• Textile Coloration and Finishing
• /
• v.15 no.6
• /
• pp.8-17
• /
• 2003

In order to investigate the possibility of PVA particle as toner, PVA/PVAc particle was manufactured. Fine spherical PVAc particle with emulsifier SDS(sodium Dodecyl Sulfate) and initiator V-50(2,2'- azo bis(2-amidinopropane) dihydrochloride) was manufactured by emulsion polymerization. And then, the PVAc was carried with surface saponification. PVA/PVAc skin core structured particle was obtained under optimum saponification condition. PVA skin side in manufactured PVA/PVAc particles was dyed with 1:2 metal complex type C. I. Acid Yellow 235 and then the dyed PVA particles were observed with a optical microscope. Under given polymerization condition such as SDS concentration, $1.62\times{10}^{-2} \;mol/lH_2O$, V-50 concetration, $3.7\times{10}^{-3}\;mol/lH_2O$ and temperature $50^\circ{C}$ , the high molecular weight of PVAc with Pn 13,900 and PVA with Pn 3,400 was produced. The particle distribution of obtained PVAc microspheres was appeared highly at 60 and $100\mu{m}$, respectively.

• Journal of the Korean Society of Clothing and Textiles
• /
• v.41 no.3
• /
• pp.517-526
• /
• 2017

The biodegradation and water absorption properties of lignin/poly(vinyl alcohol) (PVA) nanofibrous webs are investigated. Lignin/PVA nanofibrous webs containing 0, 50, and 85wt% of lignin were prepared via an electrospinning process to observe the effect of the lignin concentration on the biodegradability and water absorption properties of lignin/PVA nanofibrous webs. The morphology of the materials was examined by field emission scanning electron microscopy (FE-SEM) and atomic force microscopy (AFM). To understand the wetting behavior and hydrophilic nature of the electrospun lignin/PVA nanofibrous webs, the water absorbency, contact angle, and water uptake were examined. The enzymatic degradation of lignin/PVA nanofibrous webs was investigated using laccase by measuring total organic carbon (TOC) concentration over a course of 50 days. Water drops were absorbed immediately into all of the specimens. The water uptake of lignin/PVA nanofibrous webs increased as the amount of PVA in the lignin/PVA hybrid webs increased. The enzymatic degradation experiment indicated that the inherent biodegradability of lignin was retained after its transformation into nanofibers. Our findings imply that blending these two types of polymers is promising because it can lead to the development of a new range of multifunctional materials such as antimicrobial absorbent nanotextiles based on sustainable biopolymers.

• Journal of the Korean Geosynthetics Society
• /
• v.4 no.1
• /
• pp.37-46
• /
• 2005

PVA geotextile/HDPE geomembrane composites were made to examine the waste landfill related properties. Tensile properties, tear and bursting strengths, AOS(apparent opening size) and permittivity of PVA geotextiles were evaluated, respectively. Ultraviolet stability and chemical resistance to the leachate was evaluated also. Friction property and creep deformation were tested at various loading condition. From this, it was seen that PVA geotextile/HDPE geomembrane composites have more excellent properties than the typically used polypropylene and polyester geotextiles in waste landfill. Finally, creep deformation behaviours of PVA geotextile/HDPE geomembrane composites were more stable than polypropylene and polyester geotextiles through the reduction factor analysis.

• Journal of the Semiconductor & Display Technology
• /
• v.9 no.4
• /
• pp.1-5
• /
• 2010

The PVA (poly-vinyl alcohol) insulators were spun coated onto ITO coated glass substrates with the capacitors of Glass/ITO/PVA/Al structure. The effects of PVA concentrations (3.0, 4.0 and 5.0 wt%) on the morphology and electrical properties of the films were investigated. As the concentration of PVA increased from 3.0 to 5.0 wt%, the leakage current of device decreased from 17.1 to 0.23 pA. From the AFM measurement, the RMS value decreased with increasing PVA concentration, showing the improvement of insulator film roughness. The capacitances of the films with PVA concentrations of 4.0 and 5.0 wt% were about 28.1 and 24.2 nF, respectively. The lowest leakage current of 1.77 PA was obtained at the film thickness of 117.5 nm for the device with fixed PVA concentration of 5.0 wt%.

• Journal of the Korean Applied Science and Technology
• /
• v.38 no.1
• /
• pp.178-185
• /
• 2021

In this study, polyvinyl alcohol (PVA) and polypropylene glycol (PPG)-based polyurethane dispersion resin for wound coating was synthesized. And the physical properties of the sample were coated on the surface of the film sample and the leather (Full-Grain) to study the physical properties change. In the case of tensile strength, PUD-PA1, which reacted with the least amount of PVA, showed the highest resistance at 2.00 kgf/㎟. Likewise, the rate of elongation was measured as high as 554% for PUD-PA1, which reacted with the least amount of PVA. The abrasion resistance measurement result showed that as the PVA response increased, the strength of the surface decreased to 36.77 mg.loss.

