• Journal of Korean Society for Atmospheric Environment
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• v.16 no.2
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• pp.89-102
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• 2000

A total of 318 particulate sample sets consisting of both fine PM(FPM : dp$\leq$2.5 ${\mu}{\textrm}{m}$) and coarse PM(CPM : 2.5${\mu}{\textrm}{m}$${\mu}{\textrm}{m}$) was collected by a dichotomous sampler in Suwon area from December 1996 to November 1997. The concentration of seven inorganic elements such as pb. Cr, Cd, Cu, Zn Fe and Na were determined from each sample using an AAS. The purpose of the study was to extensively investigate environmental behaviors of particulate matters and to provide air quality management schemes applying various statistical approaches. The mean concentrations of PM10 Results of correlation analyses indicated the existence of strong correlations among inorganic elements PM10 FPM CPM and various meterological variables. Our study also examined the degree of uncertainties whether the particular elements can be assorted into the accumulation mode or the coarse mode in their size distribution. Furthermore the analysis of the pollution rose showed graphically the direction of potential sources of particulate matters. According to statistical analyses of our data quantitative differences appeared in the pollution patterns between weekdays and weekends.

• Journal of Environmental Health Sciences
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• v.26 no.4
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• pp.1-8
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• 2000

The objective of this study was to identify the sources and to estimate the source contributions to the atmospheric TSP(total suspended particulate matter) and PM-10(particulate matter with aerodynamic diameters less than 10$\mu\textrm{m}$) concentration in Taegu area. A total of 84 samples was collected during the January to December 1999. TSP and PM-10 were collected on filters by portable air sampler, and heavy metals in TSP and PM-배 were analyzed by ICO(Inductively Coupled Plasma Spectrometery) after preliminary treatment. The results were follow as : First, annual average of TSP and PM-10 concentration was 123 and 69$\mu\textrm{g}$/㎥ respectively. The concentration of TSP and PM-10 were highest in winter season compared to other seasons. Second, the concentration of Al, Fe, Mn were higher in TSP than in PM-10, indicating that these heavy metals are generally associate with natural contributions. Third, metal combinations showed that a high correlation among concentrations of heavy metals were follows: As Al, Fe and Mn in TSP ; Ni, Cr, Cd and Pb in PM-10. Finally, Statistical analysis was performed using Principal Components Analysis(PCA) in order to find possible sources of the pollutants. The factor analysis was permitted to identify four major sources(soil/road dust resuspension, waste incineration, furl combustion, vehicular emission) in each fraction. These source accounted for at least 83, 85% of variance of TSP and PM-10 concentration in Taegu area.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.24 no.4
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• pp.492-500
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• 2014

Objectives: The purpose of this study is to estimate the applicability of regional sample collection of environmental samples. The concentration of asbestos fibers were analyzed with two devices. One was an existing commercial air sampling pump that has been proved to be accurate and exact, and the other is a remodeled pump for sample collection which was made from an electric bubble generator originally designed for aquarium fish. Samples were collected with the two devices under the same environmental conditions and collection equipment. A comparative analysis of the concentration of ambient asbestos fiber was then performed. Methods: Based on previous research, six farmhouses with asbestos fiber slate roofs known to have high concentrations of asbestos fiber were selected. Using the existing commercial air sampling pump and the remodeled electric bubble generator, four to seven samples were collected each day one meter downwind from the edge of the slate roof at high volume (about 4 L/min) and low volume (about 1.4 L/min). The analyzer responsible for sample quality control of asbestos fibers counted the number of asbestos fibers with a phase microscope. Results: The rates of flow change of the existed sampler and the remodeled pump at high volume were 0.82% and 0.17%, respectively. The rates of flow change at low volume were 3.83% and 1.09%, but there was not significant difference. The rates of flow change are within the error range (${\pm}5%$) of OSHA analyzing methods. For the high volume sampler, the average asbestos fiber concentration in the air collected by the existed sampler is 6.270 fibers/L and for the remodeled one 5.527 fibers/L, not a significant difference. For the low volume sampler, the average asbestos fiber concentration in the air collected by the existed sampler is 7.755 fibers/L and for the remodeled one 7.706 fibers/L, not a significant difference. The total area of the slate roof of the targeted farmhouse has an effect on the concentration of asbestos fibers in the air from the existing pump and the remodeled one (p<0.01). Conclusions: The sampling function between the existing commercial pump and the remodeled one shows little difference. Therefore, the remodeled pump is considered a pump with a good availability for collecting ambient air asbestos samples.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.4
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• pp.275-288
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• 2009

