. In this study, aspect ratio of screen-printing method to increase the electrode Ag paste composition of the binder for the characterization of rheology in the shadow of the electrode by reducing the optical loss of the photoelectric conversion efficiency of solar cells to boost the performance measures was. Properties and printability of the paste, the binder resin sintered characteristics that affect the thermal properties are excellent with a good screen printability acrylic resin, ethyl cellulose, using a resin were evaluated. Prepared paste rheology properties, was formed to evaluate the electrode conductivity and aspect ratio.

DSSCs Efficiencies of PEG Additive In TiO2 Paste (TiO2 Paste에 PEG 첨가에 따른 DSSC의 효율 특성)

  • Kwon, Sung-Yeol;Yang, Wook;Zhang, Zi-Heng
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.11
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    • pp.746-752
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    • 2014
  • Photo electrode is an important component of DSSC, so this paper did some research on it. Through the method of adding PEG additive into $TiO_2$ paste, the electrical characteristics and efficiencies of DSSCs with photo electrode surface area were studied. In the case of not adding PEG in $TiO_2$ paste, $26{\mu}m$ thickness $TiO_2$ photo electrode shows 5.081% efficiency. The highest short circuit current density was $10.476mA/cm2^$. The structure of porous $TiO_2$ film can be controlled through changing the PEG additive amount in $TiO_2$ paste and the molecular weight of PEG. When the additive amount of PEG 20,000 in $TiO_2$ paste reaches 5%, the peak efficiency with $26{\mu}m$ thickness $TiO_2$ photo electrode was 5.387% and its highest current density were $11.084mA/cm^2$.

Design of Electrode Structure for Reducing Ag Paste for Shingled PV Module Application (Shingled PV 모듈 적용을 위한 Ag Paste 저감 전극 구조 설계)

  • Oh, Won Je;Park, Ji Su;Lee, Jae Hyeong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.4
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    • pp.267-271
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    • 2019
  • A shingled PV module is manufactured by dividing and bonding. In this method, the solar cell is divided by lasers and bonded using electrically conductive adhesives (ECAs). Consequently, the manufacturing cost increases because a process step is added. Therefore, we aim to reduce the production cost by reducing the amount of Ag paste used in the solar cell front. Various electrode structures were designed and simulated. The number of fingers was optimized by designing thinner fingers, and the number of fingers with the maximum power conversion efficiency was confirmed. The simulation confirmed the maximum efficiency in the 4-divided electrode pattern. The amount of Ag paste used for each electrode pattern was calculated and analyzed. The number of fingers was optimized by decreasing the width of the finger; this will not only reduce the amount of Ag paste required but also the increase the efficiency.

Electrocatalytic Properties of Metal-dispersed Carbon Paste Electrodes for Reagentless L-lactate Biosensors (금속이 첨가된 탄소전극의 전기화학적 특성과 이를 이용한 L-lactate 바이오센서의 개발)

  • 윤현철;김학성
    • KSBB Journal
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    • v.11 no.4
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    • pp.489-496
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    • 1996
  • Metal dispersed carbon paste electrodes were fabricated, and their electrochemical properties were investigated. Among various metal dispersed carbons, platinum-dispersed carbon paste electrode showed most efficient electrocatalytic characteristics. The overpotential for the oxidation of NADH was significantly lowered in the platinum-dispersed carbon paste electrode, and catalytic current was also enhanced. Based on these electrocatalytic observations, L-lactate biosensor using L-lactate dehydrogenase was constructed to evaluate its performance in terms of sensitivity and stability.

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Electrochemical determination of hydrogen peroxide using carbon paste biosensor bound with butadiene rubber (부타디엔 고무로 결합된 탄소반죽 바이오센서를 이용한 과산화수소의 전기화학적 정량)

  • Yoon, Kil-Joong
    • Analytical Science and Technology
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    • v.23 no.5
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    • pp.505-510
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    • 2010
  • When polybutadiene dissolved in toluene was a binder of carbon powder, the volatility of solvent just after electrode fabrication assured the mechanical solidity of the carbon paste electrode. This characteristic met the qualifications for practical use of carbon paste electrodes. A new enzyme electrode bound with butadiene rubber was constructed. In order to confirm whether it shows quantitative electrochemical behaviors or not, its electrochemical kinetic parameters, e.g. the symmetry factor, the exchange current density, the capacitance of double layer, the time constant, the maximum current, the Michaelis constant and other factors were investigated. These experimental facts showed that butadiene rubber is a recommendable binder for practical use of a carbon paste electrode.

Voltammetric Determination of Cobalt(Ⅱ) Using Carbon Paste Electrodes Modified with 1-(2-Pyridylazo)-2-naphthol

  • 배준웅;박유철;이상학;전우성;장혜영
    • Bulletin of the Korean Chemical Society
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    • v.17 no.11
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    • pp.995-999
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    • 1996
  • A method for the determination of cobalt(Ⅱ) by differential pulse voltammetry using a carbon paste electrode constructed by incorporating 1-(2-pyridylazo)-2-naphthol(PAN) into a conventional carbon paste mixture composed of graphite powder and Nujol oil has been developed. Several influencing factors for the determination of cobalt(Ⅱ) were studied in detail and the optimum analytical conditions were found to be as follows: pH, 4.6; composition of electrode, 20%; temperature of deposition, 43 ℃; time of preconcentration, 15 min. Regeneration of the electrode surface for the continuous uses of the electrode was achieved by exposing the carbon paste electrode to an acidic solution. Response of the electrode was reproducible for the uses of five times and the relative standard deviations were 6.7 and 4.6% for 2.0×10-5 M and 4.0×10-6 M cobalt(Ⅱ), respectively. The calibration curve for cobalt(Ⅱ) obtained by differential pulse voltammetry was divided into two linear ranges of 1.7× 10-6-1.3×10-4 M and 2.0×10-7-8.0×10-7 M. The detection limit was estimated to be 1.3×10-7 M. The effects of coexisting ions were also investigated to test the applicability of the proposed method to the determination of cobalt(Ⅱ) in real samples.

