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Investigation on Reaction Products From Oxidative Coupling Reactions of 1-Naphthol By Manganese Oxide (망간산화물에 의한 1-Naphthol의 산화-결합 반응에 따른 반응산물 연구)

  • Lim, Dong-Min;Lee, Doo-Hee;Kang, Ki-Hoon;Shin, Hyun-Snag
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.9
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    • pp.989-996
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    • 2007
  • In this study, abiotic transformation of 1-naphthol(1-NP) via oxidative-coupling reaction and its reaction products were investigated in the presence of Mn oxides. The reaction products were characterized for their relative polarity using solvent extraction experiment and reverse-phase HPLC, and for structure using CCMS and LC/MS, and for absorption characteristics using UV-Vis spectrometry. The reaction products present in aqueous phase were more polar than parent naphthol and comprised of 1,4-naphthoquinon(1,4-NPQ) and oligomers such as dimers and trimers. Hydrophilic component present in water phase after solvent$(CH_2Cl_2)$ extractions was identified as naphthol polymerized products having molecular weight(m/z) ranging from 400 to 2,000, and showed similar UV-Vis. absorption characteristics to that of foil fulvic acid. Transformation of 1,4-NPQ, which is non-reactive to Mn oxide, to the polymerized products via cross-coupling reaction in the presence of 1-NP was also verified. In this experimental conditions(20.5 mg/L, 1-NP, 2.5 g/L $MnO_2$, pH 5), the transformation of 1-NP into the oligomers and polymerized products were about 83% of initial 1-NP concentrations, and more than 30% of the reaction products was estimated to be water insoluble fractions, not extracted by $H_2O$ methanol. Results from this study suggest that Mn oxide-mediated treatment of naphthol contaminated soils can achieve risk reduction through the formation of oligomers md polymer precipitation.

Effects of Root Diameter and Peeling Methods on Drying Time and Paeoniflorin Content of Paeonia Lactiflora Pallas (작약(芍藥)의 뿌리굵기와 각피(刻皮)정도가 건조시간 및 품질에 미치는 영향)

  • Kim, Ki-Jae;Park, Chun-Hong;You, Oh-Jong;Shin, Jong-Hee;Park, So-Deuk;Choi, Boo-Sull
    • Korean Journal of Medicinal Crop Science
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    • v.6 no.1
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    • pp.38-43
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    • 1998
  • This experiment was carried out to gather basic information for improvement of peeling methods in peony (Paeonia lactiflora) roots which have been used for medicinal resources in Korea. Drying time required was shortened in thin root. Optimum drying time after machine peeling appeared to be 20 hrs in 5 to 10mm of root diameter, 39 hrs in 10 to 15mm, 48 hrs in 15 to 20mm, 56 hrs in more than 20mm, but those of unpeeled roots took 11 hrs in 5mm of root diameter and 4 hrs in exposed parent material. Paeoniflorin content in dried roots after peeling was lower than that of unpeeled root. Paeoniflorin content in root below 5mm in diameter was highest (6.15 %) and that was decreased in the increased root diameter up to 20mm, but it was slightly increased in root greater than 20mm in diameter.

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Mechanical Properties of Precious Metal-Ceramic Alloy Joined by the Laser-Welding and the Soldering Method (레이저 용접과 납착법으로 연결된 귀금속성 금속-도재 합금의 물리적 성질)

