• 제목/요약/키워드: Passive Film

검색결과 324건 처리시간 0.02초

Thin Film Magneto-Optic Materials

  • Kim, You-Song
    • 한국결정성장학회:학술대회논문집
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    • 한국결정성장학회 1997년도 Proceedings of the 12th KACG Technical Meeting and the 4th Korea-Japan EMGS (Electronic Materials Growth Symposium)
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    • pp.121-124
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    • 1997
  • Emergence of advanced materials has been realized by the great demands for sophisticated state devices in high technology industry. It is the ear of speedy evolution of science and technology, in particular, materials processing technology, which enables us to synthesize any materials with respect to its purity and its perfection of crystal structure and shape (form) that have, heretofore not been available. The availability of ultra pure, fine raw materials, single crystals and thick/thin film materials has been largely responsible for such startling progresses that have been made in the realization of unforeseen, functional devices for high technology industry. Of the functional devices such as passive as active devices, non-silicon devices are mostly passive. Piezoelectric, electro-optic, magneto-optic devices, etc. are some of the examples. In this paper, magneto-optic materials for Faraday device, which is little known, are reviewed including its processing toward practical applications.

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A comprehensive review of techniques for biofunctionalization of titanium

  • Hanawa, Takao
    • Journal of Periodontal and Implant Science
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    • 제41권6호
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    • pp.263-272
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    • 2011
  • A number of surface modification techniques using immobilization of biofunctional molecules of Titanium (Ti) for dental implants as well as surface properties of Ti and Ti alloys have been developed. The method using passive surface oxide film on titanium takes advantage of the fact that the surface film on Ti consists mainly of amorphous or low-crystalline and nonstoichiometric $TiO_2$. In another method, the reconstruction of passive films, calcium phosphate naturally forms on Ti and its alloys, which is characteristic of Ti. A third method uses the surface active hydroxyl group. The oxide surface immediately reacts with water molecules and hydroxyl groups are formed. The hydroxyl groups dissociate in aqueous solutions and show acidic and basic properties. Several additional methods are also possible, including surface modification techniques, immobilization of poly(ethylene glycol), and immobilization of biomolecules such as bone morphogenetic protein, peptide, collagen, hydrogel, and gelatin.

고분자 전해질 연료전지용 분리판으로서 스테인리스강에 HVOF 용사된 AISI316-WC 코팅층 (HVOF Thermal Sprayed AISI316-WC Coating Layer on Stainless Steel for PEMFC Bipolar Plate)

  • 남대근
    • 신재생에너지
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    • 제4권1호
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    • pp.31-36
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    • 2008
  • Stainless steels have been widely considered as metallic bipolar plates, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the bipolar plates and the electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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PCCS Analysis Model for the Passively Cooled Steel Containment

  • Hwang, Y.D.;Chung, B.D.;Cho, B.H.;Chang, M.H.;Jeong, Ik
    • Nuclear Engineering and Technology
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    • 제30권1호
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    • pp.26-39
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    • 1998
  • The containment pressure and temperature transient analysis computer code CONTEMPT4/MOD5 is modified to incorporate the passive containment cooling models. The correlations are selected from the existing experimental heat transfer correlations to model the natural and mixed convection in annular space between the containment shell and the shield building. The evaporative heat transfer of the water film on the outer shell of the containment is modeled using the correlations derived from the analogy between the heat and mass transfer. The modified code is applied to the Ap600 containment transient analysis for the model verification and the results are compared to the results of GOTHIC calculation done by Westinghouse. Also, d series of parametric sensitivity studies of heat transfer correlations, water film ratio and delay time of the wet cooling on the containment peak pressure and temperature following LOCA are performed for the containment of 1000MWe passive plant, KP1000.

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Electrochemical Analysis on Flow-Accelerated Corrosion Behavior of SA106 Gr.C Steel in Alkaline Solution

  • Kim, Jun Hwan;Kim, In Sup;Chung, Han Sub
    • Corrosion Science and Technology
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    • 제2권1호
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    • pp.41-46
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    • 2003
  • Flow-Accelerated Corrosion behavior concerning both activation and mass transfer process of SA106 Gr.C steel was studied using rotating cylinder electrode in room temperature alkaline solution by DC and AC electrochemical techniques. Passive film was tanned from pH 9.8 by step oxidation of ferrous product into hydroxyl compound. Corrosion potential shifted slightly upward with rotating velocity through the diffusion of cathodic species. Corrosion current density increased with rotating velocity in pH 6.98, while it soon saturated from 1000 rpm at above pH 9.8. On the other hand the limiting current increased with rotating speed regardless of pH values. It seems that activation process, which represents formation of passive film on the bare metal surface, controls the entire corrosion kinetics

