• Title/Summary/Keyword: Particle-In-Binder

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Property and Polymerization of Hi-solid PSA's using Seeded Polymerization (Seed 중합을 이용한 고고형분 수용성 점착제의 합성과 물성)

  • Jung, Young Sik;Min, Seong-Kee;Seul, Soo Duk
    • Journal of Adhesion and Interface
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    • v.10 no.4
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    • pp.174-181
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    • 2009
  • The viscosity for hi-solid pressure sensitive adhesive to improve water soluble low viscosity pressure sensitive adhesive polymerized using seeded polymerization. While seed binder polymerizing it produces an optimum polymerization condition, and acrylic acid and seed binder concentration changed were measurement of viscosity variation and adhesive power at the substrate (SUS420J) as flowing results. In adhesive polymerization, seed binder concentration 7 wt%/monomer was recovered 60% of solid content, 2,100 cps of low viscosity and clear adhesive film. When acrylic acid content was 4 wt%/monomer, it was turned excellent adhesive power and holding power.

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Manufacture of Core-Shell Composite Polymer Materials for Nonwoven binder (부직포 바인더용 Core-Shell 복합소재의 제조)

  • Lee, Sun Ryong;Lim, Jae Keel;Seul, Soo Duk
    • Journal of Adhesion and Interface
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    • v.3 no.4
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    • pp.27-36
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    • 2002
  • The organic/organic core-shell composite polymer for nonwomen binder were synthesized by stage polymerization of methyl methacrylate and styrene with ammonium persulfate after preparing monomer pre-emulsion in the presence of anionic surfactant. We study the effect of initiator concentration, $0.79{\times}10^{-3}{\sim}3.16{\times}10^{-3}mol/L$ for core polymer, $2.0{\times}10^{-4}{\sim}8.0{\times}10^{-4}mol/L$ for shell polymer, sulfactant concentration, $1.45{\times}10^{-5}{\sim}4.15{\times}10^{-5}mol/L$ for core polymer, $0.73{\times}10^{-5}{\sim}2.91{\times}10^{-5}mol/L$ for shell polymer on core-shell structure of polymethyl methacrylate/polystyrene and polystyrene/polymethyl methacrylate. Emulsion stability was major test method, particle size and particle size distribution were measured using particle size analyzer and the morphology of the core-shell composite polymer was determined using transmission electron microscope, glass temperature was also measured using differential scanning calorimeter.

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Manufacture of Alkyl Acrylate Multi Core-shell Composite Particle (알킬 아크릴레이트계의 다중 Core-shell 복합입자의 제조)

  • Cho, Dae-Hoon;Choi, Sung-Il;Go, Hyun-Mi;Seul, Soo-Duk
    • Journal of Adhesion and Interface
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    • v.12 no.1
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    • pp.16-25
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    • 2011
  • Multi core-shell composite particles were prepared by the water-born emulsion polymerization of various core monomer such as methyl methacrylate (MMA), n-butyl methacrylate (BMA), and shell monomer such as MMA, BMA, stylene (St), 2-hydroxyl ethyl methacrylate (2-HEMA) and acrylic acid (AA) in the presence of different concentration of sodium dodecyl benzene sulfonate (SDBS). The following conclusions are drawn from the measured conversion, particle size and distribution, average molecular weight, molecular structure, glass transition temperature with DSC, morphology, tensile strength and elongation. In the case of the concentration of 0.02 wt% SDBS, the conversion of MMA core-(BMA/St/AA) shell composite particle was excellent as 98%. In the case of the concentration of 0.03 wt% SDBS, the particle size of BMA core-(MMA/St/AA) shell composite particle was high as $0.47{\mu}m$. We confirmed that 3 points of glass transition temperatures appear for multi core-shell composite particles compared to 2 points of glass transition temperatures appear for general core-shell composite particles. We showed that it is possible to adjust glass transition temperatures according to the kind and composition of the inner shell monomer that it is can be used as a adhesive binder material with improved adhesive power.

Characterization of Asphalt Pavement Distress Using Korean Pavement Research Program (한국형포장설계법을 이용한 아스팔트포장의 파손특성)

  • Lee, Kwan-Ho;Lee, Kyung-Suk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.4
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    • pp.487-493
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    • 2017
  • The main purpose of this study is to evaluate the main parameters involved in the asphalt pavement distresses, including IRI (International Rough Index), fatigue, and permanent deformation. The main parameters are the region (Seoul and Busan), traffic level, asphalt binder, maximum aggregate of surface course, thickness of the surface course and base. A total of 64 case studies were carried out under the auspices of the KPRP (Korea Pavement Research Program). From the analysis of the KPRP test results, the key factors for the asphalt pavement distress were determined. Considering the effect of one variable in the basic condition, asphalt binder was the major factor having an effect on the distresses for an AADT (Annual Average Daily Traffic) of 5000 in the Seoul area. Among the remaining factors, the results were found to be in the order of the base layer thickness (A), surface layer thickness (B), and aggregate particle size thickness (D). The same results were obtained for an AADT of 10000. In the case of Busan with an AADT of 5000, the same result was obtained as for Seoul. Among the remaining factors, the results were in the order of the base layer thickness (A), aggregate particle thickness (D), and surface layer thickness (B). Even though there was a slight difference in the effect of the traffic level and region, asphalt binder was the parameter having the greatest effect on the asphalt pavement distress. In the case where the effect of multiple parameters was analyzed, the combination of the asphalt binder and base thickness showed a relatively strong effect.