A Study on the Composition of Silver Paste for Micro Nozzle Dispensing Method (미세노즐 토출에 적용 가능한 은 전극의 조성에 대한 연구)

  • Kim, Do-Hyung;Shin, Dong-Wook;Ryu, Sung-Soo;Chang, Hyo-Sik;Kim, Hyeong-Jun
    • New & Renewable Energy
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    • v.8 no.1
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    • pp.18-23
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    • 2012
  • The screen printing has been widely used to form silver electrodes in solar cell device due to their simplicity of process. However, the wavy and irregular surface which is believed to be originated from a screen mask mesh and thixotropic characteristics of paste on screen printing process is well-known to give a negative effect on solar cell efficiency. The dispensing method that the silver paste is extruded through micro nozzle under a moderate pressure and coated on substrate can form the silver electrode without any wavy surface. In this study, we optimize the composition of silver paste and develop paste blending condition based on the thixotropic behavior of paste. The optimized paste shows a large thixotropic loop area which is related to an aspect ratio of electrode line and has the viscosity of 40 $Pa{\cdot}s$ at 40 s-1. The electrode line we finally obtainis 67.2 ${\mu}m$ in width and has an aspect ratio of 0.277.

Development of Solvent-Free Type for UV-Curable Silver Paste (무용제 타입 UV경화형 실버 페이스트 개발)

  • Jang, Min Yong;Nam, Hyun Jin;Nam, Su Yong
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.2
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    • pp.107-112
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    • 2022
  • In this study, a silver paste capable of UV curing without using any solvent was developed. The viscosity and viscoelasticity of the silver paste developed as a solvent-free type were measured. And after printing the pattern by screen printing, an electrode coating film was formed by UV curing. Conductivity, pencil hardness, and adhesive force of the formed electrode coating film were evaluated. Finally, the curing characteristics of the electrode coating film were evaluated by TGA and FT-IR. Summarizing these results, in terms of conductivity, adhesion, and curing characteristics, it was found that Paste (4), that is, silver paste obtained by mixing 1.2 ㎛ spherical silver powder and 50 nm silver powder at 72:8% had the best physical properties.

Voltammetric Determination of Bisphenol A Using a Carbon Paste Electrode Based on the Enhancement Effect of Cetyltrimethylammonium Bromide (CTAB)

  • Huang, Wensheng
    • Bulletin of the Korean Chemical Society
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    • v.26 no.10
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    • pp.1560-1564
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    • 2005
  • The influence of cetyltrimethylammonium bromide (CTAB) on the electrochemical behavior of bisphenol A at the carbon paste electrode (CPE) was investigated. CTAB, with a hydrophobic C-H chain, can adsorb at the CPE surface via hydrophobic interaction and then change the electrode/solution interface, and finally affects the electrochemical response of bisphenol A, confirming from the remarkable oxidation peak current enhancement. The electrode process of bisphenol A was examined, and then all the experimental parameters which affects the electrochemical response of bisphenol A, such as pH value of the supporting electrolyte, accumulation potential and time, potential scan rate and the concentration of CTAB, were examined. Finally, a sensitive and simple voltammetric method was developed for the determination of bisphenol A. Under the optimum conditions, the oxidation peak current of bisphenol A varied linearly with its concentration over the range from $2.5\;{\times}\;10^{-8}\;to\;1\;{\times}\;10^{-6}$ mol/L, and the detection limit was found to be $7.5\;{\times}\;10^{-9}$ mol/L. This method was successfully employed to determine bisphenol A in some waste plastic samples.

Studies on Enhanced Oxidation of Estrone and Its Voltammetric Determination at Carbon Paste Electrode in the Presence of Cetyltrimethylammonium Bromide

  • Yang, Chunhai;Xie, Pingping
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1729-1734
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    • 2007
  • The electrochemical behaviors of estrone in the presence of various surfactants were examined with great details. It is found that a cationic surfactant, cetyltrimethylammonium bromide (CTAB), obviously facilitates the electro-oxidation of estrone at carbon paste electrode (CPE) from the significant peak current enhancement and the negative shift of peak potential. Additionally, chronocoulometry and electrochemical impedance spectroscopy (EIS) were also used for further investigation of the electrode process of estrone, indicating that low concentration of CTAB exhibits excellent enhancement effects on the electrochemical oxidation of estrone, greatly enhances the diffusion coefficient and the electron transfer rate. Based on this, an electrochemical method was proposed for the determination of estrone. The oxidation peak current is proportional to the concentration of estrone in the ranges over 9.0 × 10?8 - 8.0 × 10?6 mol/L, and a low detection limit of 4.0 × 10?8 mol/L was obtained for 180s accumulation at open circuit (S/N = 3). Finally, this proposed method was demonstrated using estrone tablets with good satisfaction.