  • Oh, Jung-Ran;Lee, Seok-Hyung;Woo, Yi-Hyung
    • Journal of Dental Rehabilitation and Applied Science
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    • v.19 no.4
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    • pp.269-279
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    • 2003
  • This study investigated the mechanical properties of precious metal-ceramic alloy joined by the laser-welding and the soldering compared with the parent metal. Twenty-four tensile specimens were cast in precious metal-ceramic alloy and divided into three groups of eight. All specimens in the control group(group 1) were left in the as-cast condition. Group 2 and 3 were the test specimens, which were sectioned at the center. Eight of sectioned specimens were joined by soldering with a propane-oxygen torch, and the remaining specimens were joined by laser-welding. After joining, each joint diameter was measured, and then tested to tensile failure on an Instron machine. Failure loads were recorded, and then fracture stress(ultimate tensile strength), 0.2% yield strength and % elongation calculated. These data for three groups were subjected to a one-way analysis of variance(ANOVA). Neuman-Keuls post hoc test was then used to determine any significant differences between groups. The fracture locations, fracture surfaces were examined by SEM(scanning electron microscope). The results were as follows: 1) The tensile strength and 0.2% yield strength of the soldered group($280.28{\pm}49.35MPa$, $160.24{\pm}26.67MPa$) were significantly less than both the as-cast group($410.99{\pm}13.07MPa$, $217.82{\pm}17.99MPa$) and the laser-welded group($383.56{\pm}59.08MPa$, $217.18{\pm}12.96MPa$). 2) The tensile strength and 0.2% yield strength of the laser-welded group were about each 98%, 99.7% of the as-cast group. There were no statistically significant differences in these two groups(p<0.05). 3) The percentage elongations of the soldered group($3.94{\pm}2.32%$) and the laser-welded group($5.06{\pm}1.08%$) were significantly less than the as-cast group($14.25{\pm}4.05%$) (p<0.05). 4) The fracture of the soldered specimens occurred in the solder material and many porosities were showed at the fracture site. 5) The fracture of the laser-welded specimens occurred also in the welding area, and lack of fusion and a large void was observed at the center of the fracture surface. However, the laser-welded specimens showed a ductile failure mode like the as- cast specimens. The results of this study indicated that the tensile strengths of the laser-welded joints were comparable to those of the as-cast joints and superior to those of the soldered joints.

Eating Habits and Food Preferences of Certain Middle School Students in Daegu Area (대구 지역 일부 중학생의 식습관 및 식품 기호도)

  • Sung, Young-Sook;Bae, Ji-Hyun
    • The Korean Journal of Food And Nutrition
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    • v.24 no.3
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    • pp.312-319
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    • 2011
  • We investigated the eating habits and food preferences of middle school students to provide material for establishing dietary and nutritional education at the elementary level. We questioned 270 male and female students attending certain middle schools in the Daegu area about their eating habits and food preferences. Eating habits were found to be most regular for students in families where only one parent worked and irregular for students in families where both parents worked. There was a positive correlation between a higher level of academic education of the father and the frequency of consumption of instant foods. There was also a positive correlation between a higher level of academic education of the mother and the frequency of snack consumption. Male students had a higher preference for consuming animal foods than did female students. Students that lived in extended families tented to have a higher preference for vegetable foods. On the other hand, students that lived in nuclear families and students that lived in families where both parents worked preferred snacks more. Based on these results, parental employment and academic education level influences the eating habits and food preferences of middle school students.

Geochemistry of Granitic Rocks Around the Southern Part of the Yangsan Fault (양산단층 남부일원에 분포하는 화강암질암의 지화학적 연구)

  • Hwang Byoung-Hoon;Yang Kyounghee
    • Journal of the Mineralogical Society of Korea
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    • v.18 no.3 s.45
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    • pp.165-181
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    • 2005
  • The granitic rocks distributed in the southern part of the Yangsan Fault are classified into five distinct rock facies based on the field relation, petrography and geochemical characteristics. These five different rock facies can be grouped into two considering their origins. Group I, which reveals various evidences of magma mixing, includes three rock facies of granodiorite, enclave-rich porphyritic granite, and enclave-poor porphyritic granite. Group H intruding Croup I includes equigranular granite and micrographic granite with no evidence of magma mixing. It is suggested that the distinctively different trace element and isotopic chemistries between group I and II, support evolution from the different parental magma. It is suggested that the three rock facies in group I were generated by different degrees of magma mixing in addition to fractionation of plagioclase. MMEs experienced fractionation of biotite. The two facies in group H seem to have been generated from different parent magma from group I and evolved by fractionation of K-feldspar. The Rb-Sr whole-rock ages of the group I rocks yield $59.2\~58.9Ma$, and those of the group II rocks give 53. $3\~51.7Ma$, regardless of their distribution whether they occur in the eastern or western parts of the Yangsan Fault. Based on Sm-Nd isotope compositions, depleted mantle model ages $(T_2DM)$ of the group I range $0.8\~0.9Ga$, while those of the group II$0.6\~0.7Ga$.