Effect of Latex Particle Size, Base Paper Grammage and Coating Color Concentration on Printing Quality of Coated Paper (Latex 입경과 원지 평량 및 칼라농도가 도공지의 인쇄품질에 미치는 영향)

  • Lee, Y.K.;Yoo, S.J.;Cho, B.U.;Kim, Y.S.;Nam, B.K.;Choi, S.M.
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.4
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    • pp.29-37
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    • 2007
  • The effects of latex particle size, basis weight of base paper and coating color concentration on the printing quality of coated paper were investigated. Coating colors were prepared with five types of latexes having different particle sizes. Coated papers were produced with high solid coating colors and with low solid coating colors in a industrial coater, respectively. In high solid coating colors, rheology modifier was used and GCC content was high. It was concluded that, in order to control binder migration and hence print mottle, latex particle sizes shall be controlled as well as formation, sizing degree and roughness of basis paper.

Effect of Variation in Particle Size of WC and Co Powder on the Properties of WC-Co Alloys (WC와 Co원료 입자크기 변화에 따른 WC-Co계 초경합금의 특성 변화)

  • Chung, Tai-Joo;Ahn, Sun-Yong;Paek, Yeong-Kyeun
    • Journal of the Korean Ceramic Society
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    • v.42 no.3 s.274
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    • pp.171-177
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    • 2005
  • The effect of variation in particle size of WC and Co powder on the properties of WC-Co alloys was investigated. WC and Co powders having different particle sizes were used in the fabrication of $WC-10\;wt\%$Co composites. High hardness and low fracture toughness alloy was obtained with the decrease in WC particle size regardless of Co particle size. It was newly found in this investigation that the initial particle size of Co as well as WC had a great role in the microstructure and properties of WC-Co hard materials. The average grain size and fracture toughness of WC-Co alloys using same WC powder size increased and their hardness decreased with the use of relatively finer Co binder.

Fabrication and Piezoelectric Strain Characteristics of PLZT Functionally Gradient Piezoelectric Actuator by Doctor Blade Process (닥터블레이드법에 의한 PLZT계 경사기능 압전 엑튜에이터의 제조와 압전 변위 특성)

  • 김한수;최승철;이전국;정형진
    • Journal of the Korean Ceramic Society
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    • v.29 no.9
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    • pp.695-704
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    • 1992
  • In (Pb, La)(Zr, Ti)O3 ceramic system, the functionally gradient material (FGM) was developed, and its processing and properties were investigated. The FGMs were successfully prepared through doctor blade method with acrylic binder system as well as mold stacking press method. The ultrasonic treatment was very effective for particle dispersion in slurry, and it lead to form clack-free green films. The strain-voltage characteristics of the FGM system was significantly improved which fabricated between a high piezoelectric-low dielectric and a low piezoelectric-high dielectric composition layer.

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Effect of Polymer on the Photosensitive properties of organic Photoconductor (유기감광체의 감광특성에 미치는 고분자의 영향에 관한 연구)

  • 문명준;김명숙;이상남;민성기;김은경
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.43-60
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    • 1998
  • The photosensitive properties and spectroscopic characteristics in the organic photoconductor(OPC) with carrier generation layer(CGL) of poly(vinylbutyral)(PVB) and polycarbonate(PC) doped with titanyl phthalocyanine(TiOPc) were investigated. The change of crystal structure of TiOPc dispersed with PVB and PC was shown by UV-visible reflective spectrum and FT-IR spectrum and mainly caused by the difference of solubility of solvent and the interaction between TiOPc and binder. The particle size of TiOPc dispersed with PVB measured by SEM was smaller than in PC. The crystal structure of TiOPc dispersed with PVB was amorphous type and in PC was $\alpha$type. It was found that the photosensitive properties of OPC were dependent on the change of absorbance and ionization potential of TiOPc occurred from the difference of crystal structure. In this work, the photosensitivity of OPC of TiOPc dispersed with PVB was better than PC due to the crystal type and the smaller particle size.

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Thermal Debinding Behavior of PIM Components Produced with Different Powder Sizes and Shapes

  • Shu, Guo-Jiun;Hwang, Kuen-Shyang
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.219-220
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    • 2006
  • To understand the effect of powder characteristics on the thermal debinding behavior, PIM parts produced with powders with different particle sizes and particle shapes were examined to determine their weight losses during thermal debinding. The results show that the average diameter of the pore channel in the compact increased when the temperature increased and when coarse powders were used. However, the weight loss rates did not increase proportionally with the pore size. This suggests that the different powders that are frequently used in PIM parts do not affect the thermal debinding rate significantly. This is because the pore size is much larger than the mean free path of the decomposed gas molecules. Thus, the diffusion rates of the gases are not rate-controlling in thermal debinding. The controlling mechanism of the thermal debinding rate is the decomposition of the backbone binder in the PIM parts.

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Application of Ferronickel Slag Aggregate to Improve Workability and Strength of Non-Sintered Cement Mortar (비소성 시멘트 모르타르의 작업성 및 강도 개선을 위한 페로니켈슬래그 골재의 적용방안)

  • Jang, Kyung-Soo;Na, Hyeong-Won;Hyung, Won-Gil
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.309-310
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    • 2023
  • Slag and ash generally have a higher powder degree than portland cement, so workability may deteriorate under the same unit quantity condition, and strength and durability decrease when the unit quantity is increased. At this time, if an aggregate having a low water absorption and an appropriate particle size is used to recover the loss of strength, it can contribute to reducing the unit quantity of the binder. Therefore, for the purpose of improving the workability and strength of non-sintered cement mortar using slag and ash, ferro nikel slag whose particle size was adjusted was used as an aggregate and its applicability was identified. In this experimental condition, it was confirmed that non-sintered cement mortar tends to improve workability and secure strength when ferro nikel slag having various particle size distributions is used as an aggregate. This can be analyzed as the effect of ferro nikel slag material properties including glassy properties and mixing conditions with a wide particle size distribution.

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