• Title/Summary/Keyword: PS4

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Properties of Working Electrodes with Polystyrene Beads Addition in Dye Sensitized Solar Cells

  • Noh, Yunyoung;Choi, Minkyoung;Song, Ohsung
    • Journal of the Korean Ceramic Society
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    • v.52 no.5
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    • pp.380-383
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    • 2015
  • We prepared the $TiO_2$ layer with 0 ~ 4 wt% of polystyrene (PS) beads having a radius of 250 nm to increase the dye adsorption and energy conversion efficiency (ECE) of a dye sensitized solar cell (DSSC). Then, we fabricated DSSCs using $0.45cm^2$ active area. FE-SEM was used to characterize the microstructure consisting of $TiO_2$ layer and PS beads. UV-VIS-NIR was used to determine the optical absorbance of working electrodes (WEs). Solar simulator and potentiostat were used to determine the photovoltaic properties. We observed that pores having a radius of 250 nm were formed with the density of $0.15ea/{\mu}m^2$ in $TiO_2$ layers after conducting the sintering process. The absorbance in visible light regime was found to increase with the increase in the amount of PS beads. The ECE increased from 4.66% to 5.25% when the amount of PS beads was increased from 0 to 4 wt%. This is because the pores of PS beads increased the adsorption of dye. Our results indicate that the ECE of the DSSCs can be enhanced by the addition of an appropriate amount of PS beads into $TiO_2$ layers.

Magnetic and Temperature-Sensitive Composite Polymer Particles and Adsorption Behavior of Emulsifiers and Trypsin

  • Ahmad, Hasan;Rahman, M.Abdur;Miah, M.A. Jalil;Tauer, Klaus
    • Macromolecular Research
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    • v.16 no.7
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    • pp.637-643
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    • 2008
  • A combination of magnetic and temperature-responsive properties in the same polymer composites is expected to increase their potential applications in the biomedical field. Accordingly, micron-sized magnetite/polystyrene/poly(2-dimethylaminoethyl methacrylate-ethyleneglycol dimethacrylate), which are abbreviated as $Fe_3O_4$/PS/P (DM-EGDM) composite polymer particles, were prepared by the seeded copolymerization of DM and EGDM in the presence of magnetite/polystyrene ($Fe_3O_4$/PS) particles. $Fe_3O_4$/PS/P(DM-EGDM) composite particles with magnetic properties showed a temperature-sensitive phase transition at approximately $31^{\circ}C$. The adsorption behavior of the low molecular weight emulsifiers and trypsin (TR) as biomolecules were examined on $Fe_3O_4$/PS/P(DM-EGDM) composite polymer particles at different temperatures. The native conformation of TR was followed by measuring the specific activity under various adsorption conditions. The activity of the adsorbed TR on composite polymer particles was higher than those of the tree TR and TR adsorbed on $Fe_3O_4$/PS particles.

The Effect of Plantaginis Semen on $CCI_4$ Induced Hepatoxicity in Rats (차전자(車前子)의 약침(藥鍼) 및 경구투여(經口投與)가 백서(白鼠) 간손상(肝損傷)에 미치는 영향(影響))

  • Kwon, Seon-Ho;Kim, Cheol-Hong;Youn, Hyoun-Min;Jang, Kyung-Jeon;Ahn, Chang-Beohm;Kim, Hoon;Song, Choon-Ho
    • Korean Journal of Acupuncture
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    • v.23 no.2
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    • pp.155-166
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    • 2006
  • Objectives: This study was undertaken to determine if Plantaginis Semen(PS) has a protective effect against $CCI_4$ induced hepatoxicity in Rats. Methods: The experimental groups were divided into Normal group (untreated Group), Control group $(group\;treated\;with\;CCI_4)$, Sample 1 (group treated with 0.1 ml Plantaginis Semen herbal acupuncture in both sides of $G\bar{a}nsh\bar{u}\;(BL_{18})$ after $CCI_4$ treating) and Sample 2 (group treated with feeding of 1 cc Plantaginis Semen extraction after $CCI_4$ treating). Rats were administered orally $CCI_4\;(0.1\;ml/kg)$ for 4 days. In experiments for PS effect, rats of Sample 1 group received 0.lml herbal acupuncture of PS extraction in both sides of corresponding $G\bar{a}nsh\bar{u}\;(BL_{18})$ of human body for 3 days after treated $CCI_4$. Rats of Sample 2 group feeded PS extraction (1cc) for 3 days after treated $CCI_4$. Variation of weight and biochemical assays (AST, ALT, LDH, ALP, total cholesterol, triglyceride, total protein, albumin) were performed. Results: In Control group, $CCI_4$ increased serum AST, ALT, LDH, ALP, total protein, albumin and decreased weight, total cholesterol, triglyceride. Sample 1 and Sample 2 significantly decreased serum AST, ALT, LDH, ALP, total protein, albumin as compared with Control group. Conclusion: These results indicate that PS could be used in prevention and treatment of hepatoxicity. However, precise mechanisms of PS protection remain to be determined.