The Korean government strengthened the environmental polices to manage and enhance Metropolitan Area air quality, and also has enforced "Special Act on Seoul Metropolitan Air Quality Improvement (SASMAQI)" issued in Dec. 2004. Recently government expanded the Seoul Metropolitan Air Quality Management District (SMAQMD) to the outskirts satellite cities of Seoul area through the "Revised Law Draft of SASMAQI". The SMAQMD has been alloted the allowable emission loads to the local governments on the basis of the carrying $PM_{10}$ capacity. However, in order to establish the effective air quality control strategy for $PM_{10}$, it is necessary to understand the corresponding sources which have a potential to directly impact ambient $PM_{10}$ concentration. To deal with the situations, many receptor methodologies have been developed to identify the origins of pollutants and to determine the contributions of sources of interests. The objective of this study was to extensively identify $PM_{10}$ sources and to estimate their contributions at the metropolitan area. $PM_{10}$ samples were simultaneously collected at the 3 semi-industrialized local cities in the Seoul metropolitan area such as Hwasung-si, Paju-si, and Icheon-si sites from April 15 to May 31, 2007. The samples collected on the teflon membrane filter by one $PM_{10}$ cyclone sampler were analyzed for trace metals and soluble ions and samples on the quartz fiber filter by another sampler were analyzed for OC and EC. Source apportionment study was then performed by using a positive matrix factorization (PMF) receptor model. A total of 6 sources were identified and their contributions were estimated in each monitoring site. Contribution results on Hwasung, Paju, and Icheon sites were as follows: 33%, 27%, and 27% from soil source, 26%, 26%, and 21% from secondary aerosol source, 11%, 11%, and 12% from biomass burning, 12%, 6%, and 5% from sea salt, 7%, 15%, and 19% from industrial related source, and finally 11%, 15%, and 16% from mobile and oil complex source, respectively. This study provides information on the major sources affecting air quality in the receptor sites and thus it will help to manage the ambient air quality in the metropolitan area by establishing reasonable control strategies, especially for the anthropogenic emission sources.

• Journal of Korean Society for Atmospheric Environment
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• v.33 no.5
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• pp.515-520
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• 2017

$PM_{2.5}$ concentrations were measured using a cyclone, impactor (the U.S. Environmental Protection Agency well impactor ninety-six, WINS) and optical particle counter (OPC) at a campus site located in Yongin for the period August 2014 through March 2017. The concentrations from cyclone (Y) were generally higher than those from impactor(X); the best-fit line was Y=1.22X+5.64. The ratios of $PM_{2.5}/PM_{10}$ ranged from 0.61 to 0.66 when $PM_{2.5}$ concentrations from cyclones in selected studies were converted into those from impactors using a regression equation in this study. The slope of the best-fit line between OPC and impactor was close to 1 at 0.95, while that between OPC and cyclone was 0.72. After sampling, the flow rate in the low-volume air sampler with cyclone decreased by 3% on average, which did not have a significant effect on measured concentrations.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.2
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• pp.190-201
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• 2010

Fine particulate matter < $1.8{\mu}m$ was collected as a slurry using the Semicontinuous Elements in Aerosol Sampler with time resolution of 30-min between May 23 and 27, 2002 at the Sydney Supersite, Florida, USA. Concentrations of 11 elements, i.e., Al, As, Cd, Cr, Cu, Fe, Mn, Ni, Pb, Se, and Zn, in the collected slurry samples were determined off-line by simultaneous multi-element graphite furnace atomic absorption spectrometry. Temporal profiles of $SO_2$ and elemental concentrations combined with meteorological parameters such as wind direction and wind speed indicate that some transient events in their concentrations are highly correlated with the periods when the plume from an animal feed supplement processing facility influenced the Sydney sampling site. The peaking concentrations of the elemental species during the transient events varied clearly as the plume intensity varied, but the relative concentrations for As, Cr, Pb, and Zn with respect to Cd showed almost consistent values. During the transient events, metal concentrations increased by factors of >10~100 due to the influence of consistent plumes from an individual stationary source. Also the multi-variate air dispersion receptor model, which was previously developed by Park et al. (2005), was applied to ambient $SO_2$ and 8 elements (Al, As, Cd, Cr, Cu, Fe, Pb, and Zn) measurements between 20:00 May 23 and 09:30 May 24 when winds blew from between 70 and $85^{\circ}$, in which animal feed processing plant is situated, to determine emission and ambient source contributions rates of $SO_2$ and elements from one animal feed processing plant. Agreement between observed and predicted $SO_2$ concentrations was excellent (R of 0.99; and their ratio, $1.09{\pm}0.35$) when one emission source was used in the model. Average ratios of observed and predicted concentrations for As, Cd, Cr, Pb, and Zn varied from $0.83{\pm}0.26$ for Pb to $1.12{\pm}0.53$ for Cd.

