• Title/Summary/Keyword: PET (polyethylene terephthalate)

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Heavy Metal Absorption Properties of Sulfonated Polyethylene Terephthalate (Sulfonated Polyethylene Terephthalate의 중금속 흡착능)

  • Kang, Young-Goo;Kim, Dong-Hyun
    • Journal of the Korean Society of Safety
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    • v.18 no.4
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    • pp.92-97
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    • 2003
  • The purpose of this study is heavy metal absorption of recycled PET(poly ethylene terephatalate) NWF(non woven faric). The results of test are summarized as follows; Heavy metal abworption rates in Ni ions were higher then Zn and Cu ions, whereas heavy metal absorption rates by sulfonation times were not different. The heavy metal absorption times have a higher tendency from 60 min to 120 min. There were significant negative correlations among the amount used CSA(Chloro Sulfuric Acid) and the amount of absorption Zn(r = -0.33784, p < 0.05), Cu(r = -0.61177, p < 0.01) ions, whereas correlations between heavy metal absorption rates and sulfonation times were not significant. There were significant positive correlations among the amount of absorption Zn ions and the amount of absorption Ni(r = 96475, p < 0.014), Cu(r = 0.51614, p < 0.01) ions, likewise the positive correlations between the amount of absorption N ions and the amount of absorption Cu(r = 0.54766) ions were significant(p < 0.01).

Abrasion of PET Fabrics by Using Microwave Energy (Microwave Energy를 이용한 PET 직물의 Abrasion)

  • Cho, In-Sul;Lee, Eun-Woo;Cho, Kyu-Min;Chang, Du-Sang
    • Journal of the Korean Society of Industry Convergence
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    • v.2 no.2
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    • pp.69-72
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    • 1999
  • The aim of this study is to enhance the abrasion of the hydrolyzed polyethylene terephthalate(PET) fabrics by using microwave energy. In other to achieve the aforementioned objectives, PET fabrics were hydrolyzed in NaOH solution by using abrasion method such as dipping, microwave-dipping, pad steam-dry, and pad microwave-dry, and then abrasion of the hydrolyzed PET fabrics was calculated and investigated. As a result obtained form this study, the abrasion of the hydrolyzed PET fabrics is directly proportional to hydrolyzed time and NaOH concentration. And also, microwave-dipping method and pad microwave-dry method showed remarkable abrasion effect than the others.

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Analysis of Off-flavor Generated from a Polyethylene Terephthalate Water Bottles and Caps by Using an Electronic Nose (MS-전자코를 사용한 페트(polyethylene terephthalate) 생수병과 뚜껑의 이취 이행 분석)

  • Han, Hyun Jung;Park, Su Won;Jung, Hyo Yeon;Kim, Jung Sun;Dong, Hyemin;Noh, Bong Soo
    • Korean Journal of Food Science and Technology
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    • v.47 no.4
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    • pp.425-430
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    • 2015
  • The objective of the study was to investigate the off-flavor generated from PET water bottles and their caps by using a mass spectrometry-based electronic nose. The ion fragment data obtained from the electronic nose were used for discriminant function analysis (DFA). In the case of increased concentrations of the contamination of water, the off-flavor pattern depended on the discriminant function second score instead of the discriminant function first score. To identify the cause of off-flavor in polyethylene terephthalate (PET) bottled water, the PET bottle and its cap were analyzed by DFA. The results showed that the cap generated more volatile compounds than the bottle or mineral water did. The substances causing the off-flavor were predicted to be 2,4-di-tert-butylphenol (2,4-DTBP), nonanal, and decanal when the main peak of the mass spectrum was compared with the major ion fragments of the electronic nose. Thus, using this method, we could determine whether the PET water bottle was contaminated and whether the off-flavor resulted from contamination of the bottle cap.

Electrical Conductivity, Optical Transmittance, and Oxidation Stability of Transparent Conductive Polymer Film Coated With Layered Pristine Single-walled Carbon Nanotube and Silver Nanowire (무정제 단일벽 탄소나노튜브와 은나노와이어가 적층으로 코팅된 투명전도성 고분자 필름의 전기 전도성, 광학 투과도 및 산화안정성)

  • Young Sil Lee
    • Korean Chemical Engineering Research
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    • v.61 no.3
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    • pp.456-462
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    • 2023
  • An electrically conductive and transparent electrode was created by applying a dispersion of pristine single-walled carbon nanotubes (SWCNTs) and silver nanowires to a polyethylene terephthalate (PET) film using a bar coating method. The SWCNTs were added to increase the electrical conductivity and transmittance of the silver nanowires while also preventing the haze from increasing due to the stacking of multiple layers containing SWCNTs and silver nanowires on the PET substrate. The silver nanowires in the electrode were also found to be stable against oxidation. The transparent electrode displayed excellent electrical and optical properties, with a sheet resistance of 47 Ω/□, transmittance of 96.72%, and haze of 1.93%. Additionally, the sheet resistance of the electrode remained stable over time, with a change of only 6.4% after a constant temperature and humidity test, making it suitable for long-term use. A hybrid transparent electrode that is economically feasible and environmentally sustainable has been developed through the utilization of pristine SWCNT and silver nanowire.