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Electron Transport Activities of Chloroplasts Isolated from the Detached Rice Leaves Stored under Low Temperature with Illumination (광 및 저온처리한 벼잎 절편에서 분이한 엽록체의 전자전달 활성)

  • 문병용
    • Journal of Plant Biology
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    • v.31 no.4
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    • pp.299-307
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    • 1988
  • The electron transport activities of choloroplasts isolated from hte detached rise (Oryza sativa L. cv. Chucheong) leave stored under low temperature(4$^{\circ}C$) with light illumination were investigated to understand the role of light in the low temperature inhibition of photosynthesis in the chilling-sensitive plants. Chlorophyll content of the detached leaves upon incubation at 28$^{\circ}C$ and 4$^{\circ}C$ in the dark was also measured. The rice seedlings were grown with Hoagland medium in the growth chamber of 28$^{\circ}C$ temperature and 400 ft.c fluorescent light with the photoperiod of 16 h. Although chlorophyll content of the detached leaves stored in the dark declined by 61.7% after 28$^{\circ}C$ treatement, there occurred only 5.2% decrease of chlorophyll with 4$^{\circ}C$ treatment. Low temperature treatment(4$^{\circ}C$) for 6 days brought about decreases in total photosystem(PS II+PS I) activities by 35.2% and 73.6% in te presence and absence of light, respectively, while after 28$^{\circ}C$ treatment of the detached leaves for 6 days in the dark there was only 27.6% decrease in PS II+PS I activity. PS II activities were also decreased by 35.6% and 72.2% in the light and dark, respectively. PS I activities were decreased slightly, however, by 7.6% and 16.2% in the light and dark, respectively. Investigations into DPClongrightarrowDCPIP and NH2OHlongrightarrowDCPIP activities revealed that low temperature inhibition of PS II activities was not due to the inactivation of the water oxidation capacity at low temperature. It was concluded that light protects the electron transport activities of isolated rice chloroplasts from the inhibitory effect of low temperature in the detached leaves.

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Study on Oil Production from Pyrolysis of Mixed Plastic Waste Using Multidimensional Chromatography (Multidimensional Chromatography/Mass Spectrometry를 이용한 혼합 폐플라스틱의 열분해 오일 특성 평가에 관한 연구)

  • 김석완
    • Journal of Environmental Science International
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    • v.11 no.4
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    • pp.375-382
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    • 2002
  • The total hydrocarbon distribution of oil products obtained from the pyrolysis of four kinds of mixtures of polyethylene-polystyrene waste has been studied by multidimensional chromatography(high performance liquid chromatography followed by capillary gas chromatography)/mass spectrometry. Saturated, unsaturated and aromatic hydrocarbons in oil products were selectively pre-separated according to structural groups by HPLC and the weight fraction of each group was estimated by analysis of each component using GC-FID response factors. The hydrocarbon distribution of aliphatic fraction consists of $C_{5}$ to $C_{25}$ saturated and unsaturated hydrocarbons. And that of aromatics fraction consists of benzene, toluene, xylene, styrene, propenyl benzene, naphthalene, and some of derivatives. Pyrolysis temperature did not affect the ratio of total weight fraction of aliphatic over aromatic hydrocarbon distribution in case of PS only and PE-PS mixtures (1:1 and 1:4 wt. ratio) as a feed while affected the ratio of total wt. fraction in case of PE only. The optimal temperature for the maximum oil production was $600^{\circ}C$ for pyrolysis of PS and 1:1 and 1:4 mixtures of PE and PS. The optimal condition for aromatic recovery was $600^{\circ}C$ with 1:1 mixture of PE and PS. In this condition, aromatic was produced up to 90% of total oil product. The maximum yield of toluene, xylene, styrene, and propenyl benzene were 8.6, 8.9, 51.0 and 7.4% of feed for pyrolysis PS at $700^{\circ}C$, respectively. However, only 1.3% naphthalene was recovered at $700^{\circ}C$ with 1:1 PE:PS(by wt.).

