• Transactions of the Korean hydrogen and new energy society
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• v.24 no.2
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• pp.150-159
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• 2013

To enhance the performance of SEWGS system by holding the WGS catalyst in a SEWGS reactor using bed inserts, effects of insert geometry and shape of WGS catalysts on CO conversion were measured and investigated. Small scale fluidized bed reactor was used as experimental apparatus and WGS catalyst (particle and tablet) and sand were used as bed materials. The parallel wall type and cross type bed inserts were used to hold the WGS catalysts. The CO conversion with steam/CO ratio was determined based on the exit gas analysis. The measured CO conversion using the bed inserts showed high value comparable to physical mixing cases. Moreover, gas flow direction was confirmed by bed pressure drop measurement for each case. Most of input gas flowed through the catalyst side when we charged tablet type catalyst into the bed insert and this can cause low $CO_2$ capture efficiency because the possibility of contact between input gas and $CO_2$ absorbent is low in this case. New bed insert geometry was proposed based on the results from this study to enhance contact between input gas and WGS catalyst and $CO_2$ absorbent.

• Journal of the Microelectronics and Packaging Society
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• v.28 no.2
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• pp.51-57
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• 2021

This paper analyzed the effects of the concentration of nano-silica particles contained in epoxy resin on the thermomechanical properties of the composite materials. The 12nm sized nanoparticles were mixed with epoxy polymer by 5 different weight ratios for the test samples. The glass transition temperature, stress relaxation, and thermal expansion behaviors were measured using dymanic mechanical analyzer (DMA) and thermomechanical analyzer (TMA). It was shown that the nano particle mixing ratios had significant influences on the viscoelastic behaviors of the materials. As the content of the silica particles was increased, the elastic modulus was also increased, while the glass transition temperatures were decreased. Fourier Transform Infrared Spectroscopy (FTIR) results played an important role in determining the causes of the property changes by the filler contents in terms of the molecular structures, enabling the interpretations on the material behaviors based on the chemical structure changes.

• Journal of the Korea Convergence Society
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• v.12 no.6
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• pp.33-38
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• 2021

In order to manufacture a lightweight medical radiation shielding sheet, a new shielding material was studied. We tried to verify the possibility of a shielding material by mixing egg shell powder, which is thrown away as food waste at home, with a polymer material. Existing lightweight materials satisfy eco-friendly conditions, but there are difficulties in the economics of shielding materials due to the cost of the material refining process. This study aims to solve this problem by using egg shells, which are household waste. A 3 mm-thick shielding sheet was fabricated using HDPE, a polymer material, and particle distribution within the cross-section of the shielding sheet was also verified. The shape of the particles was rough and there were voids between the particles, and the average weight per unit area was 1.5 g/cm². The shielding performance was around 20% in the low energy area and 10% in the high energy area, showing the possibility of a low-dose medical radiation shielding body.

• Tribology and Lubricants
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• v.38 no.3
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• pp.101-108
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• 2022

The structure and properties of tetrahedral amorphous carbon (ta-C) coatings depend on the main process parameters and bending angles of the magnetic field filter used in the filtered cathodic vacuum arc (FCVA). During the process, it is possible to effectively control the plasma flux of carbon ions incident on the substrate by controlling the arc discharge current, thereby influencing the mechanical properties of the coating film. Furthermore, we can control the size and amount of large particles mixed during carbon film formation while conforming with the bending angle of the mechanical filter mounted on the FCVA; therefore, it also influences the mechanical properties. In this study, we consider tribological characteristics for filtered bending angles of 45° and 90° as a function of arc discharge currents of 60 and 100 A, respectively. Experiment results indicate that the frictional behavior of the ta-C coating film is independent of the bending angle of the filter. However, its sliding wear behavior significantly changes according to the bending angle of the FCVA filter, unlike the effect of the discharge current. Further, upon changing the bending angle from 45° to 90°, abrasive wear gets accelerated, thereby changing the size and mixing amount of macro particles inside the coating film.