• Journal of Korean Society for Atmospheric Environment
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• v.21 no.6
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• pp.699-708
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• 2005

To characterize the elemental composition of fine particles in urban area, $PM_{2.5}$ was collected by a 3-stage DRUM impactor at Gwangju during spring and summer. Time and size resolved concentrations for 19 trace elements were obtained by synchrotron X-Ray fluorescence analysis. Trace elements in summer were distributed in smaller size range compared to those in spring. Almost trace element concentrations in fine particles were highly increased during the Asian dust. In spring, soil elements such as Si, K, Ca, Ti and Fe had low enrichment factors indicating the dominant influence of soil dust. However, all elements had high enrichment factors in summer implying that these elements could be emitted from the anthropogenic sources. Factor analysis was conducted with the elemental composition data in order to identify anthropogenic sources of aerosols in urban area during spring and summer. Fine particles in spring have several sources such as soil dust originating from China continental region, coal and oil combustion, biomass burning, sea salt, ferrous and nonferrous metal sources. On the other hand, fine particles in summer were influenced by road dust, gasoline vehicle as well as coal and oil combustion, sea salt, ferrous and nonferrous metal sources.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.11a
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• pp.61-64
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• 2003

This study was conducted to investigate the chemical characteristics of $PM^{10}$ at Anmyeon-do during the periods from January 1998 to December 2001. The $PM^{10}$ samples ($PM^{10}$) were collected by High Volume Air sampler (HVAS). The measured items were mass concentration of $PM^{10}$ with the major ions ($Cl^{-}$, ${SO_{4}}^{2-}$, ${NO_3}^{-}$, ${Mg}^{2+}$, ${Ca}^{2+}$, ${K}^{+}$etc.) and metallic elements (AI, Fe, Mn, Cr, Zn, Pb etc.). The chemical analysis of major ion components were made by Ion Chromatography (DX-500) and that of metallic elements were made by Inductively Coupled Plasma Spectrometer (ICP-AES, ICP-Mass). The average mass concentration of $PM^{10}$ increased substantially during the heavy dust periods (Asian Dust cases). For water-soluble ions, concentrations of ${Ca}^{2+}$, ${SO_{4}}^{2-}$ and ${NO_3}^{-}$ were remarkably enhanced. Concentrations and mass fraction of crustal elements such as Na, Mg, Ca, Fe, Mn were highly elevated, but those of pollution-derived heavy metals were appreciably decreased. The factor analysis was conducted in order to make the large and diverse data set as manageable levels and to qualitatively examine the relationship between the variables.

• Environmental Analysis Health and Toxicology
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• v.17 no.4
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• pp.333-339
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• 2002

Yellow sand (YS) storms were observed about ten times in the Korean peninsula during March and April in 2002. Twenty four hour fine particle (PM$\_$2.5/) samples were collected onto the 47 mm Teflon - coated quartz filters over 9 days during and after the events using the MiniVol Portable Air Sampler at a flow rate of 5 liters per minute. The highest PM$\_$2.5/ concentration measured during the YS period was 289 $\mu\textrm{g}$/㎥, which is 13 times higher than the lowest of the values for the samples collected during the non-yellow sand period. The filter samples were analyzed for inorganic ions using the IC, AAS and Autoanalyzer, and for metals using the ICP-MS. The results showed that the concentrations of some inorganic ions (e.g., Ca$\^$2+/ and SO$_4$$\^$2-/) and metals (e.g., Fe, Mn) of soil origin were elevated during the yellow sand events.

• Journal of Korean Society for Atmospheric Environment
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• v.26 no.1
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• pp.21-33
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• 2010

The objective of this study was to estimate the $PM_{2.5}$ source apportionment at the Pinnacles National Monument IMPROVE site in western coastal USA. The PMF was applied to identify the existing sources and apportion the $PM_{2.5}$ mass to each source. To analyze local source impacts from various wind directions, the NPR analysis was performed using source contribution results with the wind direction values measured at the site. Also, PSCF was applied to identify the locations by point sources relative to the back trajectories. A total of 1,634 samples were collected from March 1988 to May 2004 by IMPROVE sampler and 32 chemical species were analyzed by PIXE, PESA, XRF, IC, and TOR methods. The PMF modeling identified seven sources and the average mass was apportioned to gasoline vehicle, secondary sulfate, aged sea salt, secondary nitrate, wood/field burning, diesel emission, and soil, respectively. In this study, the average mass was apportioned to gasoline vehicle (33.0%), secondary sulfate (25.7%), aged sea salt (17.8%), and secondary nitrate (10.1%). Also, this study suggests the possible role for source apportionment study of $PM_{2.5}$ at similar areas such as wildness, national park, and coastal areas in Korea.