• The monthly packaging world
• /
• s.154
• /
• pp.108-109
• /
• 2006

PVA필름은 휴대폰, 카메라폰, 컴퓨터모니터, LCD TV등 편광필름이 사용되는 TFT-LCD 제품에는 반드시 필요한 핵심부품으로, 최근 인조대리석 제조용 필름, 분리필름, 내(耐)산소투과성 포장필름 등에도 활용범위를 넓혀가고 있는 신소재이다. 그러나 PVA필름은 일본이 PVA특성조절기술을 갖고 있어 그동안 일본에서 전량 수입해 사용해 온 것이 현실. 지난 1990년 설립된 이래, 국내 최초로 순수국내 기술로 고온수용성 부직포를 개발하며, 생산해 온 (주)텍스테크(대표이사 신재균)가 폐 부직포를 재활용해 LCD용 폴리비닐알코올(PVA) 필름을 제조하는 기술을 개발, 업계의 주목을 끌고 있다. 신재균 사장을 만나 폐부직포를 이용한 PVA 필름제조 기술개발 경위와 기대효과를 들어보았다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2009.11a
• /
• pp.42-42
• /
• 2009

To make up for the disadvantages of PVA gate, we blend PVP(20% wt) with PVA(5% wt) as a gate material. The best ratio for the mixture was 5:5, PVP-PVA blended gate used MIM structure showed better performance in leakage current and capacitance. PVP-PVA blended gate was fabricated by spin-coating process and pentacene was used as an organic TFT channel layer by thermal evaporation. Overall OTFT performance has also increased as PVP-PVA blended gate has relatively lower leakage current and higher capacitance than pure PVA gate has.

• Journal of the Korean Ceramic Society
• /
• v.22 no.4
• /
• pp.21-25
• /
• 1985

For studying the influence of addition of Polyvinyl alcohol (PVA)-montmorillonite complex on the hydration of Portland cement the PVA-montmorillonite derivatives were prepared in advance an characterized system-of Portland cement the PVA-montmorillonite derivatives were prepared in advance and characterized systema-tically. PVA with the polymerizationdegree ranging from 500 to 2000 have been intercalated into the lamellar structure of hydrated montmorillonites which were fractionated under 2㎛ by Stock's rule. In all cases the constant basal spacing of ∼20Å was determined whatever the molecular weight of PVA used. And the carbon chain orientation of PVA in the interfoliar space has been deduced to be parallel with bilayer structure.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.34 no.2
• /
• pp.22-31
• /
• 2002

In this paper, PVA(polyvinylalcohol), oxidized starch and SBR latex were used as binders for ink-jet printing papers, and their effects of the type and blending ratio of binders on ink-jet printing properties were compared. In case of coating color using PVA mainly used for a binder in ink-jet printing, spreading of printed letters decreased and excellent images were manifested resulting from strong hydrophilic of PVA. However, increasing solids content of coating color was somewhat limited because of the interaction of PVA and functional groups in silica as well as high molecular weight of PVA. When oxidized starch and SBR latex were mixed with PVA at desirable ratio to solve these problems, runnability in coating process was improved and good printing properties were shown. Gloss was improved when latex was used along with PVA as a binder because of the thermoplastic property of the latex. From this result, possibilities of high solids content and high gloss ink-jet printing papers were investigated.

• Proceedings of the Korean Environmental Sciences Society Conference
• /
• 2005.05a
• /
• pp.373-374
• /
• 2005

1. 조사량의 증가는 PVA의 분해를 향상시켰다. 2. PVA의 초기 농도가 50 mg/L일 경우 1 kGy에서 99% 이상의 분해효과를 나타내었으며, 250 mgh일 경우 39.2% 의 분해 효과를 나타내어, PVA의 방사선에 의한 분해는 PVA초기농도에 영향을 받고 있음을 알 수 있다. 2. PVA 자체는 방사선에 의해서 효과적으로 분해 되었지만, TOC의 경우 초기농도50mg/L의 PVA를 제외하고는 아주 미비한 제거 효과를 보였다. 하지만 생분해도가 증가함으로써 방사선 처리후 생물학적 처리의 연계는 PVA를 완전히 산화시키기 위한 효과적인 방안이 될 수 있을 것임을 예측할 수 있었다.