• Journal of the Korean Applied Science and Technology
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• v.39 no.5
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• pp.623-631
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• 2022

Using the design of experiment (DOE), factors affecting the particle size of hydrated liquid crystalline vesicles containing a high content of ceramide were analyzed and the mixture composition was optimized. Manufacturing temperature, amount of ethanol, and ultrasonic time were selected as the main variables affecting the droplet size of the vesicles, and the effect of these variables on the droplet size was examined through the signal to noise (S/N) ratios of Taguchi method and ANOVA analysis. In addition, mixture composition experiments of three lipid components constituting the vesicle membrane, hydrogenated phosphatidyl choline (HPC), cholesterol (Chol), and ceramide (Cer), were performed according to the simplex central design matrix of the mixture. Regression analysis was conducted with the experimental data to obtain a model equation, and the optimal mixing composition of the three lipid components to minimize the vesicle droplet size was determined as HPC (0.6), Chol (0.1), and Cer (0.3).

• Journal of Conservation Science
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• v.38 no.1
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• pp.45-54
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• 2022

This study examined the production technique of bracket murals in Daeungjeon Hall, Gaeamsa Temple by conducting a analysis of their wall structure, material characteristics, and painting layers. Wall was a single-branch structure with support layer, middle layer, finishing layer, and painting layer. The support layer, middle layer and finishing layer, were produced by mixing sand (quartz, feldspars etc.), and loess. The ratio of above medium sand to below fine sand was approximately 0.7 : 9.3 in the support layer, 4 : 6 in the middle layer and 6 : 4 in the finishing layer, which had a more percentage of above medium sand than the support layer. The analysis of the painting layer showed that natural soil pigment was used to establish a relatively ground layer of up to 50 ㎛, and pigments such as Lead sulfate, atacamite and mercury sulfide were painted on top of the layer. This study's results confirmed that the bracket mural paintings in Gaeamsa Temple are within the category of the production style of murals during the Joseon period. However, the points that the middle layer was formed several times, the significant difference in particle size distribution between the wall, and the absence of chopped straw in the support layer are a feature of bracket mural paintings in Gaeamsa Temple. These properties of murals as material and structure may be viewed for correlation with the degree of damage to wall structure of mural painting and would serve as an important reference to diagnosis the conservation conditions of murals or prepare conservation treatments.

• Journal of the Korean Electrochemical Society
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• v.25 no.1
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• pp.32-41
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• 2022

Various steps in the electrode production process, such as slurry mixing, slurry coating, drying, and calendaring, directly affect the quality and, consequently, mechanical properties and electrochemical performance of electrodes. Herein, a new method of slurry coating is developed: Double-coated electrode. Contrary to single-coated electrode, the cathode is prepared by double coating, wherein each coat is of half the total loading mass of the single-coated electrode. Each coat is dried and calendared. It is found that the double-coated electrode possesses more uniform pore distribution and higher electrode density and allows lesser extent of particle segregation than the single-coated electrode. Consequently, the double-coated electrode exhibits higher adhesion strength (74.7 N m^-1) than the single-coated electrode (57.8 N m^-1). Moreover, the double-coated electrode exhibits lower electric resistance (0.152 Ω cm^-2) than the single-coated electrode (0.177 Ω cm^-2). Compared to the single-coated electrode, the double-coated electrode displays higher electrochemical performance by exhibiting better rate capability, especially at higher C rates, and higher long-term cycling performance. Despite its simplicity, the proposed method allows effective electrode preparation by facilitating high electrochemical performance and is applicable for the large-scale production of high-energy-density electrodes.

• Journal of Powder Materials
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• v.29 no.1
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• pp.34-40
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• 2022

Recently, high-entropy carbides have attracted considerable attention owing to their excellent physical and chemical properties such as high hardness, fracture toughness, and conductivity. However, as an emerging class of novel materials, the synthesis methods, performance, and applications of high-entropy carbides have ample scope for further development. In this study, equiatomic (Hf-Ti-Ta-Zr-Nb)C high-entropy carbide powders have been prepared by an ultrahigh-energy ball-milling (UHEBM) process with different milling times (1, 5, 15, 30, and 60 min). Further, their refinement behavior and high-entropy synthesis potential have been investigated. With an increase in the milling time, the particle size rapidly reduces (under sub-micrometer size) and homogeneous mixing of the prepared powder is observed. The distortions in the crystal lattice, which occur as a result of the refinement process and the multicomponent effect, are found to improve the sintering, thereby notably enhancing the formation of a single-phase solid solution (high-entropy). Herein, we present a procedure for the bulk synthesis of highly pure, dense, and uniform FCC single-phase (Fm3m crystal structure) (Hf-Ti-Ta-Zr-Nb)C high-entropy carbide using a milling time of 60 min and a sintering temperature of 1,600℃.

