Browse > Article
http://dx.doi.org/10.5806/AST.2010.23.5.505

Electrochemical determination of hydrogen peroxide using carbon paste biosensor bound with butadiene rubber  

Yoon, Kil-Joong (Department of Applied Chemistry, Cheongju University)
Publication Information
Analytical Science and Technology / v.23, no.5, 2010 , pp. 505-510 More about this Journal
Abstract
When polybutadiene dissolved in toluene was a binder of carbon powder, the volatility of solvent just after electrode fabrication assured the mechanical solidity of the carbon paste electrode. This characteristic met the qualifications for practical use of carbon paste electrodes. A new enzyme electrode bound with butadiene rubber was constructed. In order to confirm whether it shows quantitative electrochemical behaviors or not, its electrochemical kinetic parameters, e.g. the symmetry factor, the exchange current density, the capacitance of double layer, the time constant, the maximum current, the Michaelis constant and other factors were investigated. These experimental facts showed that butadiene rubber is a recommendable binder for practical use of a carbon paste electrode.
Keywords
carbon paste electrode; hydrogen peroxide; peroxidase; butadiene rubber;
Citations & Related Records
Times Cited By KSCI : 5  (Citation Analysis)
연도 인용수 순위
1 J. J. Roy, T. E. Abraham, K. S. Abijith, P. V. S. Kumar and M. S. Thakur, Biosensors & Bioelectronics 21, 206-211(2005).   DOI   ScienceOn
2 A. S. Miguel, M. Arben and A. Salvador, Sens. Acturator B 69, 153-163(2000).   DOI   ScienceOn
3 Y. C. Li, W. F. Bu, L. X. Wu and C. Q. Sun, Sens. Acturator B 107, 921-928 (2005).   DOI   ScienceOn
4 X. Chen, J. Z. Zhang, B. Q. Wang, G. C. Cheng and S. J. Dong, Anal. Chim. Acta 434, 255-260(2001).   DOI   ScienceOn
5 K. J. Yoon, K. J. Kim and H. S. Kwon, J. Kor. Chem. Soc. 43, 271-279(1999).
6 K. J. Yoon, Anal. Sci. Tech. 16, 504-508(2003).
7 K. J. Yoon, J. Kor. Chem. Soc. 48, 654-658(2004).   DOI   ScienceOn
8 K. J. Yoon, Bull. Kor. Chem. Soc. 25, 997-1002(2004).   DOI   ScienceOn
9 K. J. Yoon, Elastomer 42, 112-118(2007).
10 K. J. Yoon, Bull. Kor. Chem. Soc. 29, 2264-2266(2008).   DOI   ScienceOn
11 B. G. Lee, K B. Rhyu and K. J. Yoon, Bull. Kor. Chem. Soc. 30, 2457-2460(2009).   DOI   ScienceOn
12 J. A. Brydson, 'Rubbery Materials and Compounds', Elsevier Applied Science, London and New York, 124, 1988.
13 A. Mansouri, D. P. M. Makris and P. Kepalas, J. Pham. Biochem. Anal. 39, 22-26(2005).   DOI   ScienceOn
14 T. J. Cheng, T. M. Lin and H. C. Chang, Anal. Chim. Acta 462, 261-273(2002).   DOI   ScienceOn