Microbiological, pH and Sensory Evaluations of Refrigerated Pork Tender-Loins Treated with Potassium Sorbate (Potassium Sorbate에 침지한 냉장 돼지고기 안심의 미생물, pH 및 관능평가)

  • Kim, Chang-Ryoul
    • Journal of Food Hygiene and Safety
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    • v.22 no.1
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    • pp.57-62
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    • 2007
  • Microbiological, pH, and sensory evaluations on pork tender-loins treated with potassium sorbate (PS) during storage at $4^{\circ}C$ were assessed. Treatments of 0.5-2.0% PS for 10 min effectively (P < 0.05) inhibited the growth of aerobic plate counts (APC) and gram-negative bacterial counts (GNC) compared to those of controls for 9 days at $4^{\circ}C$, respectively. Results of this investigation demonstrate that antimicrobial activity on APC and GNC in all treatments enhanced by increasing concentrations of PS during storage at $4^{\circ}C$. pH values of pork tender-loins treated with PS gradually increased by storage of 6 days at $4^{\circ}C$. Sensory data showed that 0.5-1.0% PS treatments were quite close in odor and appearance compared to fresh controls. Results indicated that pork tender-loins treated with 1.0% PS for 10 min could extend shelf-life to 9 days during refrigerated storage at $4^{\circ}C$ without adversely affecting sensory quality.

Protective Activities of Fractions of Water Extract Obtained from Artemisia iwayomogi Kitamura against Oxidative Stress-induced Mutagenesity: Correlation with Their Reactive Oxygen Scavenging Activity

  • Ahn, Byung-Yong;Jung, Mun-Yhung;Choi, Dong-Seong
    • Food Science and Biotechnology
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    • v.18 no.4
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    • pp.849-854
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    • 2009
  • Water extracts of injinssuk (Artemisia iwayomogi Kitamura) (WE) were obtained from the dried and ground leaves and stems of injinssuk. The WE was further fractionated into crude polysaccharide (C-PS) and nonpolysaccharide fractions (N-PS). The protective activities against the tert-butyl hydro peroxide induced mutangenecity on Escherichia coli PQ37 and reactive oxygen species scavenging activity of the WE, C-PS, and N-PS were studied. The WE obtained from leaves showed a significantly higher inhibitory effect on the mutagenicity than WE from stem. The WE obtained from the leaves having higher crude polysaccharide content but lower content of total carbohydrates had significantly higher antimutagenicity than that from the leaves with lower crude polysaccharide but higher total carbohydrate contents. Further study showed that C-PS fraction showed markedly stronger antimutagenic effect than N-PS. C-PS was also more effective than N-PS for hydroxyl radical scavenging activity, but was similar to N-PS in superoxide radical scavenging activity.

