• Title/Summary/Keyword: PDC

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Enzymatic Synthesis of L-tert-Leucine with Branched Chain Aminotransferase

  • Seo, Young-Man;Yun, Hyung-Don
    • Journal of Microbiology and Biotechnology
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    • v.21 no.10
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    • pp.1049-1052
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    • 2011
  • In this study, we demonstrated the asymmetric synthesis of L-tert-leucine from trimethylpyruvate using branched-chain aminotransferase (BCAT) from Escherichia coli in the presence of L-glutamate as an amino donor. Since BCAT was severely inhibited by 2-ketoglutarate, in order to overcome this here, we developed a BCAT/aspartate aminotransferase (AspAT) and BCAT/AspAT/pyruvate decarboxylase (PDC) coupling reaction. In the BCAT/AspAT/PDC coupling reaction, 89.2 mM L-tert-leucine (ee>99%) was asymmetrically synthesized from 100 mM trimethylpyruvate.

Flexural Behavior of I-Section Prestressed Dual Concrete Beam Using High Performance Steel Fiber Reinforced Concrete (고성능 강섬유보강 콘크리트가 적용된 I-단면 프리스트레스트 이중 콘크리트 보의 휨 거동)

  • Park, Tae-Hyo;Yun, Sung-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05a
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    • pp.162-165
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    • 2006
  • I-section prestressed concrete(I-PC) beam crack due to low tensile strength, may decrease rigidity and structural performance by excessive deflection. In an effort to this problem, in this research, I-section prestressed dual concrete(I-PDC) beam has been proposed, consisting of normal strength concrete in compression zone, and high performance steel fiber reinforced concrete(HPSFRC) with a bottom flange depth in tensile zone. Crack formation and its propagation are controlled by the HPSFRC in I-PDC beam. The initial cracking and service limit loads are increased along with the load carrying capacity and flexural stiffness.

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Missile Adaptive Control using T-S Fuzzy Model (T-S 퍼지 모델을 이용한 유도탄 적응 제어)

  • 윤한진;박창우;박민용
    • Journal of the Korean Institute of Intelligent Systems
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    • v.11 no.8
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    • pp.771-775
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    • 2001
  • In this paper, in order to control uncertain missile autopilot, an adaptive fuzzy control(AFC) scheme via parallel distributed compensation(PDC) is developed for the multi-input/multi -output plants represented by the Takagi-Sugeno(T-S) fuzzy model. Moreover adaptive law is designed so that the plant output tracks the stable reference model(SRM). From the simulations results, we can conclude that the suggested scheme can effectively solve the control problems of uncertain missile systems based on T-S fuzzy model.

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Design of Stabilizing Controller for an Inverted Pendulum System Using The T-S Fuzzy Model (T-S 퍼지 모델을 이용한 역진자 시스템의 안정화 제어기 설계)

  • 배현수;권성하;정은태
    • Journal of Institute of Control, Robotics and Systems
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    • v.8 no.11
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    • pp.916-921
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    • 2002
  • We presents a new method of constructing an equivalent T-S fuzzy model by using the sum of products of linearly independent scalar functions from nonlinear dynamics. This method exactly expresses nonlinear systems and automatically determines the number of rules. We design a stabilizing controller f3r ul inverted pendulum system by using the concep of parallel distributed compensation (PDC) and linear matrix inequalities (LMIs) based on the proposed T-S fuzzy modeling method. We show effectiveness of a systematically designed fuzzy controller based on the proposed T-S fuzzy modeling method through the simulation and experiment of an inverted pendulum system.

Study on Electrically Assisted Pressure Solid State Joining Between Aluminum Alloys (통전압접을 활용한 알루미늄 소재 간 고상접합에 관한 연구)

  • Choi, H.;Lee, S.;Kim, Y.;Hong, S.T;Han, H.N.
    • Transactions of Materials Processing
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    • v.31 no.6
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    • pp.337-343
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    • 2022
  • Electrically assisted pressure joining (EAPJ) utilizes electric current-induced kinetic enhancement to achieve solid state diffusion bonding within a short time. In this study, aluminum alloy specimens, which are known as a hard-to-weld metal, were successfully solid-state joined through EAPJ. The bonding process was performed in two ways: continuous direct current (CDC), which applies relatively low current density, and pulsed direct current (PDC), which applies high current density. It was observed that the bonding strength was higher in PDC than in CDC. The microstructure of the joint was characterized using 3D X-ray microscopy (XRM) and electron backscatter diffraction (EBSD).

