• Nuclear Engineering and Technology
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• v.8 no.2
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• pp.77-80
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• 1976

The halogen exchange reactions of 2-naphylmethyl chloride have been investigated in actone and acetonitrile. The results were in good accord with PMO theory and HSAB principle.

• Journal of the Korean Magnetic Resonance Society
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• v.1 no.1
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• pp.45-58
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• 1997

Heteropoly compounds, H3PMo12O40, CsxH3-xPMo12O40, and vanadium containing heteropoly compound were characterized by Solid-state broad line 1H MAS NMR, 31P MAS NMR, and High Speed MAS 51V NMR spectroscopy of quadrupolar nuclei. The effects of calcination, dehydration, and the number of protons on the structure of heteropoly compounds were studied. The results of this study demonstrate that these Solid-state NMR techniques are very useful tools to study heteropoly compounds.

• Bulletin of the Korean Chemical Society
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• v.3 no.4
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• pp.140-144
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• 1982

Through-space and through-bonds interactions between two nonbonding orbitals are shown to be first-order and second-order perturbations of nonbonding orbitals by the framework sigma orbitals. Through-space interactions for diamines and triplet diradicals are always destabilizing, but through-bonds interactions are stabilizing owing to their coupling with through-space effect. Anomalies in level ordering and magnitudes of energy splitting can be rationalized with the present approach. Orbtial interactions predicted with the PMO method were found to be consistent with those obtained by STO-3G calculations and photoelectron spectroscopy.

• Journal of the Korean Chemical Society
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• v.29 no.1
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• pp.23-30
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• 1985

PMO expressions for ${\pi}^{\ast}$-${\pi}^{\ast}$ orbital interaction have been derived. Important differences between ${\pi}$-${\pi}$ and ${\pi}^{\ast}$-${\pi}^{\ast}$ interactions predicted by PMO expressions are : (ⅰ) energy splitting in ${\pi}^{\ast}$-${\pi}^{\ast}$ interaction will be greater than that in ${\pi}$-${\pi}$ interaction, (ⅱ) energy change due to interaction will be more destabilizing in ${\pi}^{\ast}$-${\pi}^{\ast}$ than in ${\pi}$-${\pi}$ interaction. These predictions were borne out in experimental data and in results of MO theoretical computations. It was pointed out that both STeO-3G and INDO-LCBO methods underestimate ${\pi}^{\ast}$-${\pi}^{\ast}$ orbital interaction and in order to estimate properly with MO theoretical calculation, use of split valence basis set is required.

• Journal of Advanced Navigation Technology
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• v.25 no.5
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• pp.370-376
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• 2021

development of the aerospace industry is increasing the research of projectiles. In addition, many tests are under way and many failures occur accordingly. Projectiles should be able to minimize failures because they are more dangerous than other electronic equipment. Therefore, it is necessary to verify wiring before powering the projectile. Accordingly, the wiring status was verified by resistance measurements. However, the wiring test of the previous resistance measurement method cannot be accurately measured due to devices such as capacitors and inductors in the projectile circuit. In this paper, impedance is measured in the connection state of cables and projectiles using a TDR meter. The Z-Segmentation algorithm is used to set the reference value for the measured steady state impedance. The Z-Segmentation algorithm first finds the peak values of the impedance waveform using a Kalman filter and obtains the final impedance peak segment through segmentation. In this way, the wiring status is determined based on the reference value for the normal state of the wiring.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.41 no.4
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• pp.23-28
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• 2004

In this paper, the properties of Mo as PMOS gate electrodes were studied. The work-function of Mo extracted from C-V characteristic curves was appropriate for PMOS. To identify the electrical and chemical stability of Mo metal gate, the changes of work-function and EOT(Effective Oxide Thickness) values were investigated after 600, 700, 800 and 90$0^{\circ}C$ RTA(Rapid Thermal Annealing). Also it was found that Mo metal gate was stable up to 90$0^{\circ}C$ with underlying SiO$_2$through X-ray diffraction measurement. Sheet resistances of Mo metal gate obtained from 4-point probe were less than 10$\Omega$/$\square$ that was much lower than those of polysilicon.