A study on the factors influencing the satisfaction of life of disabled children parents (장애아 부모의 삶의 만족도에 영향을 미치는 요인에 관한 연구)

  • Lee, Hyun-Suk;Ha, Kyu-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.11
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    • pp.8046-8056
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    • 2015
  • The purpose of this study is the study of factors affecting the life satisfaction of disabled children parents. Survey data metropolitan area and Gyeonggi-do special schools, day shelter, Disabled Welfare, especially on the national branch in Korea Funny disabled parent meetings, through 389 branches were collected material wealth targeting parents with disabilities. Statistical analysis SPSS 19.0 program utilizes factor analysis, reliability analysis. And parents of children with disabilities and environmental factors are the demographic characteristics in order to analyze the impact on life satisfaction as a control variable, and the environmental factors as independent variables were performed hierarchical regression analysis. Results are crazy and the positive(+) influence a religious presence and the average monthly income of demographic characteristics in the satisfaction of life, environmental factors all had significant influence on life satisfaction. In other words, family support, disability, social networks, personal nature had a positive(+) influence on life satisfaction of disabled children parents, the relative influence of these factors include family support, disability, social networks, net of personality. It was in. The result is handicapped parents receive emotional support and help from family, the lower the degree of disability of the child, as participation in meetings or disability welfare various programs and handicapped parents, and the more it has a positive character increased satisfaction in life that can be interpreted.

Hybrid Vigor and Reciprocal Effect of Several Growth and Yield Characters in Fls crossed between Hulled and Naked Barley (겉보리와 쌀보리의 교잡 F1 세대에서 생육 및 수량형질의 잡종강세와 정역간 교잡효과)

  • 정원복;정영주;정영수
    • Journal of Life Science
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    • v.12 no.3
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    • pp.256-263
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    • 2002
  • This study was carried out to estimate the degree of heterosis and heterobeltiosis, and the heritability and genetic correlation in F$_1$hybrid produced by reciprocal crosses between two six-rowed hulled barley (Gangbori and Olbori) and three six-rowed naked barley (Saechalssalbori, Saessalbori, and Moodeongssalbori). Heterosis was observed positively in traits such as cults length, spike length, awn length, leaf length, leaf width, number of spikes per plant, number of grains per spike, and 1000 grain weight. Heterosis and heterobeltiosis from the crosses with hulled barley as a material parent showed higher performance in culm length, leaf length, leaf width, number of spike per plant, number of grains per spike. The hulled grain characteristics is dominant over the naked one. The highest heritability was confirmed in leaf width with a value of 94.5% and overall high heritability was observed in most traits with the range from 76.7% to 94.5%. In an analysis of correlation coefficient, higher genetic correlations were observed between leaf length and number of spikes per plant(0.970), between cults length and number of grains per spike(0.963), and between awn length and leaf length(0.862) in the forward crosses in which hulled barley was maternal. In the reverse crosses, higher genetic correlation was observed between culm length and spike length(0.926), between awn length and leaf length(0.922), and between number of spikes per plant and number of grains per spike(0.713).