• Advances in materials Research
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• v.11 no.3
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• pp.225-235
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• 2022

It includes the synthesis of pristine ZnO nanoparticles and a series of Ag-doped zinc oxide nanoparticles was carried out by reflux method by varying the amount of silver (1, 3, 5, 7 and 9% by mol.). The morphology of these nanoparticles was investigated by SEM, XRD and FT-IR techniques. These techniques show that synthesized particles are homogenous spherical nanoparticles having an average particle size of about 50-100 nm along with some agglomeration. The photocatalytic activity of the ZnO nanoparticles and Ag doped ZnO nanoparticles were investigated via photodegradation of methylene blue (MB) as a standard dye. The data from the photocatalytic activity of these nanoparticles show that 7% Ag-doped ZnO nanoparticles exhibit much enhanced photocatalytic activity as compared to pristine ZnO nanoparticles and other percentages of Ag-doped ZnO nanoparticles. Furthermore, 7% Ag-doped ZnO was made composites with sulfur-doped graphitic carbon nitride by physical mixing method and a series of nanocomposites were made (3.5, 7.5, 25, 50, 75% by weight). It was observed that the 25% composites exhibited better photocatalytic performance than pristine S-g-C 3 N 4 and pure 7% Ag-doped ZnO. Tauc's plot also supports the photodegradation results.

• Proceedings of the Korea Water Resources Association Conference
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• 2021.06a
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• pp.20-20
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• 2021

하천에서 유해화학물질 유출사고로 인하여 오염물질이 유입되었을 경우, 이에 대응하기 위하여 오염운의 도달시간과 농도를 예측하는 것은 매우 중요하다. 종방향의 혼합거동이 중요한 넓은 범위의 하천을 대상으로 오염물질의 이송을 예측하기 위하여 일반적으로 1차원 Fickian 모형을 사용한다. 그러나 실제 하천에서 오염물질의 농도를 측정하였을 경우, 대부분의 농도분포는 오염물질의 저장대효과로 인하여 긴 tail 부분을 갖는 왜곡된 분포를 갖게 된다. 이러한 저장대 효과는 여러 하천내의 다양한 불규칙성으로부터 발생하나, 국내 하천에 많은 보가 설치되어 있음에도 불구하고 하천 내부에 설치된 수리구조물에 의하여 발생하는 인공적인 저장대 효과에 관한 연구가 미흡한 실정이다. 따라서 본 연구에서는 실내 수리실험과 수치 모의를 통하여 노치가 존재하는 보주변에서의 흐름 특성과 오염 물질의 이송 특성을 규명하고, 이를 통해 보의 지형 및 수리적 인자가 저장대 메커니즘에 미치는 영향을 분석하였다. 수리 실험을 통한 넓은 범위에서의 수평방향 흐름장과 농도장을 측정하기 위하여 본 연구에서는 광역 계측방법인 Large Scale Particle-Image-Velocimetry (LSPIV) 기법과 Planar-Concentration-Analysis (PCA) 기법을 각각 유속과 농도 측정을 위해 적용하였다. 더 많은 보의 지형 및 수리적 조건에 따른 저장대 메커니즘을 분석하기 위하여 3차원 Reynolds-averaged Navier-Stokes (RANS) 모형을 통해 모의조건을 확장 적용하였다. 측정 및 모의 결과를 바탕으로 노치가 존재하는 보의 지형 및 수리적 인자가 저장대 메커니즘에 미치는 영향을 분석하였다. 저장대 영역 면적의 크기는 노치사이의 간격이 증가할수록 증가하였으며 노치의 높이의 경우에는 크게 민감하지 않은 경향을 나타냈다. 추적물질의 체류 시간은 노치사이의 간격과 보의 높이가 증가할수록, 유량이 감소할수록 증가하여 질량교환계수 값이 감소하는 경향을 나타냈다. 프루드 수와 레이놀드 수 모두 질량교환계수와 양의 상관 관계를 나타냈으나 저장대 영역의 면적의 크기와는 낮은 관계성을 나타냈다.