Transesterification of Dimethyl Terephthalate with Ethylene Glycol (Dimethyl terephthalate와 ethylene glycol의 에스테르 교환 반응)

  • Lee, Jinhong;Cho, Impyo;Jo, Sanhwan;Cho, Minjung;Han, Myungwan;Kang, Kyungsuk
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.144-150
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    • 2013
  • The kinetics of the transesterification of dimethyl terephthalate (DMT) with ethylene glycol (EG) was studied in a batch reactor. Bishydroxyethyl terephthalate (BHET), which is poly(ethylene terephthalate) (PET) monomer, can be produced by the transesterification reaction. Zinc acetate was used as a catalyst. Previous kinetic studies was carried out in a semi-batch reactor where generated methanol was removed so that reverse reactions were not considered in the kinetic expressions, resulting in inaccuracy of the kinetic model. Mathematical models of a batch reactor for the tranesterification reaction were developed and used to characterize the reaction kinetics and the composition distribution of the reaction products. More accurate models than previous ones were obtained and found to have a good agreement between model predictions and experimental data. Effect of process variables on the esterification reaction was investigated based on the experimental and simulation results.

The excimer laser ablation of PET for nickel electroforming (니켈 전주도금을 위한 PET의 엑시머 레이저 어블레이션)

  • Shin, Dong-Sik;Lee, Je-Hoon;Seo, Jung;Kim, Do-Hoon
    • Laser Solutions
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    • v.6 no.2
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    • pp.35-41
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    • 2003
  • In this study, manufacturing of polymer master and mold insert for micro injection molding was investigated. Ablation by excimer laser radiation could be used successfully to make 3-D microstructure of PET. The mechanism for ablative decomposition of PET with KrF excimer laser(λ: 248nm, pulse duration: 5ns) was explained by photochemical process. And this process showed PET to be adopted in polymer master for nickel mold insert. Nickel electroforming by using laser ablated PET master was preferable for replication method. Finally, it was shown that excimer laser ablation can substitute for X-ray lithography of LIGA process in microstructuring.

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The Physiological Response on Wear Comfort of Polyethylene Terephthalate Irradiated by Ultra-violet

  • Choi, Hae-Young;Lee, Jung-Soon
    • Fibers and Polymers
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    • v.7 no.4
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    • pp.446-449
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    • 2006
  • The purpose of this study was to evaluate the comfort of PET clothing treated by UV. The physiological responses of the human body were investigated. Mean skin temperature and physiological signals such as Electroencephalogram (EEG), and heart rate (Electrocardiogram, (ECG)) were examined for 20 minutes during stable wearing conditions. Mean skin temperature was measured every two seconds using Ramanathan's method. Physiological responses were measured using Biopac MP100 series and analyzed using the software, Acqknowledge 3.5.2. Psychological effects were analyzed every five minutes. Comfort of untreated PET clothing decreased with the passage of time. Compared with PET clothing untreated, treated for 30 minutes, and treated for 90 minutes, the analysis of EEG showed that PET clothing treated for 90 minutes was the most comfortable after 20 minutes. In addition, the interval of the heart rate shown on the ECG was the highest in PET clothing treated for 90 minutes. Skin temperature was the lowest in PET treated for 90 minutes. We thus conclude that suitable UV irradiation would improve comfort.

Lipase Treatment of Polyester Fabrics

  • Kim, Hye-Rim;Song, Wha-Soon
    • Fibers and Polymers
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    • v.7 no.4
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    • pp.339-343
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    • 2006
  • The aim of this paper is to improve moisture regain of PET fabrics using a lipase treatment. Effects of nine lipase sources, lipase activator and nonionic surfactant on moisture regain of PET fabrics are examined. Moisture regains of lipase-treated samples improve by two times in average compared with untreated and buffer-treated samples. Alkaline treatment creates larger pitting by more aggressive attack into fiber which is proved by SEM and water contact angle measurement. Moisture regain by alkaline treatment ($0.568%{\pm}0.08$) does not improve. However, lipase-treatment (L2 treatment) improves moisture regain up to 2.4 times ($1.272%{\pm}0.05$). Although lipase treatment is more moderate than alkaline treatment, lipase hydrolysis on PET fabrics improves moisture regain, efficiently. K/S values improved confirm that carboxyl and hydroxyl groups are produced on the surface of PET fabrics by lipase hydrolysis. Moisture regain and dyeability improve by lipase hydrolysis on PET fabrics.

Excimer laser induced ablation of PMMA and PET (엑시머 레이저를 이용한 PMMA와 PET의 가공)

  • Shin, Dong-Sik;Lee, Je-Hoon;Seo, Jung;Kim, Do-Hoon
    • Laser Solutions
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    • v.6 no.1
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    • pp.33-40
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    • 2003
  • The ablative decomposition mechanism of PMMA(polymethyl methacrylate) and PET(polyethylene terephthalate) with KrF excimer laser(λ : 248nm, pulse duration: 5㎱) is investigated. The UV/Vis spectrometer analysis showed that PMMA is a weak absorber and PET is a strong absorber at the wavelength of 248nm. The results(surface debris, melt, etch depth, etching shape) from drilling and direct writing experiments imply that ablation mechanism of PMMA is dominated by photothermal process, while that of PET is dominated by photochemical process.

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Bond Performance of Recycled PET Bottle Fiber Reinforced Concrete (폐 PET병을 이용한 콘크리트 보강 섬유의 부착특성)

  • Won, Jong-Pil;Park, Chan-Gi;Lee, Su-Jin;Kim, Jung-Hoon;Kim, Hwang-Hee;Lee, Jae-Young
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.373-376
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    • 2006
  • The purpose of this study was manufactured and evaluated the bond performance of recycled polyethylene terephthalate(PET) bottle fiber reinforced concrete. Four deformed recycled PET bottle fibers were manufactured and pullout test was conducted in accordance with the JCI-SF 8. Test parameters included four different type of fiber geometry and two types of mortar specimens. According to bond test results, it was found that embossing type recycled PET bottle fiber was significant improving the pullout load and interface toughness.

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