A study on recovery of Platinum Group Metals(PGMs) from spent automobile catalyst by melting technology (용융기술(熔融技術)을 이용(利用)한 자동차폐촉매(自動車廢觸媒)에서의 백금족(白金族) 금속(金屬) 회수(回收) 연구(硏究))

  • Park, Hyun-Seo
    • Resources Recycling
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    • v.20 no.2
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    • pp.74-81
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    • 2011
  • The dry method and wet method are currently used for the recovery of platinum group metals (Pt, Rh, Pd) contained in spent automobile catalysts. The study herein aims to identify the melting condition and optimum collector metal in accordance with a comparison of each concentration change in melting waste catalysts, using Fe and Cu in a basic experiment to recover waste catalysts through application of the dry melting method. As a summarized result of the experiment herein, it was determined to be more advantageous to use Fe as a parent material rather than Cu from the aspect of recollection rate, and the concentration change rate of platinum group metals within slag was greatly enhanced at $1,600^{\circ}C$ melting condition rather than at $1,500^{\circ}C$ in terms of melting processing temperature. The mean concentration of platinum group metals - Rh, Pd and Pt - within slag after a melting process at $1,600^{\circ}C$ were 6.21 ppm, 5.98 ppm and 6.97 ppm. The Rh and Pd were 50.58% and 55.31% respectively greater than the concentration change rate of platinum group metals in slag at a melting temperature of $1,500^{\circ}C$. However, since the initial concentration of Pt within the waste catalysts was 12.9 ppm, is relatively low, it was difficult to compare concentration change rates after the melting process.

A study on the evolution of granite hill on the west coast area (서해안의 화강암 암체 지형 발달에 대한 연구 - 반발 강도와 화학 조성 특징을 중심으로 -)

  • Kim, Jong Yeon;Yang, Dong Yun;Shin, Won Jeong
    • Journal of The Geomorphological Association of Korea
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    • v.21 no.4
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    • pp.19-40
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    • 2014
  • Rock rebound values and chemical compositions of Gamak island at Sangha, Gochang, Jeollabuk do are analysed as a part of geomorphic survey of that area. Some corestones are formed by deep weathering found from the summit of rock mass of Gamak island, while the rocks a part of weathering front are exposed at the foot of the island. Rebound values of rock increase toward coastal plain, so summit would be weak in resistance to erosion. It can be assumed that chemical weathering is more active at the summit by the chemical index of alteration and changes in chemical composition ratio. However it should be mentioned that the samples are taken from the surface of the rock mass that more fresh part will be exposed when the weathered parts are removed. The chemical composition and CIA values of the polygonal cracks found from on the surface of weathering rind showed that this part has values between those of the summit and the footslope. The bottom of weathering rind with polygonal cracks has higher CIA value than those of the surface. Though it supports the result from the Bisul Mt., there also difference in the ratio of SiO2. It looks caused by the difference in weathering environment and chemical difference in parent rock. In summary Gamak island is the remnants of weathering front after removal of weathered material. The removal processes are more active at the footslope where the coastal processes are stronger than the summit.

A Study on the Analysis of Mediated Effects of Father's Play Participation in the Relationship Between Father's Play Belief and Child's Playfulness (아버지의 놀이신념과 유아 놀이성 관계에서 아버지의 놀이 참여도의 매개효과 분석)

  • Choi, Tae-Sun
    • Journal of Korea Entertainment Industry Association
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    • v.14 no.7
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    • pp.333-342
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    • 2020
  • Children grow and develop through play. Play is being used as a friend and a learning material and tool in everyday life of children. It is a research study aimed to empirically analyze the effects of father's play belief and play participation on child's playfulness. A survey was carried out for the selected 284 children aged 5 years and older attending kindergarten located in D-gu, Seoul in order to achieve the goal of this study. Frequency analysis, descriptive statistics, reliability verification, correlation analysis, and regression analysis were conducted on the data collected through the survey by using the SPSS program, and the research results were derived as below. First, it showed that father's play belief and play participation have a positive effect on child's playfulness of physical spontaneity, social spontaneity, cognitive spontaneity, expression of joy, and a sense of humor. Second, father's play participation had a significant effect as a partial parameter in the relationship between father's play belief and child's playfulness. Thus, it was drawn the conclusion that father's play belief and play participation are important variables that can predict child's playfulness. Therefore, It will be necessary to promote children's playfulness development by continuously providing parent education programs on creating an atmosphere of various interaction at home through plays in the relationship between father and child and a desirable role of father in the play activities with child at the level of preschool educational institutions.