• Journal of Adhesion and Interface
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• v.21 no.3
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• pp.113-122
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• 2020

Mesoporous materials are a sort of promising materials with a wide spectrum of applications due to their unique well-defined porous structures that provide high surface area and controllable pore size. Among mesoporous materials, periodic mesoporous organosilicas (PMOs) are highly emerging materials in sense of applications due to their large pore sizes and organic functionality in the frame. The organic functional groups in the frameworks of these solids allow tuning of the surface properties and modification of the bulk properties of the material. This article provides a comprehensive overview of PMOs and discusses their different functionalities, morphology and applications, such as catalysis, environmental applications, and adsorption, for which PMOs have been used after their discovery. The review article will provide fundamental understanding of PMOs and their advanced applications to readers.

• Journal of the Korea Institute of Military Science and Technology
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• v.18 no.1
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• pp.37-45
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• 2015

These days many systems use the gps signal to get their own position. Because it's cheap and accurate and convenient. But, the strength of gps signal is very weak and can be easily interrupted by GPS jamming and GPS spoofing. Normally, fighter can use DME, TACAN, etc to correct their position error when GPS is not working. But, many aircraft which does not have those kinds of hardware need to pay additional cost to get it. In this paper, we propose how to overcome GPS jamming and GPS spoofing by only using data link system. The main purpose of this paper is to make the data link protocol to get an exact position information of own unit at gps error environment.

• Bulletin of the Korean Chemical Society
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• v.34 no.1
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• pp.225-230
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• 2013

A new heteropolyanion-based ionic ($[Hmim]_5PMo_{10}V_2O_{40}$) was synthesized by the reaction of molybdovanadophosphoric acid ($H_5PMo_{10}O_{40}$) with N-methylimidazole. [$[Hmim]_5PMo_{10}V_2O_{40}$ showed a high catalytic activity in the oxidative desulfurization of sulfur-containing compounds in 1-methylimidazolium tetrafluoroborate ($[Hmim]BF_4$) ionic liquid using 30% aqueous $H_2O_2$ as the oxidant. The catalytic system was of high activity, simplified workup and flexible recyclability. The catalytic oxidation reactivity of sulfur-containing compounds decreased in the order dibenzothiophene (DBT) > 4,6-dimethyldibenzothiophene (4,6-DMDBT) > benzothiophene (BT). The influences of various parameters including reaction time (t) and temperature (T), catalyst dosage, and oxidant to sulfur molar ratio n(O)/n(S) on the desulfurization of model oil were investigated in details. 99.1% of DBT conversion in the model oil was achieved at atmospheric pressure under the optimal conditions: n(O)/n(S) = 4:1, $60^{\circ}C$, 100 min and molar ratio of catalyst to sulfur of 0.062. The ionic liquid can be recycled six times without significant decrease in activity.

• Journal of the Korea Institute of Military Science and Technology
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• v.19 no.3
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• pp.379-386
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• 2016

In this paper, phase noise analysis result for 2.4 GHz PLL(phase locked loop) using SPD(sample phase detector) is proposed. It can be used for high performance frequency synthesizer's LO(local oscillator) to extend output frequency range or for LO of offset PLL to reduce a division rate or for clock signal of DDS(direct digital synthesizer). Before manufacturing, theoretical estimation of PLL's phase noise performance should be performed. In order to calculate phase noise of PLL using SPD, Leeson model is used for modeling phase noise of VCO(voltage controlled oscillator) and OCXO(ovened crystal oscillator). After theoretically analyzing phase noise of PLL, optimized loop filter bandwidth was determined. And then, phase noise of designed loop filter was calculated to find suitable OP-Amp. Also, the calculated result of phase noise was compared with the measured one. The measured phase noise of PLL was -130 dBc/Hz @ 10 kHz.