Hydrothermal Synthesis, Crystal Structure of Four Novel Complexes Based on Thiabendazole Ligand

  • Wei, Shui-Qiang;Lin, Cui-Wu;Yin, Xian-Hong;Huang, Yue-Jiao;Luo, Pei-Qi
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.2917-2924
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    • 2012
  • Four novel metal-organic complexes $[Cd_2(IP)_2(TBZ)_2(H_2O)_2]{\cdot}(H_2O)$ (1), $[Zn_4(IP)_4(TBZ)_4]{\cdot}2(H_2O)$ (2), $[Zn_2(BTC)(TBZ)_2(CO_2H)]$ (3), [Co(PDC)(TBZ)] (4) (where IP = isophthalate; TBZ = thiabendazole; BTC = 1,3,5-benzenetricarboxylate; PDC = pyridine-3,4-dicarboxylate) have been prepared and characterized by IR spectrum, elemental analysis, thermogravimetric analysis, and single-crystal X-ray diffraction. X-ray structure analysis reveals that 1, 2, and 3 are one-dimensional chain polymers, while 4 is a two-dimensional network polymer. The TBZ acts as a typical chelating ligand coordinated to the metal center in all complexes. The 1D chain architecture of 1 is constructed from isophthalates and cadmium atoms. A simultaneous presence of chelating, monodentate and bidentate coordination modes of IP ligands is observed in complex 2. In complex 3, the 16-membered rings are alternately arranged forming an infinite 1D double-chain structure. The 2D skeleton of 4 is formed by cobalt ions as nodes and PDC dianions as spacers, through coordination bonds. The hydrogen bonds and ${\pi}-{\pi}$ stacking play important roles in affecting the final structure where complexes 1 and 3 have 2D supramolecular networks, while complexes 2 and 4 have 3D supramolecular architectures.

Comparison of Growth Characteristics and Ginsenoside Contents of 3-Year-Old Ginseng (Panax ginseng C. A. Meyer) by Drainage Class and Shade Material in Paddy Soil (논토양에서 해가림 유형별 3년생 인삼의 생육과 진세노사이드함량 비교)

  • Lee, Sung-Woo;Kim, Gum-Sook;Hyun, Dong-Yun;Kim, Yong-Burm;Yeon, Byeong-Yeol;Kang, Seung-Won;Kim, Young-Churl
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.54 no.4
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    • pp.390-396
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    • 2009
  • To select optimal shade material in paddy soil, growth characteristics and ginsenoside contents were investigated in new cultivar, 'Cheonpoong' of three-year-old ginseng cultured under three kinds of shade materials such as three-layered blue and one-layered black PE (polyethylene) net (TBPN), blue PE sheet (BPSS), and aluminium-coated PE sheet (APSS). The order of light transmission ratio and air temperature by shade materials were BPSS > APSS > TBSB among three shade materials. Average soil water tension in PDC and IDC was 64 mbar (absolute soil moisture, 25%) and 123 mbar (absolute soil moisture, 17%), respectively, and soil water tension in IDC was changed more distinctly than that of PDC by season and shade materials. Yield in PDC was distinctly decreased more than that in IDC because of the increase of discolored-leaf and rusted-root ratio. BPSS and TBPN among three shade materials were the most effective on the increase of yield in PDC and IDC, respectively. Ratio of rusty-colored root showed not significant difference by drainage class and shade materials. Contents of panaxatriol ginsenoside (Rg1, Re and Rf) were decreased in PDC, while it of panaxadiol ginsenoside (Rb1, Rc and Rd) were increased in IDC. Total ginsenoside contents of IDC was distinctly higher than that of PDC, and BPSS showed the highest contents among three shade materials regardless of poorly and imperfectly drainage class.

Comparison of Growth Characteristics and Ginsenoside Contents by Drainage classes and Varieties in 3-Year-Old Ginseng (Panax ginseng C. A. Meyer) (논토양 배수등급 및 품종별 3년생 인삼의 생육과 진세노사이드함량 비교)

  • Lee, Sung-Woo;Kim, Gum-Sook;Yeon, Byeong-Yeol;Hyun, Dong-Yun;Kim, Yong-Burm;Kang, Seung-Won;Kim, Young-Churl
    • Korean Journal of Medicinal Crop Science
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    • v.17 no.5
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    • pp.346-351
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    • 2009
  • To study the optimal cultivation for paddy soil, growth characteristics and ginsenoside content was investigated by both of poor drainage class (PDC) and imperfect drainage class (IDC) in three-year-old ginseng of varieties, Cheonpoong (CP), Yeonpoong (YP), Hwangsookjong (HS), and Jakyeongjong (JK). Root yield of IDC was higher than that of PDC by 3.6 times because stem length, leaf area, and chlorophyll contents were increased, while discolored leaf ratio was decreased. Root yield of HS in PDC was highest among four varieties because chlorophyll contents, leaf area, and survived plant ratio were relatively high. Root yield of CP in IDC was highest among four varieties because of high leaf area and survived plant ratio, and low discolored leaf ratio. Ratio of rusty-colored root showed significant difference by varieties, which was the highest in HS and the lowest in CP among four varieties irrespective of drainage classes. Total ginsenoside contents showed significant difference by drainage classes, which were high in IDC of good growth and low in PDC of poor growth. Total ginsenoside contents were high in JK and CP, while low in HS and YP both of drainage classes.