Effect of Lead(IV) Acetate on Procoagulant Activity in Human Red Blood Cells

  • Kim, Keun-Young;Lim, Kyung-Min;Shin, Jung-Hun;Noh, Ji-Yoon;Ahn, Jae-Bum;Lee, Da-Hye;Chung, Jin-Ho
    • Toxicological Research
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    • v.25 no.4
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    • pp.175-180
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    • 2009
  • Lead (Pb) is a ubiquitously occurring environmental heavy metal which is widely used in industry and human life. Possibly due to a global industrial expansion, recent studies have revealed the prevalent human exposure to Pb and increased risk of Pb toxicity. Once ingested by human, 95% of absorbed Pb is accumulated into erythrocytes and erythrocytes are known to be a prime target for Pb toxicity. Most of the studies were however, focused on $Pb^{2+}$ whereas the effects of $Pb^{4+}$, another major form of Pb on erythrocytes are poorly understood yet. In this study, we investigated and compared the effects of $Pb^{4+}$, $Pb^{2+}$ and other heavy metals on procoagulant activation of erythrocytes, an important factor for the participation of erythrocytes in thrombotic events in an effort to address the cardiovascular toxicity of $Pb^{4+}$. Freshly isolated erythrocytes from human were incubated with $Pb^{4+}$, $Pb^{2+}$, $Cd^{2+}$ and $Ag^+$ and the exposure of phosphatidylserine (PS), key marker for procoagulant activation was measured using flow cytometry. As a result, while $Cd^{2+}$ and $Ag^+$ did not affect PS exposure, $Pb^{4+}$ and $Pb^{2+}$ induced significantly PS exposure in a dose-dependent manner. Of a particular note, $Pb^{4+}$ induced PS exposure with a similar potency with $Pb^{2+}$. PS bearing microvesicle (MV), another important contributor to procoagulant activation was also generated by $Pb^{4+}$. These PS exposure and MV generation by $Pb^{4+}$ were well in line with the shape change of erythrocyte from normal discocytes to MV shedding echinocytes following $Pb^{4+}$ treatment. Meanwhile, nonspecific hemolysis was not observed suggesting the specificity of $Pb^{4+}$-induced PS exposure and MV generation. These results indicated that $Pb^{4+}$ could induce procoagulant activation of erythrocytes through PS exposure and MV generation, suggesting that $Pb^{4+}$ exposure might ultimately lead to increased thrombotic events.

Effect of Salicornia herbacea Polysaccharides on the Activation of Immune Cells in vitro and in vivo

  • Ryu, Deok-Seon;Kim, Seon-Hee;Lee, Dong-Seok
    • Food Science and Biotechnology
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    • v.18 no.6
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    • pp.1481-1486
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    • 2009
  • The immunomodulating effect of Salicornia herbacea polysaccharides on BALB/c mice splenocytes was investigated. Crude (CS) and fine polysaccharide (PS) extracts with potential biological activity were prepared from S. herbacea. For in vitro experiments, splenocytes and separated T cells were treated with CS and PS (0.5, 1, 2, and 4 mg/mL). For in vivo experiments, the CS and PS were orally administered to BALB/c mice every day for 2 weeks. For basic data analysis, physiological parameters were recorded. Cell proliferation of splenocytes and T cells was used as an index for immunomodulating activity. The proliferation of splenocytes and separated T cells was 3.2 and 3.5 times higher than the control, respectively. Moreover, when splenocytes were treated with mitogen, the highest proliferation rate was observed in splenocytes cultured with PS. Interestingly, the stimulative activity of PS was more strongly exerted through $CD4^+$ T cells than through $CD8^+$ T cells.

A Study on the Hepatoprotective effect of PS-1 from Artemisia iwayomogi (한인전 추출물의 간장보호 작용에 관한 연구)

  • 이순복;조태순;윤기욱;이종찬;이선미;심성보
    • Biomolecules & Therapeutics
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    • v.6 no.2
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    • pp.119-129
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    • 1998
  • The dose-response effect of polysaccharide extracts(PS-1) from Artemisia iwayomogi was inves-tigated under various hepatic disease models. Silymarin, DDB and UDCA were used as reference compounds. We found that the maximal effective dose of PS-1 was 100 mg/kg b.wt. in $CCl_4$-induced hepatotoxicity, D-galactosamine-induced hepatitis, in ANIT-induced cholestasis and 300 mg/kg b.wt. in $CCl_4$-induced chronic liver disease, 30 mg/tg b.wt. in chronic bile duct ligation and chronic ethanol fatty liver. These findings suggest that PS-1 fraction protects the hepatocyte against various hepatic injuries, and this fracton might be of therapeutic value.

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