고분자 전해질 연료전지용 스테인리스강 분리판의 HVOF AISI316-WC 코팅층 특성 (Characteristic of HVOF AISI316-WC Coating Layer on Stainless Steel Separator for PEMFC)

  • 남대근;강남현;박영도;김영석
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 추계학술대회 논문집
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    • pp.1-5
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    • 2008
  • Stainless steels have been widely considered as metallic separators, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the separators and electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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Development of Metallic Bipolar Plate Material with W-addition in Austenitic Stainless Steel for PEMFC Environment

  • Kim, Kwang Min;Koh, Sung Ung;Kim, Kyoo Young
    • Corrosion Science and Technology
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    • 제5권5호
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    • pp.153-159
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    • 2006
  • Austenitic stainless steels with addition of various amounts of Mo and W were evaluated in terms of corrosion and contact resistance to determine optimum alloy composition of metallic bipolar plate for PEMFC. The corrosion property was evaluated by both acid fume exposure test at $130^{\circ}C$ and by electrochemical polarization tests in $H_3PO_4$ solution at $80^{\circ}C$. Austenitic stainless steel with proper amount of Mo and W demonstrated not only good corrosion resistance but also low contact resistance. Analyses on the passive film show that partial substitution of Mo by W enhances passive film stability and repassivation property. Test results suggest that austenitic stainless steel with 2 wt%Mo and 4 wt%W has optimum composition for metallic bipolar plate used in PEMFC.

EIS를 이용한 염해에 노출된 철근콘크리트의 부식개시 측정에 관한 실험적 연구 (An Experimental Study on Measurement of Corrosion Initiation in Reinforced Concrete Exposed to Chloride Using EIS Method)

  • 박동진;박장현;이광수;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 추계 학술논문 발표대회
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    • pp.61-62
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    • 2017
  • In this study, the initiation of steel corrosion was monitored due to chloride attack using embedded sensor. In general, Steel bars embedded in concrete are protected from corrosion by being forming a passive film on the surface. However, the passive film is destroyed by chemical erosion such as concrete carbonation and chloride penetration, and the rebar is exposed to the deteriorating factor and corrosion proceeds. In order to realize the initiation of steel corrosion, OCP and change of Impedance parameter were observed by using Half-cell and EIS method depending on cover depth. As result, 10mm cover showed the impedence increased in 6weeks.

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FeCrMnN 계 스테인리스강의 일반부식 및 공식부식 거동에 미치는 고용 탄소의 영향 (Effects of Alloyed Carbon on the General Corrosion and the Pitting Corrosion Behavior of FeCrMnN Stainless Steels)

  • 하헌영;이태호;김성준
    • 대한금속재료학회지
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    • 제49권10호
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    • pp.780-789
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    • 2011
  • The effects of alloyed carbon on the pitting corrosion, the general corrosion, and the passivity behavior of Fe18Cr10Mn0.4NxC (x=0~0.38 wt%) alloys were investigated by various electrochemical methods and XPS analysis. The alloyed carbon increased the general corrosion resistance of the FeCrMnN matrix. Carbon enhanced the corrosion potential, reduced the metal dissolution rate, and accelerated the hydrogen evolution reaction rate in various acidic solutions. In addition, carbon promoted the pitting corrosion resistance of the matrix in a chloride solution. The alloyed carbon in the matrix increased the chromium content in the passive film, and thus the passive film became more protective.

Effects of Corrosion Inhibitor on Corrosion of Al-based Alloys in Ethylene Glycol-Water Coolant Environment

  • Gwang-Soo Choi;Young-Man Kim;Chan-Jin Park
    • Corrosion Science and Technology
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    • 제22권5호
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    • pp.305-313
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    • 2023
  • The objective of this study was to investigate the effectiveness of sodium dodecyl benzene sulfonate (SDBS) as a corrosion inhibitor on the pitting corrosion behavior of aluminum alloys used in electric vehicle battery cooling systems within a mixture of ethylene glycol and water (EG-W) coolant. Potentiodynamic polarization testing revealed unstable passive film formation on the aluminum alloys in the absence of SDBS. However, the addition of SDBS resulted in a robust passive film, enhancing the pitting corrosion resistance across all examined alloys. Pitting corrosion was predominantly observed near intermetallic compounds in the presence of Cl? ions, which was attributed to galvanic interactions. Among tested alloys, A1040 demonstrated superior resistance due to its lower areal fraction of precipitates and donor density. The incorporation of SDBS inhibitors mitigated the overall pitting corrosion process by hindering Cl? ion penetration. These findings suggest that SDBS can significantly improve pitting corrosion resistance in aluminum alloys employed in battery coolant environments.