Measurement of Microbial Protein Supply in Murrah Buffaloes (Bubalus bubalis) Using Urinary Purine Derivatives Excretion and PDC Index

  • Dipu, M.T.;George, S.K.;Singh, P.;Verma, A.K.;Mehra, U.R.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.3
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    • pp.347-355
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    • 2006
  • A study was conducted to predict the rumen microbial protein production based on urinary excretion of purine derivatives in buffaloes fed a diet of wheat straw and concentrate (40:60) at four fixed levels of feed intake. (95, 80, 60 and 40% of preliminary voluntary feed intake) following experimental protocol of IAEA (Phase I). The buffaloes were allocated according to a $4{\times}4$ latin square design. The urinary allantoin, uric acid, total PD excretion (mmol/d) in treatments L-95, L-80, L-60 and L-40 was 20.13, 16.00, 12.96 and 9.17; 1.88, 2.12, 2.11 and 2.15; 22.01, 18.12, 15.07 and 11.32, respectively and were significantly (p<0.05) different among treatments except for uric acid. The rate of PD excretion (mmol/d) was positively correlated with the digestible organic matter intake. Variations were observed in PD and creatinine concentration in spot samples collected at 6-hour interval. However, daily PD:Creatinine ratio (PDC index) appears to be a reasonably good predictor of microbial-N supply. The contribution of basal purine excretion to total excretion of purine derivatives (PD) was determined in pre-fasting period followed by a fasting period of 6 d (Phase II). Daily PD and creatinine excretion (mmol/kg $W^{0.75}$) during fasting averaged 0.117 and 0.456 respectively for buffaloes. The excretion rates of PD decreased significantly (p<0.01) during fasting compare to pre-fasting period, the urinary creatinine excretion remained almost similar. Except for creatinine, plasma concentration of target parameters significantly (p<0.01) declined during fasting. Likewise, glomerular filtration rate (GFR) and renal clearance of allantoin and uric acid also decreased. Based on the PD excretion rates during fasting and at different levels of feed intake obtained in this study, a relationship between daily urinary PD excretion (Y-mmol) and microbial purine absorption (X-mmol) was developed for buffaloes as Y = 0.74X+0.117 kg $W^{0.75}$. The microbial N supply (g/kg DOMI) remained statistically similar irrespective of dietary treatment. The results showed that excretion of urinary purine derivatives is positively correlated with the levels of feed intake in Murrah buffaloes and thus, estimation of urinary purine derivatives and PDC index could be used to determine microbial nitrogen supply when there is large variation in level of feed intake.

Hybrid Integration of P-Wave Velocity and Resistivity for High-Quality Investigation of In Situ Shear-Wave Velocities at Urban Areas (도심지 지반 전단파속도 탐사를 위한 P-파 속도와 전기비저항의 이종 결합)

  • Joh, Sung-Ho;Kim, Bong-Chan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.1C
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    • pp.45-51
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    • 2010
  • In urban area, design and construction of civil engineering structures such as subway tunnel, underground space and deep excavation is impeded by unreliable site investigation. Variety of embedded objects, electric noises and traffic vibrations degrades the quality of site investigation, whatever the site-investigation technique would be. In this research, a preliminary research was performed to develop a dedicated site investigation technique for urban geotechnical sites, which can overcome the limitations of urban sites. HiRAS (Hybrid Integration of Surface Waves and Resistivity) technique which is the first outcome of the preliminary research was proposed in this paper. The technique combines surface wave as well as electrical resistivity. CapSASW method for surface-wave technique and PDC-R technique for electrical resistivity survey were incorporated to develop HiRAS technique. CapSASW method is a good method for evaluating material stiffness and PDC-R technique is a reliable method for determination of underground stratification even in a site with electrical noise. For the inversion analysis of HiRAS techniuqe, a site-specific relationship between stress-wave velocity and resistivity was employed. As for outgrowth of this research, the 2-D distribution of Poisson's ratio could be also determined.